Chapter 4: Problem 28
If one mole of the following compounds were each placed into separate beakers containing the same amount of water, rank the \(\mathrm{Cl}^{-}(a q)\) concentrations from highest to lowest (some may be equivalent): \(\mathrm{KCl}, \mathrm{AlCl}_{3}, \mathrm{PbCl}_{2}, \mathrm{NaCl}\) \(\mathrm{HCl}, \mathrm{NH}_{3}, \mathrm{KOH},\) and \(\mathrm{HCN}\)
Short Answer
Step by step solution
Identifying Ionic Substances
Determining Dissociation in Water
Calculating Chloride Ion Contribution
Ranking the Concentrations
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ionic Dissociation
When we consider a compound like KCl (potassium chloride), it dissociates into potassium ions (\( \mathrm{K}^+ \)) and chloride ions (\( \mathrm{Cl}^- \)) when placed in water. Each mole of KCl will yield one mole of chloride ions due to its simple 1:1 ratio.
Similarly, when NaCl (sodium chloride) is dissolved, it also separates into \( \mathrm{Na}^+ \) and \( \mathrm{Cl}^- \) ions. Compounds like AlCl鈧 (aluminum chloride) are interesting because they produce three moles of chloride ions for each mole of the compound that dissociates, due to its formula of one aluminum ion to three chloride ions.
However, some compounds, such as PbCl鈧 (lead(II) chloride), do not fully dissolve. While they will dissociate, they have low solubility in water, meaning not all of the compound dissolves, resulting in fewer ions available in solution.
Solubility
Highly soluble compounds like KCl, NaCl, and AlCl鈧 readily dissolve in water, fully dissociating into their respective ions. This means they have a high solubility, allowing them to contribute greatly to the chloride ion concentration in a solution.
- KCl, NaCl, and AlCl鈧 fully dissociate, contributing significantly to the chloride ion concentration.
- HCl (hydrochloric acid), although sometimes not considered a typical salt, ionizes completely in water to release hydrogen and chloride ions, adding to the chloride ion pool.
Chemical Compounds
An ionic compound such as AlCl鈧 has more intricate chemical behavior due to its crystalline structure and the presence of metal and non-metal ions. The chemical composition determines how these compounds interact with water, leading to ionic dissociation.
On the contrary, NH鈧, and HCN do not provide chloride ions as they lack the Cl鈦 group in their structure. NH鈧 is a covalent compound that doesn鈥檛 produce ions in the same manner and primarily affects the solution's properties through interactions, not by contributing to ion concentration. Understanding these interactions is key to predicting the outcomes when different compounds are mixed with water.
Aqueous Solutions
When compounds like NaCl or HCl are added to water, they break apart into their component ions, each ion interacting with water molecules. This makes the ions available for potential chemical reactions.
- Water's exceptional ability to solvate ions is what allows solutions to conduct electricity could bring significant industrial and laboratory applications.
- In contrast, compounds that do not dissociate, like NH鈧, remain mostly in their molecular form, performing differently in an aqueous environment.