Chapter 20: Problem 10
Describe the interaction between a donor atom and a metal atom in terms of a Lewis acid-base reaction.
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Chapter 20: Problem 10
Describe the interaction between a donor atom and a metal atom in terms of a Lewis acid-base reaction.
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What are the systematic names for these ions and compounds: (a) \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right]^{+},\) (b) \(\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3},\) (c) \(\left[\mathrm{Co}(\mathrm{en})_{2} \mathrm{Br}_{2}\right]^{+},\) (d) \(\mathrm{Fe}(\mathrm{CO})_{5} ?\)
What factors determine whether a given complex will be diamagnetic or paramagnetic?
Give the oxidation numbers of the metals in these species: (a) \(\mathrm{Na}_{2} \mathrm{MoO}_{4}\) (b) \(\mathrm{MgWO}_{4}\), (c) \(\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\)
Draw qualitative diagrams for the crystal-field splittings in (a) a linear complex ion \(\mathrm{ML}_{2},\) (b) a trigonalplanar complex ion \(\mathrm{ML}_{3},\) and \((\mathrm{c})\) a trigonalbipyramidal complex ion ML \(_{5}\).
The \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) ion, which has a square planar geometry, is diamagnetic, whereas the \(\left[\mathrm{NiCl}_{4}\right]^{2-}\) ion, which has a tetrahedral geometry, is paramagnetic. Show the crystal field splitting diagrams for those two complexes.
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