Chapter 18: Q38. (page 967)
Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.
(j) (k) (l)
Short Answer
(a)
(b)
(c) heptanal
(d) benzophenone
(e)butanal
(f)
(g)
(h)
(i)
(j)
(k)
(l)
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Chapter 18: Q38. (page 967)
Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.
(j) (k) (l)
(a)
(b)
(c) heptanal
(d) benzophenone
(e)butanal
(f)
(g)
(h)
(i)
(j)
(k)
(l)
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is frequently used for making derivatives of ketones and aldehydes because the products (, called derivatives) are even more likely than the phenlyhydrazones to be solids with sharp melting points. Propose a mechanism for the reaction of acetone with in a mildly acidic solution.
The following road-map problem centers on the structure and properties of A, a key intermediate in these reactions. Give structures for compounds A through J.


Use equations to show the fragmentation leading to each numbered peak in the mass spectrum of octane-2-one .

For each compound,




(a) Propose a mechanism for the acid-catalyzed reaction of cyclohexanone with ethylene glycol to give cyclohexanone ethylene acetal.
(b) Propose a mechanism for the acid-catalyzed hydrolysis of cyclohexanone ethylene acetal.
(c) Compare the mechanisms you drew in parts (a) and (b). How similar are these mechanisms, comparing them in reverse order?
(d) Propose a mechanism for the acid-catalyzed hydrolysis of the acetal given in Problem 18-26(f).
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