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Potassium sulfate solution reacts with barium bromide solution to produce a precipitate of barium sulfate and a solution of potassium bromide. Write the molecular equation for this reaction. Then write the corresponding net ionic equation.

Short Answer

Expert verified
Molecular: \( K_2SO_4 (aq) + BaBr_2 (aq) \rightarrow BaSO_4 (s) + 2 KBr (aq) \); Net Ionic: \( Ba^{2+} (aq) + SO_4^{2-} (aq) \rightarrow BaSO_4 (s) \).

Step by step solution

01

Understand the Reaction

Identify the reactants and products in the reaction. Potassium sulfate (\(K_2SO_4\)) reacts with barium bromide (\(BaBr_2\)) to produce a precipitate of barium sulfate (\(BaSO_4\)) and a solution of potassium bromide (\(KBr\)). This is a double displacement reaction.
02

Write the Molecular Equation

In this step, we write the balanced molecular equation for the reaction. The reactants \(K_2SO_4\) and \(BaBr_2\) will exchange partners to form the products \(BaSO_4\) and \(KBr\):\[ K_2SO_4 (aq) + BaBr_2 (aq) \rightarrow BaSO_4 (s) + 2 KBr (aq) \]
03

Write the Complete Ionic Equation

In the complete ionic equation, soluble ionic compounds are represented as dissociated ions. The precipitate \(BaSO_4\) remains as a solid:\[ 2K^+ (aq) + SO_4^{2-} (aq) + Ba^{2+} (aq) + 2Br^- (aq) \rightarrow BaSO_4 (s) + 2K^+ (aq) + 2Br^- (aq) \]
04

Write the Net Ionic Equation

The net ionic equation focuses on the ions that participate in forming the precipitate. Remove the spectator ions \(K^+\) and \(Br^-\), which do not participate in the formation of the precipitate:\[ Ba^{2+} (aq) + SO_4^{2-} (aq) \rightarrow BaSO_4 (s) \]
05

Verify the Reactions

Ensure that both equations are balanced and respect the conservation of mass and charge laws. Both the number of atoms on each side and the charges must be equal, which they are in the above equations.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Double Displacement Reaction
A double displacement reaction is a fascinating type of chemical reaction where two compounds exchange ions to form two new compounds. This can be thought of as a swap of partners. In the case of our exercise with potassium sulfate (\(K_2SO_4\)) and barium bromide (\(BaBr_2\)), they switch their components to form barium sulfate (\(BaSO_4\)) and potassium bromide (\(KBr\)).
These types of reactions often lead to the formation of a precipitate—an insoluble solid that forms out of a liquid solution. In our example, barium sulfate is the precipitate. Double displacement reactions can result in a visible change, like the formation of a solid, a color change, or the release of gas.
It's crucial for students to recognize that in double displacement reactions, the original compounds decompose into their constituent ions in solution. Then, the ions swap, forming new partners and possibly forming one insoluble product that precipitates from the solution.
Understanding this concept is essential for mastering many types of laboratory and real-world chemical transformations.
Molecular Equation
The molecular equation is a representation of the chemical reaction where all the reactants and products are shown as compounds without indicating their ionic nature. For students learning chemistry, it's important to comprehend that this equation offers a macroscopic view of the reaction.
In our exercise example, the molecular equation is:\[ K_2SO_4 (aq) + BaBr_2 (aq) \rightarrow BaSO_4 (s) + 2 KBr (aq) \]This equation shows all the reactants and products in their complete form, focusing on the initial and final compounds rather than the individual ions involved.
The equation balances both the number of atoms and the charge, conveying that matter is neither created nor destroyed during the reaction. It provides a straightforward way for chemists to represent the process on paper, making sure that all elements are accounted for, even if their ionic states are not depicted.
Complete Ionic Equation
When it comes to a complete ionic equation, the goal is to express the soluble ionic compounds as they actually exist in solution—dissociated into their respective ions. This form of the equation provides insight into the actual particles involved in the reaction.
In our case with potassium sulfate and barium bromide, the complete ionic equation is:\[ 2K^+ (aq) + SO_4^{2-} (aq) + Ba^{2+} (aq) + 2Br^- (aq) \rightarrow BaSO_4 (s) + 2K^+ (aq) + 2Br^- (aq) \]Notice how the barium sulfate remains as a solid. This solid is the precipitate that forms when barium ions combine with sulfate ions.
In this equation, we identify the spectator ions, which are ions that appear on both sides of the equation, remaining unchanged. These ions do not participate directly in the formation of the precipitate and include \(K^+\) and \(Br^-\) in our example.
Understanding which ions are actively engaged in the chemical reaction can be instrumental in identifying the precipitate formation, giving students a more microscopic view of the process.

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Most popular questions from this chapter

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