/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 16 A fuel distributor supplies four... [FREE SOLUTION] | 91Ó°ÊÓ

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A fuel distributor supplies four liquid fuels, each of which has a different ratio of ethanol to gasoline. Five percent of the demand is for E100 (pure ethanol), 15\% for E85 (85.0 volume\% ethanol), 40\% for E10 (10.0\% ethanol), and the remainder for pure gasoline. The distributor blends gasoline and ethanol to produce E85 and E10, and the four products are produced continuously. (a) Draw and label a flowchart for the blending operation, letting \(\dot{V}\) represent the combined volumetric flow rate of all four fuels and \(\dot{V}_{\mathrm{G}}\) and \(\dot{V}_{\mathrm{E}}\) represent the volumetric flow rates of gasoline and ethanol sold as fuels and sent to the blending operation. (b) Assuming volume additivity when blending ethanol and gasoline, determine the volumetric flow rates of all streams when delivery of 100,000 L/d of \(\mathrm{E} 10\) is specified. (c) Tank trucks are to transport the fuel from the blending operation to service stations in the area. The gross weight of a loaded truck, which has a tare (empty) weight of \(12,700 \mathrm{kg}\), cannot exceed \(36,000 \mathrm{kg} .\) Assuming the specific gravity of pure gasoline is \(0.73,\) estimate the maximum volume (L) of each fuel that can be loaded onto a truck.

Short Answer

Expert verified
The total volumetric flow rate \(\dot{V}\) is 250,000 L/d: 12,500 L/d for E100, 37,500 L/d for E85, 100,000 L/d for E10, and 100,000 L/d for pure gasoline. The maximum volume that can be loaded onto a truck is 31,918 L if it is pure gasoline.

Step by step solution

01

Drawing and Labeling the Flowchart

The first step involves creating a flowchart for the process. Draw two initial inputs representing gasoline (\(\dot{V}_{\mathrm{G}}\)) and ethanol (\(\dot{V}_{\mathrm{E}}\)). Both of these inputs flow into two blending operations where E85 and E10 fuels are formed. The E85 and E10 fuels, along with E100 and pure gasoline, form four output streams, each representing the various fuels. The total cumulative flow from these four streams is represented as \(\dot{V}\).
02

Determining the Volumetric Flow Rates

Given that the delivery of 100,000 L/d of E10 is specified, and that the demand for E10 is 40% of the total demand, we can calculate the total demand (\(\dot{V}\)) as 100,000 * (100/40) = 250,000 L/d. Using the percentages given in the problem for E100 (5%), E85 (15%), and pure gasoline (the remainder), we can calculate the volumetric flow rates for these as 5% of 250,000 = 12,500 L/d (E100), 15% of 250,000 = 37,500 L/d (E85), and the remainder, which equals 250,000 - 100,000 (E10) - 12,500 (E100) - 37,500 (E85) = 100,000 L/d (pure gasoline). The amount of ethanol for blending (E10 and E85) is (0.85 * 37,500 (ethanol in E85) + 0.10 * 100,000 (ethanol in E10)) = 41,750 L/d, and the amount of gasoline for blending is (0.15 * 37,500 (gasoline in E85) + 0.90 * 100,000 (gasoline in E10)) = 105,625 L/d.
03

Estimating Maximum Volume for Transportation

A loaded truck's gross weight must not exceed 36,000 kg, and the truck's empty weight is 12,700 kg, meaning it can carry a maximum of 36,000 - 12,700 = 23,300 kg of fuel. Given that the specific gravity of gasoline is 0.73, and knowing that the specific gravity is the ratio of the substance's density to that of water (roughly 1,000 kg/m3), the maximum volume of pure gasoline that can be loaded onto a truck is 23,300 / (0.73 * 1,000) = 31,918 L. For the ethanol blends, the specific gravity will be different, so for any ethanol blend, it would be necessary to know its specific gravity to perform a similar calculation.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Fuel Blending Operations
Fuel blending is a critical process in the petrochemical industry, where different types of fuels are combined to create products that meet specific quality and regulatory standards. In the context of the textbook exercise, the distributor is blending ethanol and gasoline to produce different ethanol blends: E100, E85, E10, and pure gasoline. Each blend has a specific ratio of ethanol to gasoline, tailored to satisfy various market demands.

