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Chapter 18: Q22P (page 947)

Predict the products of the following reactions.

Short Answer

Expert verified

Cyclopentanone on treatment with hydroxylamine in acidic medium generates oxime. It is a condensation reaction and loss of water molecule is there. Oximes exists as thick liquids and are insoluble in water.

Oxime of cyclopentanone

Step by step solution

01

Explanation of part (a):

Cyclopentanone on treatment with hydroxylamine in acidic medium generates oxime. It is a condensation reaction and loss of water molecule is there. Oximes exists as thick liquids and are insoluble in water.

Oxime of cyclopentanone

02

Explanation of part (b):

The given reactant on treatment with hydrazine in acidic medium gives hydrazone as the product. This is a condensation reaction and loss of water molecule occurs as a result.

Hydrazone of 3,4-dihydronapthalen-1-one

03

Explanation of part (c):

Benzophenone on reaction with phenylhydrazone in acidic medium generates phenylhydrazine of benzophenone as the product. This reaction is condensation reaction and occurs with a loss of water molecule.

Phenylhydrazine of benzophenone

04

Explanation of part (d):

Cinnamaldehyde on reaction with semicarbazide in acidic medium leads to the generation of semicarbazone of cinnamaldehyde. It is a condensation reaction which occurs with a loss of water molecule.

Semicarbazone of cinnamaldehyde

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Most popular questions from this chapter

Trimethylphosphine is a stronger nucleophile than triphenylphosphine, but it is rarely used to make ylides. Why is trimethylphosphine unsuitable for making most phosphorus ylides?

In the mechanism for acetal hydrolysis shown, the ring oxygen atom was protonated first, the ring was cleaved, and then the methoxy group was lost. The mechanism could also be written to show the methoxy oxygen protonating and cleaving first, followed by ring cleavage. Draw the alternative mechanism.

Show how you would synthesize each compound from starting materials containing no more than six carbon atoms.

(a)

(b)

(c)

Question: Solving the following road-map problem depends on determining the structure of A, the key intermediate. Give structures for compounds A through K.

Question: Within each set of structures, indicate which will react fastest, and which slowest, toward nucleophilic addition in basic conditions.
See all solutions

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