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Calculate the volume in \(\mathrm{mL}\) of a \(1.420 \mathrm{M} \mathrm{NaOH}\) solution required to titrate the following solutions: (a) \(25.00 \mathrm{~mL}\) of a \(2.430 \mathrm{M} \mathrm{HCl}\) solution (b) \(25.00 \mathrm{~mL}\) of a \(4.500 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) solution (c) \(25.00 \mathrm{~mL}\) of a \(1.500 \mathrm{M} \mathrm{H}_{3} \mathrm{PO}_{4}\) solution

Short Answer

Expert verified
(a) 42.77 mL, (b) 158.5 mL, (c) 79.23 mL

Step by step solution

01

Find moles of HCl

For (a), calculate the moles of HCl using the formula: \[ \text{moles of HCl} = M \times V = 2.430 \, \text{M} \times 0.02500 \, \text{L} = 0.06075 \, \text{mol} \]
02

Stoichiometry for NaOH and HCl

The reaction is: \[ \text{HCl} + \text{NaOH} \rightarrow \text{NaCl} + \text{H}_2\text{O} \]Mole ratio is 1:1, so moles of NaOH needed = moles of HCl = 0.06075 mol.
03

Calculate Volume of NaOH for HCl Titration

Using the molarity of NaOH, find the volume needed: \[ 1.420 \, \text{M} = \frac{0.06075 \, \text{mol}}{V} \Rightarrow V = \frac{0.06075}{1.420} = 0.04277 \, \text{L} = 42.77 \, \text{mL} \]
04

Find moles of H2SO4

For (b), calculate the moles of \(\text{H}_2\text{SO}_4\) using: \[ 4.500 \, \text{M} \times 0.02500 \, \text{L} = 0.1125 \, \text{mol} \]
05

Stoichiometry for NaOH and H2SO4

The reaction is: \[ \text{H}_2\text{SO}_4 + 2\text{NaOH} \rightarrow \text{Na}_2\text{SO}_4 + 2\text{H}_2\text{O} \]Mole ratio is 1:2, so moles of NaOH needed = 2 \times 0.1125 = 0.225 mol.
06

Calculate Volume of NaOH for H2SO4 Titration

Using the molarity of NaOH: \[ 1.420 \, \text{M} = \frac{0.225 \, \text{mol}}{V} \Rightarrow V = \frac{0.225}{1.420} = 0.1585 \, \text{L} = 158.5 \, \text{mL} \]
07

Find moles of H3PO4

For (c), calculate the moles of \(\text{H}_3\text{PO}_4\) using: \[ 1.500 \, \text{M} \times 0.02500 \, \text{L} = 0.0375 \, \text{mol} \]
08

Stoichiometry for NaOH and H3PO4

The reaction is: \[ \text{H}_3\text{PO}_4 + 3\text{NaOH} \rightarrow \text{Na}_3\text{PO}_4 + 3\text{H}_2\text{O} \]Mole ratio is 1:3, so moles of NaOH needed = 3 \times 0.0375 = 0.1125 mol.
09