For educational clarity, imagine the blending operations taking place in a large facility where ethanol and gasoline are stored in separate tanks. Pipes channel these two raw materials into mixing units, where they are combined in predetermined proportions. The E100 is pure ethanol and requires no blending, whereas E85 and E10 require precise volumes of ethanol and gasoline to achieve 85% and 10% ethanol content, respectively. This process is continuous, reflecting the constant demand for these fuel products in the market.

Understanding this blending operation is essential for students, as it encompasses principles of both chemistry and engineering. It demonstrates the application of volumetric concepts and the consideration of the properties of substances, such as specific gravity, when combining them. It also reflects real-world practices and economic factors that drive the operations in fuel production industries.
Volumetric Flow Rates Calculation
Calculating volumetric flow rates is a foundational skill in chemical engineering, essential for designing and optimizing processes like the fuel blending operation featured in the exercise. The volumetric flow rate, denoted by \( \dot{V} \), represents the volume of a fluid passing through a given point per unit time. In our example, the volumetric flow rates of gasoline \( \dot{V}_{\mathrm{G}} \) and ethanol \( \dot{V}_{\mathrm{E}} \) must be calculated to understand the production rates and requirements for the blending operation.

To solve for these rates, one starts by determining the total demand for the fuel, based on the specified output of one of the products—in this case, E10. Using proportionality, if E10 represents 40% of the total demand, you can calculate the total volume demand and then derive the volumetric rates for the other products based on their market share percentages. Volume additivity, the assumption that the volumes of mixed substances will sum up without volume change, allows for straightforward calculations of individual stream rates.

Students must grasp this concept to solve various chemical process problems accurately. Knowing how to calculate volumetric flow rates equips future engineers with tools to design processes, forecast resource needs, and ensure that production meets demand efficiently.
Transportation Constraints in Chemical Processes
The transportation of chemicals—including fuels—is governed by multiple constraints to ensure safety, efficiency, and compliance with regulations. The textbook exercise highlights a practical transportation constraint related to the weight capacity of a delivery truck. This constraint dictates the maximum volume of fuel that can be transported in a single trip, considering the vehicle's maximum allowable gross weight and the tare weight.

In chemical engineering education, students learn that understanding transportation constraints is just as important as mastering production processes. For example, the specific gravity of a substance, which compares its density to that of water, must be taken into account when determining the maximum transportable volume to avoid surpassing weight limits.

When dealing with chemicals of different densities, this becomes a critical factor. Since ethanol is less dense than gasoline, trucks can carry a larger volume of pure ethanol than gasoline before reaching the weight limit. This exercise compels students to apply their knowledge of physical properties like specific gravity and density to resolve real-world logistical challenges in the transport and delivery of chemical products.

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Most popular questions from this chapter

