Chapter 16: Problem 3
Define an acid and a base according to the Brønsted-Lowry concept. Give an acid-base equation and identify each species as an acid or a base.
Short Answer
Expert verified
HCl is the acid, and NH\(_3\) is the base in the given reaction.
Step by step solution
01
Understanding the Brønsted-Lowry Concept
The Brønsted-Lowry concept defines an acid as a substance that can donate a proton (H\(^+\)), and a base as a substance that can accept a proton. This concept focuses on the transfer of protons during a chemical reaction.
02
Selecting the Acid-Base Equation Example
Let's consider the reaction between hydrochloric acid (HCl) and ammonia (NH\(_3\)). The equation is: \[ \text{HCl}(aq) + \text{NH}_3(aq) \rightarrow \text{NH}_4^+(aq) + \text{Cl}^-(aq) \]
03
Identifying the Acid in the Equation
In the equation, HCl donates a proton to NH\(_3\), forming Cl\(^-\). Therefore, HCl is the acid because it donates a proton.
04
Identifying the Base in the Equation
NH\(_3\) accepts a proton from HCl to form NH\(_4^+\). Thus, NH\(_3\) is the base because it receives a proton during the reaction.
05
Classifying the Products
After the reaction, Cl\(^-\) remains as the conjugate base of HCl, and NH\(_4^+\) is the conjugate acid formed from NH\(_3\). Therefore, \[\text{HCl} + \text{NH}_3 \rightarrow \text{NH}_4^+ + \text{Cl}^- \] can be classified with HCl as the acid and NH\(_3\) as the base.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Proton Donation
The concept of proton donation is central to the Brønsted-Lowry acid-base theory. According to this theory, an acid is any substance that can donate a proton, commonly represented as \(H^+\). This process involves an acid giving away a positively charged hydrogen ion.
When an acid donates a proton, it essentially loses a positively charged particle. This act of shedding a proton turns the acid into its conjugate base, which carries the leftover negative charge.
For example, in the reaction between hydrochloric acid (HCl) and ammonia (NH\(_3\)), HCl acts as the proton donor. When HCl releases a proton to NH\(_3\), it transforms into the chloride ion (Cl\(^-\)), which is the conjugate base of HCl.
When an acid donates a proton, it essentially loses a positively charged particle. This act of shedding a proton turns the acid into its conjugate base, which carries the leftover negative charge.
For example, in the reaction between hydrochloric acid (HCl) and ammonia (NH\(_3\)), HCl acts as the proton donor. When HCl releases a proton to NH\(_3\), it transforms into the chloride ion (Cl\(^-\)), which is the conjugate base of HCl.
- The HCl molecule loses a proton and becomes Cl\(^-\).
- Proton donation converts an acid to its conjugate base.
Proton Acceptance
Proton acceptance refers to the process where a base gains a proton, or \(H^+\), from an acid. In the Brønsted-Lowry model, a base is any substance capable of accepting a proton. This acceptance leads to the formation of a new compound known as the conjugate acid.
When a base accepts a proton, it transforms into its conjugate acid, which has an additional positive charge due to the extra \(H^+\) ion.
In our example, ammonia (NH\(_3\)) plays the role of a proton acceptor by receiving a proton from HCl. This action results in the formation of the ammonium ion (NH\(_4^+\)), which is the conjugate acid of NH\(_3\).
When a base accepts a proton, it transforms into its conjugate acid, which has an additional positive charge due to the extra \(H^+\) ion.
In our example, ammonia (NH\(_3\)) plays the role of a proton acceptor by receiving a proton from HCl. This action results in the formation of the ammonium ion (NH\(_4^+\)), which is the conjugate acid of NH\(_3\).
- NH\(_3\) accepts a proton and becomes NH\(_4^+\).
- Proton acceptance converts a base to its conjugate acid.
Acid-Base Equation
Understanding acid-base equations helps to visualize the interactions between acids and bases. An acid-base equation demonstrates the transfer of protons from the acid to the base. This transfer is the hallmark of the Brønsted-Lowry theory.
Consider the equation: \[ \text{HCl}(aq) + \text{NH}_3(aq) \rightarrow \text{NH}_4^+(aq) + \text{Cl}^-(aq) \] Here, HCl and NH\(_3\) are the reactants, with HCl donating a proton to NH\(_3\).
By examining this equation, we observe:
Consider the equation: \[ \text{HCl}(aq) + \text{NH}_3(aq) \rightarrow \text{NH}_4^+(aq) + \text{Cl}^-(aq) \] Here, HCl and NH\(_3\) are the reactants, with HCl donating a proton to NH\(_3\).
By examining this equation, we observe:
- HCl is the acid because it donates a proton.
- NH\(_3\) is the base because it accepts a proton.
- The products are NH\(_4^+\), the conjugate acid, and Cl\(^-\), the conjugate base.