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Iron(II) ion is oxidized by hydrogen peroxide in acidic solution. $$\mathrm{H}_{2} \mathrm{O}_{2}(a q)+2 \mathrm{Fe}^{2+}(a q)+2 \mathrm{H}^{+}(a q) \longrightarrow$$ The rate law is $$\text { Rate }=k\left[\mathrm{H}_{2} \mathrm{O}_{2}\right]\left[\mathrm{Fe}^{2+}\right]$$ What is the order with respect to each reactant? What is the overall order?

Short Answer

Expert verified
Each reactant has an order of 1, making the overall reaction order 2.

Step by step solution

01

Identify the Rate Law

Examine the given rate law expression:\[ \text{Rate} = k[\text{H}_2\text{O}_2][\text{Fe}^{2+}] \]The rate law shows how the rate of the reaction depends on the concentration of the reactants.
02

Determine the Order with Respect to Each Reactant

The concentration of each reactant raised to its respective power in the rate law indicates its order respect to that reactant.- For \([\text{H}_2\text{O}_2]\), the exponent is not explicit, implying it is 1. Thus, the order with respect to \(\text{H}_2\text{O}_2\) is 1.- For \([\text{Fe}^{2+}]\), the exponent is not explicit, implying it is 1. Thus, the order with respect to \(\text{Fe}^{2+}\) is also 1.
03

Calculate the Overall Reaction Order

The overall order of the reaction is the sum of the orders with respect to each reactant:\[ \text{Order with respect to } \text{H}_2\text{O}_2 = 1 \]\[ \text{Order with respect to } \text{Fe}^{2+} = 1 \]\[ \text{Overall Reaction Order} = 1 + 1 = 2 \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Rate Law
The rate law is a mathematical expression that offers vital insight into the kinetics of a chemical reaction. It provides a relationship between the rate of a reaction and the concentrations of reactants involved in the reaction. Understanding the rate law is essential for predicting how changes in conditions might affect the speed of a reaction.

The form of the rate law depends on the individual reaction and is determined experimentally. In the exercise provided, the given rate law is expressed as:

\[ \text{Rate} = k[\text{H}_2\text{O}_2][\text{Fe}^{2+}] \]

Here, \(k\) is the rate constant, which is specific to the reaction at a constant temperature. The concentration terms [\(\text{H}_2\text{O}_2\)] and [\(\text{Fe}^{2+}\)] are each raised to the power of 1. This indicates how the rate is linearly proportional to each reactant's concentration. While the exponents may be integers, fractions, or even zero, in this case, both are 1, suggesting a first-order dependence on each reactant.
Oxidation Reaction
An oxidation reaction involves the loss of electrons by a species. It is a key part of redox (reduction-oxidation) reactions, with one species being oxidized and another reduced. In many chemical processes, particularly those in solution, oxidation reactions are fundamental.

In the exercise's context, Iron(II) ions, denoted as \( \text{Fe}^{2+}\), undergo oxidation when they react with hydrogen peroxide in an acidic solution. This specific process signifies that \( \text{Fe}^{2+}\) loses electrons, effectively becoming Iron(III) ions. Meanwhile, the hydrogen peroxide acts as the oxidizing agent, which itself will undergo concomitant reduction.

Oxidation reactions are essential in various fields, from metabolism in biological systems to procedures in industrial chemistry. Understanding these reactions is crucial for predicting how substances will interact under different conditions.
Hydrogen Peroxide
Hydrogen peroxide (\(\text{H}_2\text{O}_2\)) is a versatile compound acting both as an antiseptic in everyday use and as a powerful chemical oxidizer. Its properties enable it to engage in significant reactions, such as the oxidation of metals such as Iron(II) ions.

In the provided reaction, hydrogen peroxide is considered a key reactant and acts primarily as an oxidizing agent. When hydrogen peroxide reacts, it can be reduced to water (\(\text{H}_2\text{O}\)), which completes its role in the redox process.

Its application in diverse chemical and biological systems highlights the importance of understanding its behavior and reactivity, especially in controlled chemical reactions. Knowing how hydrogen peroxide functions can help chemists design experiments and entire processes that can utilize its properties while maintaining safety.
Iron(II) Ion
Iron(II) ions, represented as \(\text{Fe}^{2+}\), are a form of iron commonly found in various environments, including biological systems and industrial processes. These ions are highly reactive and readily participate in oxidation reactions.

In the context of the given reaction with hydrogen peroxide, \(\text{Fe}^{2+}\) ions act as a reducing agent. This means they donate electrons in the redox reaction, undergoing oxidation to form Iron(III) ions \(\text{Fe}^{3+}\).

Understanding the role of \(\text{Fe}^{2+}\) ions in this reaction is important for applications in fields such as wastewater treatment, where they can aid in the removal of contaminants through oxidation and subsequent precipitation. Additionally, in biological systems, the balance between Iron(II) and Iron(III) is crucial for processes like oxygen transport and energy production.

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Most popular questions from this chapter

Nitrogen monoxide, \(\mathrm{NO}\), is believed to react with chlorine according to the following mechanism: $$\begin{aligned}\mathrm{NO}+\mathrm{Cl}_{2} & \rightleftharpoons \mathrm{NOCl}_{2} & & \text { (elementary reaction) } \\ \mathrm{NOCl}_{2}+\mathrm{NO} & \longrightarrow 2 \mathrm{NOCl} & &(\text { elementary reaction }) \end{aligned}$$ Identify any reaction intermediate. What is the overall equation?

The chemical reaction \(\mathrm{A} \longrightarrow \mathrm{B}+\mathrm{C}\) has a rate constant that obeys the Arrhenius equation. Predict what happens to both the rate constant \(k\) and the rate of the reaction if the following were to occur. a. a decrease in temperature b. an increase in the activation energy of the forward and reverse reactions C an increase in both activation energy and temperature

Nitryl bromide, \(\mathrm{NO}_{2} \mathrm{Br}\), decomposes into nitrogen dioxide and bromine. $$2 \mathrm{NO}_{2} \mathrm{Br}(g) \longrightarrow 2 \mathrm{NO}_{2}(g)+\mathrm{Br}_{2}(g)$$ A proposed mechanism is $$\begin{array}{r}\mathrm{NO}_{2} \mathrm{Br} \longrightarrow \mathrm{NO}_{2}+\mathrm{Br} \\\\\mathrm{NO}_{2} \mathrm{Br}+\mathrm{Br} \longrightarrow \mathrm{NO}_{2}+\mathrm{Br}_{2}\end{array}$$ Write the rate law predicted by this mechanism.

The decomposition of hydrogen peroxide is a first-order reaction: $$\mathrm{H}_{2} \mathrm{O}_{2}(a q) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l)+\frac{1}{2} \mathrm{O}_{2}(g)$$ The half-life of the reaction is \(17.0\) minutes. a. What is the rate constant of the reaction? b. If you had a bottle of \(\mathrm{H}_{2} \mathrm{O}_{2}\), how long would it take for \(86.0 \%\) to decompose? C. If you started the reaction with \(\left[\mathrm{H}_{2} \mathrm{O}_{2}\right]=0.100 M\), what would be the hydrogen peroxide concentration after \(15.0\) minutes?

A compound decomposes by a first-order reaction. If the concentration of the compound is \(0.0250 M\) after \(65 \mathrm{~s}\) when the initial concentration was \(0.0350 M\), what is the concentration of the compound after 88 s?

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