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Problem 57

What is the original molarity of a solution of ammonia whose \(\mathrm{pH}\) is \(11.22 ?\)

Problem 59

List four factors that affect the strength of an acid.

Problem 60

How does the strength of an oxoacid depend on the electronegativity and oxidation number of the central atom?

Problem 61

Predict the acid strengths of the following compounds: \(\mathrm{H}_{2} \mathrm{O}, \mathrm{H}_{2} \mathrm{~S},\) and \(\mathrm{H}_{2} \mathrm{Se} .\)

Problem 62

Compare the strengths of the following pairs of acids: (a) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{H}_{2} \mathrm{SeO}_{4}\), (b) \(\mathrm{H}_{3} \mathrm{PO}_{4}\) and \(\mathrm{H}_{3} \mathrm{AsO}_{4}\).

Problem 63

Which of the following is the stronger acid: \(\mathrm{CH}_{2} \mathrm{ClCOOH}\) or \(\mathrm{CHCl}_{2} \mathrm{COOH}\) ? Explain your choice.

Problem 65

Define salt hydrolysis. Categorize salts according to how they affect the \(\mathrm{pH}\) of a solution.

Problem 66

Define salt hydrolysis. Categorize salts according to how they affect the \(\mathrm{pH}\) of a solution.

Problem 67

\(\mathrm{Al}^{3+}\) is not a Brónsted acid, but \(\mathrm{Al}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{3+}\) is. Explain.

Problem 68

Specify which of these salts will undergo hydrolysis: \(\mathrm{KF}, \mathrm{NaNO}_{3}, \mathrm{NH}_{4} \mathrm{NO}_{2}, \mathrm{MgSO}_{4}, \mathrm{KCN}, \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COONa}\) \(\mathrm{RbI}, \mathrm{Na}_{2} \mathrm{CO}_{3}, \mathrm{CaCl}_{2}, \mathrm{HCOOK}\).

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