Calculate Volume of NaOH for H3PO4 Titration

Using the molarity of NaOH: \[ 1.420 \, \text{M} = \frac{0.1125 \, \text{mol}}{V} \Rightarrow V = \frac{0.1125}{1.420} = 0.07923 \, \text{L} = 79.23 \, \text{mL} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molarity
Molarity is a fundamental concept in chemistry, useful for understanding the concentration of solutions. Molarity (M) is defined as the number of moles of solute per liter of solution. It helps in comparing how concentrated one solution is to another. To find molarity, use the formula:
  • \[ M = \frac{\text{moles of solute}}{\text{liters of solution}} \]
In the given exercise, you need the molarity to determine the volume of NaOH needed to neutralize the given acid solution. By understanding molarity, we gain insights into the amount of a substance dissolved in a given volume, which is critical in titration calculations. It is important to note that working with molarity involves converting volumes from milliliters to liters and vice versa for calculations, aligning with the standard unit calculations used in chemical reactions.
Stoichiometry
Stoichiometry is the part of chemistry that deals with the quantitative relationships between reactants and products in a chemical reaction. It involves balanced chemical equations that reflect the proportions of how substances react and form products. Using stoichiometry, one can determine how much of a reactant is needed to fully react with another.In the context of titration calculations, stoichiometry helps us calculate the precise amount of titrant (like NaOH) required. For instance, in our step-by-step solution:
  • The reaction between HCl and NaOH is 1:1 based on the equation \( \text{HCl} + \text{NaOH} \rightarrow \text{NaCl} + \text{H}_2\text{O} \).
  • For \(\text{H}_2\text{SO}_4\), the ratio is 1:2 with NaOH.
  • With \(\text{H}_3\text{PO}_4\), it is 1:3 with NaOH.
Recognizing these stoichiometric relationships allows you to calculate exactly what volume of NaOH is required to react with different acids in the exercise.
Acid-Base Reactions
Acid-base reactions are a type of chemical reaction that occurs when an acid reacts with a base. These reactions are crucial in titration, where you determine the concentration of an acidic or basic solution by exactly neutralizing it with a solution of known concentration.In a neutralization reaction, such as those in the exercise, the acid and base react to form water and a salt. The complete reactions are:
  • \( \text{HCl} + \text{NaOH} \rightarrow \text{NaCl} + \text{H}_2\text{O} \)
  • \( \text{H}_2\text{SO}_4 + 2\text{NaOH} \rightarrow \text{Na}_2\text{SO}_4 + 2\text{H}_2\text{O} \)
  • \( \text{H}_3\text{PO}_4 + 3\text{NaOH} \rightarrow \text{Na}_3\text{PO}_4 + 3\text{H}_2\text{O} \)
Understanding these reactions helps students visualize how bases neutralize acids, forming water and a respective salt. Recognizing these patterns is essential for performing titration calculations correctly.
Volume Calculations
Volume calculations in chemistry are essential when you need to know how much of a liquid is required or formed in a reaction. In titration exercises, you start by finding the moles of solute (acid) and then calculate the corresponding volume of the titrant (base) needed for complete reaction.The process involves the following steps:
  • Calculate moles of the solute using molarity and volume in liters.
  • Apply stoichiometry to find moles of the titrant required.
  • Use these moles with the titrant's molarity to find the volume required, using the formula:\[ V = \frac{\text{moles of solute}}{M} \]
In the solution provided, converting between milliliters and liters and setting up the equations correctly ensures accurate volume determination. Mastering these volume calculations through practice is key to solving titration problems efficiently.

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Most popular questions from this chapter

Milk of magnesia is an aqueous suspension of magnesium hydroxide \(\left[\mathrm{Mg}(\mathrm{OH})_{2}\right]\) used to treat acid indigestion. Calculate the volume of a \(0.035 \mathrm{M} \mathrm{HCl}\) solution (a typical acid concentration in an upset stomach) needed to react with two spoonfuls of milk of magnesia [approximately \(10.0 \mathrm{~mL}\) at \(\left.0.080 \mathrm{~g} \mathrm{Mg}(\mathrm{OH})_{2} / \mathrm{mL}\right]\).

The recommended procedure for preparing a very dilute solution is not to weigh out a very small mass or measure a very small volume of a stock solution. Instead, it is done by a series of dilutions. A sample of \(0.8214 \mathrm{~g}\) of \(\mathrm{KMnO}_{4}\) was dissolved in water and made up to the volume in a 500 -mL volumetric flask. A 2.000-mL sample of this solution was transferred to a 1000-mL volumetric flask and diluted to the mark with water. Next, \(10.00 \mathrm{~mL}\) of the diluted solution were transferred to a 250-mL flask and diluted to the mark with water. (a) Calculate the concentration (in molarity) of the final solution. (b) Calculate the mass of \(\mathrm{KMnO}_{4}\) needed to directly prepare the final solution.

Which of these aqueous solutions would you expect to be the best conductor of electricity at \(25^{\circ} \mathrm{C} ?\) Explain your answer. (a) \(0.20 M \mathrm{NaCl}\) (b) \(0.60 \mathrm{M} \mathrm{CH}_{3} \mathrm{COOH}\) (c) \(0.25 M \mathrm{HCl}\) (d) \(0.20 M \mathrm{Mg}\left(\mathrm{NO}_{3}\right)_{2}\)

Acetic acid \(\left(\mathrm{CH}_{3} \mathrm{COOH}\right)\) is an important ingredient of vinegar. A sample of \(50.0 \mathrm{~mL}\) of a commercial vinegar is titrated against a \(1.00 \mathrm{M} \mathrm{NaOH}\) solution. What is the concentration (in \(M\) ) of acetic acid present in the vinegar if \(5.75 \mathrm{~mL}\) of the base were required for the titration?

Identify each of the following substances as a strong electrolyte, weak electrolyte, or nonelectrolyte: (a) \(\mathrm{Ba}\left(\mathrm{NO}_{3}\right)_{2},\) (b) \(\mathrm{Ne}\) (c) \(\mathrm{NH}_{3}\) (d) \(\mathrm{NaOH}\).

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