Chapter 2: Problem 1
a. Which compounds are Br酶nsted-Lowry acids: \(\mathrm{HBr}, \mathrm{NH}_{3}, \mathrm{CCl}_{4} ?\) b. Which compounds are Br酶nsted-Lowry bases: \(\mathrm{CH}_{3} \mathrm{CH}_{3},\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CO}^{-}, \mathrm{HC} \equiv \mathrm{CH}\) ? c. Classify each compound as an acid, a base, or both: \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}, \mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{CH}_{3}\).
Short Answer
Step by step solution
Understanding Br酶nsted-Lowry Acids
Identifying Acid: HBr
Analyzing NH鈧 as an Acid
Analyzing CCl鈧 as an Acid
Conclusion for Part a
Understanding Br酶nsted-Lowry Bases
Analyzing CH鈧僀H鈧 as a Base
Identifying Base: (CH鈧)鈧僀O鈦
Analyzing HC鈮H as a Base
Conclusion for Part b
Classifying CH鈧僀H鈧侽H
Classifying CH鈧僀H鈧侰H鈧侰H鈧
Classifying CH鈧僀O鈧侰H鈧
Conclusion for Part c
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Proton Donor
In the context of the exercise, compounds like (HBr) exhibit these characteristics. When dissolved in water, (HBr) donates (H鈦), breaking into (H鈦) and (Br鈦), thus acting as a Br酶nsted-Lowry acid.
A proton donor doesn't need to be in water to act as an acid; it just needs to be capable of releasing a proton within any chemical interaction.
- **Ability to Donate Protons:** Central to its classification as a proton donor.
- **Presence of Hydrogens:** Compounds considered as acids must have hydrogen atoms available for donation.
Proton Acceptor
("(CH鈧)鈧僀O鈦"), known as an alkoxide ion, unequivocally illustrates this concept as it contains a lone pair on its oxygen atom, enabling it to accept a proton efficiently.
An important aspect when considering proton acceptors is the presence of lone pairs or negative charges capable of bonding with protons.
- **Lone Pair Electrons:** Essential for the acceptance of protons.
- **Affinity for Protons:** Determines the strength of a base.
Acid-Base Classification
An important case is **ethanol (CH鈧僀H鈧侽H)**, which can either donate a proton, making it an acid, or accept a proton at the oxygen's lone pairs, thus functioning as a base. This dual potential shows that some substances don't fit neatly into just one category.
Other compounds like **butane (CH鈧僀H鈧侰H鈧侰H鈧)** show neither propensity, as they lack the functional groups to donate or accept protons, categorically excluding them from being either acids or bases.
Here are critical distinctions in classifying:
- **Proton Donating Ability:** To identify acids.
- **Proton Accepting Ability:** To determine bases.
- **Functional Group Presence:** Critical in evaluating the compound's behavior as an acid, base, or neutral.