The hormone estrogen is produced in the ovaries of females and elsewhere in the body in men and postmenopausal women, and it is also administered in estrogen replacement therapy, a common treatment for women who have undergone a hysterectomy. Unfortunately, it also binds to estrogen receptors in breast tissue and can activate cells to become cancerous. Tamoxifen is a drug that also binds to estrogen receptors but does not activate cells, in effect blocking the receptors from access to estrogen and inhibiting the growth of breast-cancer cells. Tamoxifen is administered in tablet form. In the manufacturing process, a finely ground powder contains tamoxifen (tam) and two inactive fillers- -lactose monohydrate (lac) and corn starch (cs). The powder is mixed with a second stream containing water and suspended solid particles of polyvinylpymolidone (pvp) binder, which keeps the tablets from easily crumbling. The slurry leaving the mixer goes to a dryer, in which 94.2\% of the water fed to the process is vaporized. The wet powder leaving the dryer contains 8.80 wr\% tam, 66.8\% lac, 21.4\% cs, 2.00\% pvp, and 1.00\% water. After some additional processing, the powder is molded into tablets. To produce a hundred thousand tablets, 17.13 kg of wet powder is required. (a) Taking a basis of 100,000 tablets produced, draw and label a process flowchart, labeling masses of individual components rather than total masses and component mass fractions. It is unnecessary to label the stream between the mixer and the dryer. Carry out a degree-of-freedom analysis of the overall two-unit process. (b) Calculate the masses and compositions of the streams that must enter the mixer to make 100,000 tablets. (c) Why was it unnecessary to label the stream between the mixer and the dryer? Under what circumstances would it have been necessary? (d) Go back to the flowchart of Part (a). Without using the mass of the wet powder (17.13 kg) or any of the results from Part (b) in your calculations, determine the mass fractions of the stream components in the powder fed to the mixer and verify that they match your solution to Part (b). (Hint: Take a basis of \(100 \mathrm{kg}\) of wet powder.) (e) Suppose a student does Part (d) before Part (b), and re-labels the powder feed to the mixer on the flowchart of Part (a) with an unknown total mass ( \(m_{1}\) ) and the three now known mole fractions. (Sketch the resulting flowchart.) The student then does a degree-of-freedom analysis, counts four unknowns (the masses of the powder, pvp, and water fed to the mixer, and the mass of water evaporated in the dryer), and six equations (five material balances for five species and the percentage evaporation), for a net of -2 degrees of freedom. since there are more equations than unknowns, it should not be possible to get a unique solution for the four unknowns. Nevertheless, the student writes four equations, solves for the four unknowns, and verifies that all of the balance equations are satisfied. There must have been a mistake in the degree-of-freedom calculation. What was it?

One thousand kilograms per hour of a mixture containing equal parts by mass of methanol and water is distilled. Product streams leave the top and the bottom of the distillation column. The flow rate of the bottom stream is measured and found to be \(673 \mathrm{kg} / \mathrm{h}\), and the overhead stream is analyzed and found to contain 96.0 wt\% methanol. (a) Draw and label a flowchart of the process and do the degree-of-freedom analysis. (b) Calculate the mass and mole fractions of methanol and the molar flow rates of methanol and water in the bottom product stream. (c) Suppose the bottom product stream is analyzed and the mole fraction of methanol is found to be significantly higher than the value calculated in Part (b). List as many possible reasons for the discrepancy as you can think of. Include in your list possible violations of assumptions made in Part (b).

A \(100 \mathrm{kmol} / \mathrm{h}\) stream that is 97 mole \(\%\) carbon tetrachloride \(\left(\mathrm{CCl}_{4}\right)\) and \(3 \%\) carbon disulfide \(\left(\mathrm{CS}_{2}\right)\) is to be recovered from the bottom of a distillation column. The feed to the column is 16 mole \(\% \mathrm{CS}_{2}\) and \(84 \% \mathrm{CCl}_{4},\) and \(2 \%\) of the \(\mathrm{CCl}_{4}\) entering the column is contained in the overhead stream leaving the top of the column. (a) Draw and label a flowchart of the process and do the degree-of-freedom analysis. (b) Calculate the mass and mole fractions of \(\mathrm{CCl}_{4}\) in the overhead stream, and determine the molar flow rates of \(\mathrm{CCl}_{4}\) and \(\mathrm{CS}_{2}\) in the overhead and feed streams. (c) Suppose the overhead stream is analyzed and the mole fraction of \(\mathrm{CS}_{2}\) is found to be significantly lower than the value calculated in Part (b). List as many reasons as you can for the discrepancy, including possible violations of assumptions made in Part (b).

