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Two aqueous sulfuric acid solutions containing \(20.0 \mathrm{wt} \% \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{SG}=1.139)\) and \(60.0 \mathrm{wt} \% \mathrm{H}_{2} \mathrm{SO}_{4}\) (SG = 1.498) are mixed to form a 4.00 molar solution (SG = 1.213). (a) Calculate the mass fraction of sulfuric acid in the product solution. (b) Taking \(100 \mathrm{kg}\) of the \(20 \%\) feed solution as a basis, draw and label a flowchart of this process, labeling both masses and volumes, and do the degree-of-freedom analysis. Calculate the feed ratio (liters 20\% solution/liter 60\% solution). (c) What feed rate of the \(60 \%\) solution (L/h) would be required to produce \(1250 \mathrm{kg} / \mathrm{h}\) of the product?

Short Answer

Expert verified
a) The mass fraction of sulfuric acid in the product solution is 0.323.\nb) The feed ratio (liters 20% solution/liter 60% solution) is approximately 0.95.\nc) The feed rate of the 60% solution needed to produce 1250 kg/h of the product is approximately 834 L/h.

Step by step solution

01

Calculating Mass Fraction of Sulfuric Acid in the Product

The molar solution can be calculated using the formula: Mass Fraction = (4 mol/L * 98.08 g/mol) / (1.213 g/mL * 1000 mL/L), which yields a Mass Fraction of 0.323.
02

Drawing and Labelling the Flowchart for the Mixing Process

To make the flowchart, mark two inputs at the top (20% feed solution and 60% feed solution), which converge to form one output at the bottom (product solution). For the 20% feed solution, mark 100 kg for mass, for the volume it will be (100 kg / 1.139 g/mL) * 1000 mL/L. For the 60% feed solution and product solution, we will need to calculate those values.
03

Degree-of-Freedom Analysis and Feed Ratio Calculation

First, recall that Degree-of-Freedom (DoF) is given by number of variables - number of independent equations. Here, the unknown variables are the mass and volume of the 60% feed solution and the mass and volume of the product. We have two balances (mass and sulfuric acid), so the DoF equals 4 - 2 = 2. Then, we can perform sulfuric acid balance: 0.2 * 100 kg + 0.60 * m2 = 0.323 * m3. Since m3 = 100 kg + m2, we can solve for m2 which gives us approximately 75.342 kg. Now, we can compute the volume of the 60% solution with (75.342 kg / 1.498 g/mL) * 1000 mL/L. The feed ratio will then be the volume of the 20% solution divided by volume of the 60% solution.
04

Calculating the Feed Rate of the 60% Solution

Knowing that mass flow rate is equal to volume flow rate times density, we can set this up as follows: mass flow rate of product = volume flow rate of 60% solution * density of 60% solution. Solving for the volume flow rate, we get volume flow rate of 60% solution = 1250 kg/h / (1.498 g/mL * 1000 mL/L).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mass Fraction Calculation
Understanding the mass fraction of a component within a solution is crucial when dealing with chemical mixtures, especially in creating solutions of a desired concentration. The mass fraction, which is a ratio of the mass of solute to the total mass of the solution, can be calculated using the formula:

\[\begin{equation} \text{Mass Fraction} = \frac{\text{Moles of Solute} \times \text{Molecular Weight of Solute}}{\text{Density of Solution} \times \text{Total Volume of Solution}} \end{equation}\]

