/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 68 Ethanol, \(\mathrm{C}_{2} \mathr... [FREE SOLUTION] | 91Ó°ÊÓ

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Ethanol, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH},\) is mixed with gasoline and sold as gasohol. Use the following to calculate the grams of ethanol needed to provide \(429 \mathrm{~kJ}\) of heat. $$ \begin{array}{c} \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l)+3 \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{CO}_{2}(g)+3 \mathrm{H}_{2} \mathrm{O}(g) ; \\ \Delta H=-1235 \mathrm{~kJ} \end{array} $$

Short Answer

Expert verified
16.0 grams of ethanol are required.

Step by step solution

01

Understand the Reaction

The combustion of ethanol is given by the equation \( \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l) + 3 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{CO}_{2}(g) + 3 \mathrm{H}_{2} \mathrm{O}(g) \) with \( \Delta H = -1235 \mathrm{~kJ} \). This means that 1235 kJ of energy is released per mole of ethanol combusted.
02

Calculate the Moles of Ethanol Needed

To find the grams of ethanol required, we first determine how many moles of ethanol are needed to provide 429 kJ of heat. Given that 1235 kJ is released by 1 mole, the equation \( n \times 1235 = 429 \) allows us to calculate the moles \( n \). Solving gives \( n = \frac{429}{1235} \approx 0.347 \) moles.
03

Find the Molar Mass of Ethanol

The molar mass of ethanol \( \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH} \) is calculated by adding the atomic masses: \( 2 \times 12.01 + 6 \times 1.008 + 16.00 = 46.08 \ \text{g/mol} \).
04

Calculate the Mass of Ethanol

Using the moles needed (0.347 moles) and the molar mass (46.08 g/mol), the mass of ethanol is calculated by \( 0.347 \times 46.08 = 15.98 \ \text{g} \approx 16.0 \ \text{g} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Thermodynamics
Thermodynamics is the branch of physics that deals with the relationships between heat and other forms of energy. It explains how energy is transferred in physical and chemical processes. In the context of the enthalpy of combustion, thermodynamics helps us understand how much heat energy is released during a chemical reaction. In the exercise, we deal with the combustion of ethanol, a common process in everyday life when we use fuel for energy.

When ethanol combusts, it releases energy. The energy change for this reaction, known as the enthalpy change, is given by \( \Delta H = -1235 \ \text{kJ} \). This negative value shows that the reaction releases energy to the atmosphere, making it an exothermic process.

Understanding how much heat a reaction produces is essential in predicting the behavior of chemical systems. It helps in designing engines, heating systems, and even industrial processes. Knowing that ethanol releases this specified amount of energy per mole allows us to calculate how much of another substance is needed to achieve a desired amount of energy through combustion.
Stoichiometry
Stoichiometry is a critical concept in chemistry that involves calculating the quantities of reactants and products in chemical reactions. It helps chemists and students predict how much of each ingredient is needed for a reaction to occur. In the exercise, stoichiometry is applied to find out how many grams of ethanol are necessary to produce a certain amount of heat energy.

The given chemical reaction for ethanol combustion is \( \text{C}_2\text{H}_5\text{OH}(l) + 3 \text{O}_2(g) \rightarrow 2 \text{CO}_2(g) + 3 \text{H}_2\text{O}(g) \). Using this balanced equation, stoichiometry helps us convert between moles of ethanol and the energy produced.
  • The change in enthalpy (\
Thermodynamics
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