Chapter 16: Problem 46
Define the equivalent mass of (a) an acid and (b) a base.
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Chapter 16: Problem 46
Define the equivalent mass of (a) an acid and (b) a base.
These are the key concepts you need to understand to accurately answer the question.
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A \(1.217-\mathrm{g}\) sample of commercial KOH contaminated by \(\mathrm{K}_{2} \mathrm{CO}_{3}\) was dissolved in water, and the resulting solution was diluted to \(500.0 \mathrm{~mL}\). A \(50.00-\mathrm{mL}\) aliquot of this solution was treated with \(40.00 \mathrm{~mL}\) of \(0.05304 \mathrm{M}\) \(\mathrm{HCl}\) and boiled to remove \(\mathrm{CO}_{2}\). The excess acid consumed \(4.74 \mathrm{~mL}\) of \(0.04983 \mathrm{M} \mathrm{NaOH}\) (phenolphthalein indicator). An excess of neutral \(\mathrm{BaCl}_{2}\) was added to another \(50.00-\mathrm{mL}\) aliquot to precipitate the carbonate as \(\mathrm{BaCO}_{3}\). The solution was then titrated with \(28.56 \mathrm{~mL}\) of the acid to a phenolphthalein end point. Calculate the percentage \(\mathrm{KOH}, \mathrm{K}_{2} \mathrm{CO}_{3}\), and \(\mathrm{H}_{2} \mathrm{O}\) in the sample, assuming that these are the only compounds present.
The digestion of a 0.1417-g sample of a phosphoru: containing compound in a mixture of \(\mathrm{HNO}_{3}\) an \(\mathrm{H}_{2} \mathrm{SO}_{4}\) resulted in the formation of \(\mathrm{CO}_{2}, \mathrm{H}_{2} \mathrm{O}\), an \(\mathrm{H}_{3} \mathrm{PO}_{4}\). Addition of ammonium molybdate yielded solid having the composition \(\left(\mathrm{NH}_{4}\right)_{3} \mathrm{PO}_{4} \cdot 12 \mathrm{MoC}\) (1876.3 \(\mathrm{g} / \mathrm{mol}\) ). This precipitate was filtered, washed and dissolved in \(50.00 \mathrm{~mL}\) of \(0.2000 \mathrm{M} \mathrm{NaOH}\) : $$ \begin{gathered} \left(\mathrm{NH}_{4}\right)_{3} \mathrm{PO}_{4} \cdot 12 \mathrm{MoO}_{3}(s)+26 \mathrm{OH}^{-} \rightarrow \mathrm{HPO}_{4}^{2-} \\ +12 \mathrm{MoO}_{4}^{2-}+14 \mathrm{H}_{2} \mathrm{O}+3 \mathrm{NH}_{3}(g) \end{gathered} $$ After the solution was boiled to remove the \(\mathrm{NH}_{3}\), the excess \(\mathrm{NaOH}\) was titrated with \(14.17 \mathrm{~mL}\) of \(0.1741 \mathrm{M} \mathrm{HCl}\) to a phenolphthalein end point. Calculate the percentage of phosphorus in the sample.
A dilute solution of an unknown weak acid required a 28.62-mL titration with \(0.1084 \mathrm{M} \mathrm{NaOH}\) to reach a phenolphthalein end point. The titrated solution was evaporated to dryness. Calculate the equivalent mass of the acid if the sodium salt was found to weigh \(0.2110 \mathrm{~g}\).
How would you prepare \(500 \mathrm{~mL}\) of (a) \(0.200 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) from a reagent that has a density of \(1.1539 \mathrm{~g} / \mathrm{mL}\) and is \(21.8 \% \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{w} / \mathrm{w})\) ? (b) \(0.250 \mathrm{M} \mathrm{NaOH}\) from the solid? (c) \(0.07500 \mathrm{M} \mathrm{Na}_{2} \mathrm{CO}_{3}\) from the pure solid?
A \(0.5000-\mathrm{g}\) sample containing \(\mathrm{NaHCO}_{3}, \mathrm{Na}_{2} \mathrm{CO}_{3}\), and \(\mathrm{H}_{2} \mathrm{O}\) was dissolved and diluted to \(250.0 \mathrm{~mL}\). A \(25.00-\mathrm{mL}\) aliquot was then boiled with \(50.00 \mathrm{~mL}\) of \(0.01255 \mathrm{M} \mathrm{HCl}\). After cooling, the excess acid in the solution required \(2.34 \mathrm{~mL}\) of \(0.01063 \mathrm{M} \mathrm{NaOH}\) when titrated to a phenolphthalein end point. A second \(25.00-\mathrm{mL}\) aliquot was then treated with an excess of \(\mathrm{BaCl}_{2}\) and \(25.00 \mathrm{~mL}\) of the base. All the carbonate precipitated, and \(7.63 \mathrm{~mL}\) of the \(\mathrm{HCl}\) was required to titrate the excess base. Determine the composition of the mixture.
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