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A \(3.664-\mathrm{g}\) sample of a monoprotic acid was dissolved in water and required \(20.27 \mathrm{~mL}\) of a \(0.1578 \mathrm{M}\) \(\mathrm{NaOH}\) solution for neutralization. Calculate the molar mass of the acid.

Short Answer

Expert verified
The molar mass of the acid is approximately 1145 g/mol.

Step by step solution

01

Calculate moles of $\mathrm{NaOH}$ using concentration and volume

Firstly, calculate the moles (n) of the $\mathrm{NaOH}$ used in the reaction by using the equation n = c × V, where c is the concentration and V is the volume. In this case, c = \(0.1578 \mathrm{M}\) and V = \(20.27 \mathrm{~mL} = 20.27 \times 10^{-3} \mathrm{L}\). Therefore n = \(0.1578 \times 20.27 \times 10^{-3} = 3.200 \times 10^{-3}\) moles.
02

Determine moles of the acid

Since each acid molecule reacts with one $\mathrm{NaOH}$ molecule, the moles of the acid are also \(3.20 \times 10^{-3}\) moles.
03

Calculation of the Molar mass of the acid

Finally, calculate the molar mass (MM) of the acid by using the equation MM = m / n, where m is the mass and n is the moles. In this case m = 3.664 g and n = 3.20 x 10^{-3} mol, hence MM = 3.664 / \(3.20 \times 10^{-3} = 1145 \mathrm{g/mol}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Monoprotic Acid
A monoprotic acid is a type of acid that can donate only one proton (hydrogen ion) per molecule during a reaction. This is an essential concept when working with reactions involving acids and bases. In a neutralization reaction, a monoprotic acid will exactly neutralize an equivalent amount of a base.
This is because it provides one proton per acid molecule, reacting with one hydroxide ion from the base.
For example:
  • Hydrochloric acid (HCl)
  • Acetic acid (CH₃COOH)
These acids only have one replaceable hydrogen atom, making calculations straightforward.
During calculations, remember monoprotic acids equate their moles directly to the moles of the base in a reaction, simplifying stoichiometric calculations.
Neutralization Reaction
A neutralization reaction occurs when an acid and a base react to form water and a salt. It's an important chemical process widely seen in chemistry and everyday life.
In the context of the exercise, the neutralization involves a monoprotic acid and sodium hydroxide (NaOH), a common strong base.
Here's what generally happens in neutralization:
  • The acid donates a proton to the hydroxide ion from the base.
  • Water ( Hâ‚‚O ) is formed as a result.
  • The remaining ions form a salt.
For a monoprotic acid, such as those mentioned earlier, each molecule of acid will neutralize one molecule of a strong base like NaOH.
The reaction can be summarized as follows, showing the balance:
  • HA + NaOH → NaA + Hâ‚‚O
Here, HA represents the monoprotic acid molecule, and NaA is the salt produced.
Stoichiometry
Stoichiometry is the area of chemistry that deals with the quantitative relationships of reactants and products in a chemical reaction. It allows you to calculate amounts of substances needed or produced in reactions, crucial for solving problems like calculating molar masses.
In our specific case of neutralizing a monoprotic acid with NaOH:
  • Step 1: Calculate the moles of NaOH used, since volume and concentration are known. Use the formula \( n = c \times V \), where \( c \) is the concentration and \( V \) is the volume in liters.
  • Step 2: Since it's a 1:1 neutralization reaction, the moles of NaOH will equal the moles of the monoprotic acid used.
  • Step 3: Finally, to find the molar mass of the acid, use \( \text{Molar Mass} = \frac{\text{mass of acid}}{\text{moles of acid}} \).
This process demonstrates how stoichiometry ties volume and concentration to actual chemical quantities, allowing you to determine essential properties like molar mass.

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Most popular questions from this chapter

Phosphorus forms many oxoacids. Indicate the oxidation number of phosphorus in each of the following acids: (a) \(\mathrm{HPO}_{3},\) (b) \(\mathrm{H}_{3} \mathrm{PO}_{2},\) (c) \(\mathrm{H}_{3} \mathrm{PO}_{3},\) d) \(\mathrm{H}_{3} \mathrm{PO}_{4}\) (e) \(\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{7},\) (f) \(\mathrm{H}_{5} \mathrm{P}_{3} \mathrm{O}_{10}\).

Phosphoric acid \(\left(\mathrm{H}_{3} \mathrm{PO}_{4}\right)\) is an important industrial chemical used in fertilizers, detergents, and in the food industry. It is produced by two different methods. In the electric furnace method elemental phosphorus \(\left(\mathrm{P}_{4}\right)\) is burned in air to form \(\mathrm{P}_{4} \mathrm{O}_{10}\), which is then reacted with water to give \(\mathrm{H}_{3} \mathrm{PO}_{4}\). In the wet process the mineral phosphate rock \(\left[\mathrm{Ca}_{5}\left(\mathrm{PO}_{4}\right)_{3} \mathrm{~F}\right]\) is reacted with sulfuric acid to give \(\mathrm{H}_{3} \mathrm{PO}_{4}\) ( and HF and \(\mathrm{CaSO}_{4}\) ). Write equations for these processes and classify each step as precipitation, acid-base, or redox reaction.

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Describe the basic steps involved in gravimetric analysis. How does this procedure help us determine the identity of a compound or the purity of a compound if its formula is known?

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