Methanol is formed from carbon monoxide and hydrogen in the gas-phase reaction The mole fractions of the reactive species at equilibrium satisfy the relation where \(P\) is the total pressure (atm), \(K_{c}\) the reaction equilibrium constant (atm \(^{-2}\) ), and \(T\) the temperature (K). The equilibrium constant \(K_{c}\) equals 10.5 at 373 K, and \(2.316 \times 10^{-4}\) at \(573 \mathrm{K}\). A semilog plot of \(K_{\mathrm{c}}\) (logarithmic scale) versus 1/ \(T\) (rectangular scale) is approximately linear between \(T=300 \mathrm{K}\) and \(T=600 \mathrm{K}\) (a) Derive a formula for \(K_{\mathrm{c}}(T),\) and use it to show that \(K_{\mathrm{e}}(450 \mathrm{K})=0.0548 \mathrm{atm}^{-2}\) (b) Write expressions for \(n_{A}, n_{B},\) and \(n_{C}\) (gram-moles of each species), and then \(y_{A}, y_{B},\) and \(y_{C},\) in terms of \(n_{\mathrm{A} 0}, n_{\mathrm{B} 0}, n_{\mathrm{C} 0},\) and \(\xi,\) the extent of reaction. Then derive an equation involving only \(n_{\mathrm{A} 0}, n_{\mathrm{B} 0}, n_{\mathrm{C} 0}, P, T,\) and \(\xi_{e},\) where \(\xi_{e}\) is the extent of reaction at equilibrium. (c) Suppose you begin with equimolar quantities of CO and \(\mathrm{H}_{2}\) and no \(\mathrm{CH}_{3} \mathrm{OH}\), and the reaction proceeds to equilibrium at 423 K and 2.00 atm. Calculate the molar composition of the product ( \(y_{\mathrm{A}}\), \(\left.y_{\mathrm{B}}, \text { and } y_{\mathrm{C}}\right)\) and the fractional conversion of \(\mathrm{CO}\) (d) The conversion of CO and \(\mathrm{H}_{2}\) can be enhanced by removing methanol from the reactor while leaving unreacted CO and \(\mathrm{H}_{2}\) in the vessel. Review the equations you derived in solving Part (c) and determine any physical constraints on \(\xi_{c}\) associated with \(n_{\mathrm{A} 0}=n_{\mathrm{B} 0}=1\) mol. Now suppose that 90\% of the methanol is removed from the reactor as it is produced; in other words, only 10\% of the methanol formed remains in the reactor. Estimate the fractional conversion of CO and the total gram moles of methanol produced in the modified operation. (e) Repeat Part (d), but now assume that \(n_{\mathrm{B} 0}=2\) mol. Explain the significant increase in fractional conversion of CO. (f) Write a set of equations for \(y_{\mathrm{A}}, y_{\mathrm{B}}, y_{\mathrm{C}},\) and \(f_{\mathrm{A}}\) (the fractional conversion of \(\mathrm{CO}\) ) in terms of \(y_{\mathrm{A} 0}, y_{\mathrm{B} 0}, T,\) and \(P(\) the reactor temperature and pressure at equilibrium). Enter the equations in an equation-solving program. Check the program by running it for the conditions of Part (c), then use it to determine the effects on \(f_{\mathrm{A}}\) (increase, decrease, or no effect) of separately increasing, (i) the fraction of \(\mathrm{CH}_{3} \mathrm{OH}\) in the feed, (ii) temperature, and (iii) pressure.

A liquid mixture containing 30.0 mole \(\%\) benzene \((\mathrm{B}), 25.0 \%\) toluene \((\mathrm{T}),\) and the balance xylene \((\mathrm{X})\) is fed to a distillation column. The bottoms product contains 98.0 mole \(\% \mathrm{X}\) and no \(\mathrm{B},\) and \(96.0 \%\) of the \(\mathrm{X}\) in the feed is recovered in this stream. The overhead product is fed to a second column. The overhead product from the second column contains \(97.0 \%\) of the \(\mathrm{B}\) in the feed to this column. The composition of this stream is 94.0 mole\% B and the balance T. (a) Draw and label a flowchart of this process and do the degree-of-freedom analysis to prove that for an assumed basis of calculation, molar flow rates and compositions of all process streams can be calculated from the given information. Write in order the equations you would solve to calculate unknown process variables. In each equation (or pair of simultaneous equations), circle the variable(s) for which you would solve. Do not do the calculations. (b) Calculate (i) the percentage of the benzene in the process feed (i.e., the feed to the first column) that emerges in the overhead product from the second column and (ii) the percentage of toluene in the process feed that emerges in the bottom product from the second column.

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