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Chapter 6: 58 P-d (page 331)

Question: Show the products you expect when each compound reacts with NBS with light shining on the reaction.

d)

Short Answer

Expert verified

d)The product formed from the above compound when react with NBS

Step by step solution

01

Step 1:

The bromination reaction is the process by which one or more bromine atoms are added to a chemical. Halogination reaction includes bromination reactions. N-bromosuccinimide, also known as NBS (sourse of Br), is employed in this reaction as a reagent to aid in radical substitution.

A free radical is a molecule that lacks charge and has an unpaired electron. Free radicals are extremely reactive substances with a brief shelf life.

02

Step 2:

First, the reagent N-bromosuccinimide (NBS) that produces the bromine radical Br undergoes radical formation.

03

Step 3:

An allylic free radical is the end product of the formation of free radical in the alkene. The proposed mechanism to explain the observed products in the described reaction between an alkene and NBS.

Because of the generated radical is both allylic and benzyllic in nature which making it a highly stable product, it is the most advantageous and significant result.

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Most popular questions from this chapter

Give the structures of the following compounds.

(a) Methylene chloride

(b) Carbon tetrachloride

(c) 3-iodo-2-methylpentane

(d) Chloroform

(e) 2-chloro-3-ethyl-2-methyhexane

(f) Isobutyl iodide

(g) Cis-1-chloro-3-(chloromethyl)cyclohexane

(h) Tert-butyl bromide

(a)Optically active 2-bromobutane undergoes racemization on treatment with a solution of KBr. Give a mechanism for this racemization.

(b)In contrast, optically active butan-2-ol does not racemize on treatment with a solution of KOH. Explain why a reaction like that in part (a) does not occur.

(c)Optically active butan-2-ol racemizes in dilute acid. Propose a mechanism for this racemization.

(c)Optically active butan-2-ol racemizes in dilute acid. Propose a mechanism for this racemization.

Predict the major product of the following reaction, and give a mechanism to support your prediction.

Question: Propose mechanisms to account for the observed products in the following reactions.

b)
See all solutions

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