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Chapter 22: Q.69D (page 1204)

Question: Predict the products of the following reactions
d.

Short Answer

Expert verified

Answer

Step by step solution

Aldol self-condensation

It is the reaction of the enolate ion with another carbonyl group lead to form $伪, 尾$ unsaturated aldehyde or ketone.

Formation of the product

As the hydrogen is protonated from the reacting species formation of enolate ion occur which combine with another group of carbonyl followed by the removal of formation of unsaturated aldehyde occur as shown:

Product

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Most popular questions from this chapter

Give the expected products for the aldol condensations of

propanal.
phenylacetaldehyde
pentan-3-one.

The following compounds can be synthesized by aldol condensations, followed by further reactions. (In each case, work backward from the target molecule to an aldol product, and show what compounds are needed for the condensation.)

Question:Show how you would use the Robinson annulation to synthesize the following compounds.

Question: Predict the products of the following reactions

Some (but not all) of the following keto esters can be formed by Dieckmann condensations. Determine which ones are possible, and draw the starting diesters.