/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 8 How would you prepare \(500 \mat... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

How would you prepare \(500 \mathrm{~mL}\) of (a) \(0.200 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) from a reagent that has a density of \(1.1539 \mathrm{~g} / \mathrm{mL}\) and is \(21.8 \% \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{w} / \mathrm{w})\) ? (b) \(0.250 \mathrm{M} \mathrm{NaOH}\) from the solid? (c) \(0.07500 \mathrm{M} \mathrm{Na}_{2} \mathrm{CO}_{3}\) from the pure solid?

Short Answer

Expert verified
H2SO4: Use 39.06 mL reagent; NaOH: Dissolve 5 g; Na2CO3: Dissolve 3.975 g.

Step by step solution

01

Calculate the initial moles required

To prepare the solution, we first need to determine the number of moles needed for each solution. For H2SO4 (a), calculate the moles using Molarity formula: \( ext{moles} = M \times V = 0.200 \times 0.5 = 0.1 \text{ moles}\). For NaOH (b), \( ext{moles} = 0.250 \times 0.5 = 0.125 \text{ moles}\). For Na2CO3 (c), \( ext{moles} = 0.07500 \times 0.5 = 0.0375 \text{ moles}\).
02

Calculate the volume or mass needed from the reagent or solid

For H2SO4 solution (a), we first find mass \( m = V \times \text{density} \) of the stock solution to determine H2SO4 moles. The stock has 21.8% w/w, so: \( m = 500 \text{ mL} \times 1.1539 \text{ g/mL} = 576.95 \text{ g} \) and mass of H2SO4 is \( 576.95 \times 0.218 = 125.7781 \text{ g}\). Moles are \( \frac{125.7781}{98.079} \approx 1.2826 \text{ moles} \).

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molarity
Molarity is a core concept in chemistry dealing with the concentration of solutions. It defines the number of moles of solute present in a liter of solution. The formula for molarity (\( M \)) is given by \[ M = \frac{n}{V} \] where \( n \) is the number of moles of solute and \( V \) is the volume of the solution in liters. Understanding molarity is crucial because it allows chemists to express the concentration of a solution precisely, which is essential for reactions and experiments.In the context of solution preparation, molarity helps in determining the exact amount of solute required to achieve a specific concentration. For example, when asked to prepare 500 mL of a 0.2 M sulfuric acid solution, the molarity formula helps us calculate that we need 0.1 moles of \( \text{H}_2\text{SO}_4 \), as shown in the original exercise. This calculation is critical for ensuring that the solution has the desired properties.
Concentration Calculations
Concentration calculations entail discerning the amount of solute in a given amount of solvent or solution, often expressed in percentage, molarity, or molality. Concentration is vital as it influences the reactivity and properties of chemical mixtures. For example, in the given exercise, various units of concentration are used, such as molarity and weight/weight percentage.When dealing with the reagent stock solution described in the exercise, where the sulfuric acid has a density and percentage in \( w/w \), it is important to first calculate the mass of the entire solution. By multiplying the density (1.1539 g/mL) by the volume (500 mL), we find the mass of the solution. The percentage allows conversion to mass of sulfuric acid, achieved by multiplying the total mass by the percentage as a fraction.For solid NaOH and \( \text{Na}_2\text{CO}_3 \), using the moles calculated initially, we convert these to grams using the molar mass. This showcases how concentration calculations ensure that only the exact amount of NaOH or \( \text{Na}_2\text{CO}_3 \) needed to achieve the desired molarity is used.
Acid-Base Chemistry
Acid-base chemistry is a fundamental area of chemistry dealing with acids, bases, their reactions, and their role in solution concentration preparation. This type of chemistry defines acids as proton donors and bases as proton acceptors. The exercise involves solutions of both acidic (sulfuric acid \( \text{H}_2\text{SO}_4 \)) and basic (sodium hydroxide \( \text{NaOH} \), sodium carbonate \( \text{Na}_2\text{CO}_3 \)) substances.In preparing solutions of these substances, understanding their dissociation in water is key. For \( \text{H}_2\text{SO}_4 \), a strong acid, it fully dissociates providing protons which can react with bases. Meanwhile, \( \text{NaOH} \) is a strong base, completely dissociating to release \( \text{OH}^- \) ions.Handling acids and bases in solution requires caution since the dissociation can be exothermic, meaning it releases heat. This necessitates careful measuring and gradual mixing as a safety measure. A thorough understanding of acid-base chemistry aids in anticipating the behavior of these substances once in solution, ensuring safety and accuracy in laboratory settings.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

A dilute solution of an unknown weak acid required a 28.62-mL titration with \(0.1084 \mathrm{M} \mathrm{NaOH}\) to reach a phenolphthalein end point. The titrated solution was evaporated to dryness. Calculate the equivalent mass of the acid if the sodium salt was found to weigh \(0.2110 \mathrm{~g}\).

The formaldehyde content of a pesticide preparation was determined by weighing \(0.2985 \mathrm{~g}\) of the liquid sample into a flask containing \(50.0 \mathrm{~mL}\) of \(0.0959 \mathrm{M} \mathrm{NaOH}\) and \(50 \mathrm{~mL}\) of \(3 \% \mathrm{H}_{2} \mathrm{O}_{2}\). Upon heating, the following reaction took place: $$ \mathrm{OH}^{-}+\mathrm{HCHO}+\mathrm{H}_{2} \mathrm{O}_{2} \rightarrow \mathrm{HCOO}^{-}+2 \mathrm{H}_{2} \mathrm{O} $$ After cooling, the excess base was titrated with \(22.71 \mathrm{~mL}\) of \(0.053700 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\). Calculate the percentage of \(\mathrm{HCHO}(30.026 \mathrm{~g} / \mathrm{mol})\) in the sample.

A 0.1401-g sample of a purified carbonate was dissolved in \(50.00 \mathrm{~mL}\) of \(0.1140 \mathrm{M} \mathrm{HCl}\) and boiled to eliminate \(\mathrm{CO}_{2}\). Back-titration of the excess \(\mathrm{HCl}\) required \(24.21 \mathrm{~mL}\) of \(0.09802 \mathrm{M} \mathrm{NaOH}\). Identify the carbonate.

Define the equivalent mass of (a) an acid and (b) a base.

Briefly describe the circumstance where the concentration of a sodium hydroxide solution will apparently be unaffected by the absorption of carbon dioxide.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.