/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 9 How does the enthalpy change for... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

How does the enthalpy change for an endothermic reaction occurring at constant pressure?

Short Answer

Expert verified
The enthalpy change \( \Delta H \) is positive for an endothermic reaction at constant pressure.

Step by step solution

01

Understanding Enthalpy Change

Enthalpy change, denoted as \( \Delta H \), is the heat absorbed or released by a reaction at constant pressure. For a reaction occurring at constant pressure, \( \Delta H \) represents the flow of energy as heat. If \( \Delta H > 0 \), the reaction is endothermic, meaning that it absorbs heat from the surroundings.
02

Identify the Nature of the Reaction

In an endothermic reaction, heat is absorbed by the system from the surroundings. Therefore, the enthalpy change, \( \Delta H \), is positive. This indicates that the total enthalpy of the products is greater than the total enthalpy of the reactants.
03

Write the Mathematical Expression

Mathematically, for an endothermic reaction, the enthalpy change is expressed as \( \Delta H = H_{products} - H_{reactants} > 0 \), where \( H_{products} \) is the enthalpy of the products, and \( H_{reactants} \) is the enthalpy of the reactants.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Endothermic Reaction
An endothermic reaction is a chemical process in which energy is absorbed from its surroundings. This means that during the reaction, the environment gets cooler as the system takes in energy. This absorption of energy results in a positive enthalpy change, often represented in equations as \( \Delta H > 0 \).

In practical terms, you can think of endothermic reactions when you feel a cold pack start to chill when shaken or cracked—that's because the pack absorbs heat from your skin to cause the reaction.
  • An endothermic process needs to gain heat to proceed.
  • They are characterized by a positive enthalpy change \( (\Delta H) \).
  • Temperature of the surroundings usually decreases.
Understanding endothermic reactions is crucial in fields like chemistry, meteorology, and even biology, which rely on predicting and manipulating energy changes.
Constant Pressure
In many chemical reactions, constant pressure conditions are assumed to simplify the calculations. This is because most reactions conducted in open laboratories or natural conditions occur under atmospheric pressure, which remains fairly consistent.

Under such conditions, the change in the system’s heat content, known as enthalpy change \( \Delta H \), becomes especially relevant. When pressure is constant, any increase or decrease in heat directly affects enthalpy.
  • Enthalpy (\( H \)) is a measure of total energy of a thermodynamic system.
  • At constant pressure, enthalpy change aligns with heat exchange.
  • The term \( \Delta H \) specifically refers to changes at constant pressure.
Overall, studying reactions at constant pressure helps chemists understand energy exchanges without the added complexity of varying pressure, ensuring more predictable and readable results.
Heat Absorption
In endothermic reactions, heat absorption is a key aspect. It implies that the chemical system is taking in energy from its environment, disrupting the existing thermal equilibrium. This process can be quantified by measuring the enthalpy change \( \Delta H \).

When a reaction absorbs heat, the \( \Delta H \) value is positive. This indicates that energy is required for the reaction to take place. In cases where the reaction is endothermic, the products end up with more energy than the reactants had initially.
  • Heat absorption results in a positive \( \Delta H \).
  • It is a defining feature of endothermic reactions.
  • Helps understand the energy requirements of reactions.
The concept of heat absorption is fundamental in areas such as chemical engineering and environmental science, where controlling the energy exchange of reactions is crucial.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

What is a fuel? What are the fossil fuels?

6.44 Hydrogen sulfide, \(\mathrm{H}_{2} \mathrm{~S}\), is produced during decomposition of organic matter. When \(0.5000 \mathrm{~mol} \mathrm{H}_{2} \mathrm{~S}\) burns to produce \(\mathrm{SO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(l),-281.0 \mathrm{~kJ}\) of heat is released. What is this heat in kilocalories?

A \(29.1-\mathrm{mL}\) sample of \(1.05 \mathrm{M} \mathrm{KOH}\) is mixed with \(20.9 \mathrm{~mL}\) of \(1.07 M \mathrm{HBr}\) in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is \(-55.8 \mathrm{~kJ}\). Both solutions are at \(21.8^{\circ} \mathrm{C}\) prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is \(1.00 \mathrm{~g} / \mathrm{mL},\) and volumes are additive.

Suppose you mix \(19.8 \mathrm{~g}\) of water at \(80.0^{\circ} \mathrm{C}\) with \(54.7 \mathrm{~g}\) of water at \(29.0^{\circ} \mathrm{C}\) in an insulated cup. What is the maximum temperature of the water after mixing?

Colorless nitric oxide, NO, combines with oxygen to form nitrogen dioxide, \(\mathrm{NO}_{2},\) a brown gas. $$ 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{NO}_{2}(g) ; \Delta H=-114 \mathrm{~kJ} $$ What is the enthalpy change per gram of nitric oxide?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.