/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 79 An ore is analyzed for its lead ... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

An ore is analyzed for its lead content as follows. A sample is dissolved in water; then sodium sulfate is added to precipitate the lead as lead(II) sulfate, \(\mathrm{PbSO}_{4}(s) .\) The net ionic equation for the reaction is $$ \mathrm{Pb}^{2+}(a q)+\mathrm{SO}_{4}^{2-}(a q) \rightarrow \mathrm{PbSO}_{4}(s) $$ It was found that \(13.73\) grams of lead(II) sulfate were precipitated from a sample of ore having a mass of \(53.92\) grams. How many grams of lead are there in the sample? What is the mass percentage of lead in the ore?

Short Answer

Expert verified
The ore contains 9.39 g of lead, making up 17.41% of the sample.

Step by step solution

01

Calculate Molar Mass of PbSOâ‚„

Begin by calculating the molar mass of PbSOâ‚„. Using the atomic masses: Pb = 207.2 g/mol, S = 32.07 g/mol, O = 16 g/mol, we find:\[\text{Molar mass of PbSO}_4 = 207.2 + 32.07 + (4 \times 16) = 303.27\, \text{g/mol}\].
02

Determine Moles of PbSOâ‚„

To find the moles of PbSOâ‚„ that were precipitated, divide the mass of the precipitate by its molar mass:\[\text{Moles of PbSO}_4 = \frac{13.73 \, \text{g}}{303.27 \, \text{g/mol}} = 0.0453 \, \text{mol}\].
03

Calculate Mass of Lead in the Sample

Since the molar ratio of Pb to PbSOâ‚„ is 1:1, the moles of Pb is equal to the moles of PbSOâ‚„:\[\text{Moles of Pb} = 0.0453 \, \text{mol}\]. Next, calculate the mass of Pb using its molar mass:\[\text{Mass of Pb} = 0.0453 \, \text{mol} \times 207.2 \, \text{g/mol} = 9.39 \, \text{g}\].
04

Calculate Mass Percentage of Lead

Finally, compute the mass percentage of lead in the ore sample by dividing the mass of lead by the total mass of the ore and multiplying by 100:\[\text{Mass percentage of Pb} = \left(\frac{9.39 \, \text{g}}{53.92 \, \text{g}}\right) \times 100 = 17.41\%\].

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Molar Mass
Molar mass is a crucial concept in chemistry that helps us understand the mass of one mole of a substance. It's determined by adding up the atomic masses of all the elements in a compound. For instance, in the exercise, we calculated the molar mass for lead(II) sulfate \( \text{PbSO}_4 \). This involves:
  • Identifying the atomic mass of each element: Lead (Pb) = 207.2 g/mol, Sulfur (S) = 32.07 g/mol, Oxygen (O) = 16 g/mol.
  • Summing these values, with consideration for how many atoms of each element are present in the molecule: \( 207.2 + 32.07 + (4 \times 16) = 303.27 \, \text{g/mol} \).
The molar mass is significant because it allows us to convert between moles and grams, a conversion that is essential in stoichiometry for analyzing chemical reactions and compositions. Understanding molar mass enables chemists to "weigh" atoms and molecules using macroscopic scales.
Calculating Mass Percentage
Mass percentage is a measure that denotes how much of a certain element is present in a compound relative to the total mass. This is extremely useful for understanding compound compositions and analyzing mixtures like ores. To find the mass percentage, you use the formula:
\[\text{Mass percentage} = \left(\frac{\text{mass of element}}{\text{total mass of compound}}\right) \times 100\]
In our exercise, after determining that 9.39 grams of lead (Pb) are present in a 53.92-gram sample of ore, we can calculate the mass percentage of lead in the sample:
  • Compute the ratio: \( \frac{9.39 \, \text{g}}{53.92 \, \text{g}} \)
  • Multiply by 100 to convert to percentage: \( 17.41\% \)
This high percentage of lead indicates that the ore is a relatively rich source of this element. Understanding this concept helps in material processing and economic considerations.
Net Ionic Equation Explained
A net ionic equation simplifies chemical reactions by showing only the reactive parts of compounds. It omits spectator ions that do not change during the reaction. This clarity is particularly useful in analyzing precipitation reactions, like the one in our problem.
The net ionic equation for the precipitation of lead(II) sulfate is:\[\text{Pb}^{2+}(aq) + \text{SO}_4^{2-}(aq) \rightarrow \text{PbSO}_4(s)\]
This equation indicates that aqueous lead ions \( \text{Pb}^{2+} \) react with sulfate ions \( \text{SO}_4^{2-} \) to form solid lead(II) sulfate \( \text{PbSO}_4 \).
  • Spectator ions, which are unchanged, are left out for simplicity.
  • It provides a concise description of the molecular changes occurring.
Net ionic equations are powerful tools for focusing on the essential chemical changes and are fundamental in studying reaction mechanisms, particularly those forming precipitates or involving redox processes.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Determine the mass of ammonium nitrate, \(\mathrm{NH}_{4} \mathrm{NO}_{3}(s)\), that has the same number of nitrogen atoms as \(2.0\) liters of liquid nitrogen, \(\mathrm{N}_{2}(l) .\) Take the density of liquid nitrogen to be \(0.808 \mathrm{~g} \cdot \mathrm{mL}^{-1}\).

Sodium reacts with anhydrous ammonia to produce sodium amide, \(\mathrm{NaNH}_{2}(s) .\) How many grams of sodium amide can be produced from \(10.0\) grams of sodium?

Naproxen sodium, \(\mathrm{C}_{14} \mathrm{H}_{13} \mathrm{O}_{3} \mathrm{Na}(s)\), the active ingredient in the pain reliever Aleve \(^{\circledast}\), is a nonsteroidal anti-inflammatory drug. Calculate the mass percentage of each of the elements in naproxen sodium to four significant figures and show that the sum of these mass percentages totals one hundred percent.

II-92. (*) A 30.450-milligram sample of a chemical known to contain only carbon, hydrogen, oxygen, and sulfur is put into a combustion analysis apparatus, yielding \(54.246\) milligrams of carbon dioxide and \(22.206\) milligrams of water. In another experiment, \(23.725\) milligrams of the compound is reacted with excess oxygen to produce \(10.255\) milligrams of sulfur dioxide. What is the empirical formula of the compound?

When analyzing the results of combustion analysis, we use the mass percentage of carbon in the \(\mathrm{CO}_{2}(g)\) produced to find the mass of carbon from our original sample and the mass percentage of hydrogen in the \(\mathrm{H}_{2} \mathrm{O}(g)\) produced to find the mass of hydrogen from our original sample. Why can't the same procedure be used to determine the mass of oxygen present in the original sample?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.