Chapter 16: Problem 68
Specify which of these salts will undergo hydrolysis: \(\mathrm{KF}, \mathrm{NaNO}_{3}, \mathrm{NH}_{4} \mathrm{NO}_{2}, \mathrm{MgSO}_{4}, \mathrm{KCN}, \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COONa}\) \(\mathrm{RbI}, \mathrm{Na}_{2} \mathrm{CO}_{3}, \mathrm{CaCl}_{2}, \mathrm{HCOOK}\).
Short Answer
Expert verified
Salts that undergo hydrolysis are KF, NH鈧凬O鈧, KCN, C鈧咹鈧匔OONa, Na鈧侰O鈧, and HCOOK.
Step by step solution
01
Understanding Hydrolysis
Hydrolysis refers to the chemical reaction where a salt reacts with water to form its respective acid and base. Typically, salts undergo hydrolysis if they are formed from a weak acid or a weak base.
02
Classify Salts Based on Acid/Base Origin
Identify if each salt is derived from a strong/weak acid and a strong/weak base. Salts from strong acids and strong bases (e.g., NaNO鈧) do not hydrolyze much. Salts from strong bases and weak acids or vice versa often hydrolyze.
03
Assess Each Given Salt
Evaluate each salt:
- KF: From KOH (strong base) and HF (weak acid).
- NaNO鈧: From NaOH (strong base) and HNO鈧 (strong acid).
- NH鈧凬O鈧: From NH鈧 (weak base) and HNO鈧 (weak acid).
- MgSO鈧: From Mg(OH)鈧 (weak base) and H鈧係O鈧 (strong acid).
- KCN: From KOH (strong base) and HCN (weak acid).
- C鈧咹鈧匔OONa: From NaOH (strong base) and C鈧咹鈧匔OOH (weak acid).
- RbI: From RbOH (strong base) and HI (strong acid).
- Na鈧侰O鈧: From NaOH (strong base) and H鈧侰O鈧 (weak acid).
- CaCl鈧: From Ca(OH)鈧 (strong base) and HCl (strong acid).
- HCOOK: From KOH (strong base) and HCOOH (weak acid).
04
Identify Salts That Undergo Hydrolysis
From the evaluations:
- KF will hydrolyze (due to weak HF).
- NH鈧凬O鈧 will hydrolyze because of the weak nature of both constituents.
- KCN will hydrolyze (due to weak HCN).
- C鈧咹鈧匔OONa will hydrolyze (due to weak benzoic acid).
- Na鈧侰O鈧 will hydrolyze (due to weak carbonic acid).
- HCOOK will hydrolyze (due to weak formic acid).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Weak Acids
A weak acid is an acid that does not completely dissociate into its ions in water. When mixed in a solution, only a small fraction of its molecules release protons (H鈦), maintaining an equilibrium between the undissociated acid and its ions. This partial dissociation is what makes certain salts, derived from weak acids, prone to hydrolysis.
Key characteristics of weak acids include:
Key characteristics of weak acids include:
- They have higher pH values compared to strong acids, but less than neutral (about 7).
- Common examples include acetic acid (CH鈧僀OOH) and hydrofluoric acid (HF).
- Their equilibrium constant for dissociation (\( K_a \)) is typically small, reflecting the incomplete dissociation.
Weak Bases
Weak bases are similar to weak acids in that they do not completely ionize in water. Instead of donating protons, weak bases have a limited ability to accept protons from water, resulting in an equilibrium between the base, water, and the ions in solution.
Key features of weak bases include:
Key features of weak bases include:
- They have a higher pH, but still below neutral, indicating the formation of hydroxide ions (OH鈦).
- Ammonia (NH鈧) is a classic example of a weak base.
- Like weak acids, they also have a small equilibrium constant for dissociation (\( K_b \)).
Chemical Reaction
Chemical reactions involve the transformation of substances through the reconfiguration of atomic connections. In the context of salt hydrolysis, the chemical reaction specifically refers to the interaction between water and the salt, leading to the formation of its acidic and basic components.
During hydrolysis:
During hydrolysis:
- The salt reacts with water in a reversible reaction.
- The result is the generation of an acid and a base.
- This reaction can impact the acidity or alkalinity of the solution.
Acid-Base Reactions
Acid-base reactions are central to understanding hydrolysis, especially when considering the nature of salts in water. These reactions involve the transfer of protons between species, determining whether a solution is acidic or basic based on the presence of hydrogen ions (H鈦) or hydroxide ions (OH鈦).
In salt hydrolysis:
In salt hydrolysis:
- Salts from a strong acid and a strong base usually do not affect pH significantly.
- Salts from a strong base and a weak acid or vice versa can create acidic or basic solutions.
- This is due to either the remaining acidic or basic nature of the ions from the weak source.