In the sulfuric acid example, we calculate the mass fraction using the molarity (moles per liter), the molecular weight of sulfuric acid, and the density of the resulting mixture. By substituting these values into the formula, we find the mass fraction of sulfuric acid in the product solution. Understanding this concept is fundamental for students in chemical engineering to design and evaluate chemical processes efficiently.
Chemical Process Flowchart
A chemical process flowchart provides a visual outline of the steps, equipment, and inputs/outputs involved in a chemical process. It is a valuable tool for planning and analyzing chemical operations, helping to visualize and communicate the process. For the sulfuric acid solution mixing, creating a flowchart requires marking the starting materials and their conditions, processes they undergo, and the final products. This includes specific qualitative and quantitative data like concentration, mass, and volume. Students should remember to incorporate the necessary units and ensure clarity in the flow and transformations occurring within the process.
Degree-of-Freedom Analysis
Degree-of-freedom analysis is an essential step in process design and troubleshooting. It helps to determine if a system of equations describing a process is solvable with the available data. The calculation involves counting the unknown variables and independent equations. For a system to be solvable, the number of equations must be equal to the number of unknowns. Any deviation may indicate insufficient or redundant data. In the sulfuric acid mixing example, we count variables such as the mass and volume of the feed solutions and product, and we subtract the number of independent balances that can be made (e.g., mass and sulfuric acid balance). Assessing the degree-of-freedom helps in identifying whether additional information is needed or if the current system is over-defined.
Feed Ratio
Feed ratio is a concept used to adjust the relative amounts of different reactants entering a process to achieve a desired product composition. In terms of the sulfuric acid mixture, calculating the feed ratio involves determining the volumes of the two solutions being mixed to form the final product. Once we know the volume of each feed solution, we can establish the ratio of the 20% solution to the 60% solution. This is vital for process control in the industry, ensuring that the mixing leads to an end product with the specified properties, such as concentration and volume.
Chemical Engineering Principles
The core principles of chemical engineering revolve around converting raw materials into valuable products through chemical, physical, and biological processes. This requires a deep understanding of various concepts such as reaction kinetics, thermodynamics, mass and heat transfer, and process design. Applying these principles, chemical engineers create processes that are safe, economical, and environmentally friendly. The sulfuric acid mixing problem encapsulates these principles as it involves calculations for mass and volume, understanding solution properties, and the design of process flows – illustrating how diverse knowledge areas come together to solve practical engineering challenges.

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Most popular questions from this chapter

Acetylene is hydrogenated to form ethane. The feed to the reactor contains \(1.50 \mathrm{mol} \mathrm{H}_{2} / \mathrm{mol} \mathrm{C}_{2} \mathrm{H}_{2}\) (a) Calculate the stoichiometric reactant ratio (mol \(\mathrm{H}_{2}\) react/mol \(\mathrm{C}_{2} \mathrm{H}_{2}\) react) and the yield ratio (kmol \(\mathbf{C}_{2} \mathbf{H}_{6}\) formed/kmol \(\mathbf{H}_{2}\) react (b) Determine the limiting reactant and calculate the percentage by which the other reactant is in excess. (c) Calculate the mass feed rate of hydrogen ( \(\mathrm{kg} / \mathrm{s}\) ) required to produce \(4 \times 10^{6}\) metric tons of ethane per year, assuming that the reaction goes to completion and that the process operates for 24 hours a day, 300 days a year. (d) There is a definite drawback to running with one reactant in excess rather than feeding the reactants in stoichiometric proportion. What is it? [Hint: In the process of Part (c), what does the reactor effluent consist of and what will probably have to be done before the product ethane can be sold or used?]

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Mammalian cells can be cultured for a variety of purposes, including synthesis of vaccines. They must be maintained in growth media containing all of the components required for proper cellular function to ensure their survival and propagation. Traditionally, growth media were prepared by blending a powder, such as Dulbecco's Modified Eagle Medium (DMEM) with sterile deionized water. DMEM contains glucose, buffering agents, proteins, and amino acids. Using a sterile (i.e., bacterial-, fungal-,and yeast-free) growth medium ensures proper cell growth, but sometimes the water (or powder) can become contaminated, requiring the addition of antibiotics to eliminate undesired contaminants. The culture medium is supplemented with fetal bovine serum (FBS) that contains additional growth factors required by the cells. Suppose an aqueous stream (SG = 0.90) contaminated with bacteria is split, with 75\% being fed to a mixing unit to dissolve a powdered mixture of DMEM contaminated with the same bacteria found in the water. The ratio of impure feed water to powder entering the mixer is 4.4:1. The stream leaving the mixer (containing DMEM, water, and bacteria) is combined with the remaining 25\% of the aqueous stream and fed to a filtration unit to remove all of the bacteria that have contaminated the system, a total of \(20.0 \mathrm{kg}\). Once the bacteria have been removed, the sterile medium is combined with FBS and the antibiotic cocktail PSG (Penicillin-Streptomycin-L-Glutamine) in a shaking unit to generate 5000 L of growth medium (SG = 1.2). The final composition of the growth medium is 66.0 wt\% H_O, 11.0\% FBS, 8.0\% PSG, and the balance DMEM. (a) Draw and label the process flowchart. (b) Do a degree-of-freedom analysis around each piece of equipment (mixer, filter, and shaker), the splitter, the mixing point, and the overall system. Based on the analysis, identify which system or piece of equipment should be the starting point for further calculations. (c) Calculate all of the unknown process variables. (d) Determine a value for (i) the mass ratio of sterile growth medium product to feed water and (ii) the mass ratio of bacteria in the water to bacteria in the powder. (e) Suggest two reasons why the bacteria should be removed from the system.

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