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A multi-step reaction takes place with the following elementary steps: \(\begin{array}{ll}{\text { Step I. }} & {A+B=C} \\ {\text { Step II. }} & {C+A \rightarrow D} \\ {\text { Step III. }} & {C+D \rightarrow B+E}\end{array}\) If step II is the slow step for the reaction, what is the overall rate law? (A) Rate = k[A]2[B] (B) Rate = k[A][C] (C) Rate = k[A][B] (D) Rate = k[A]/[D]

Short Answer

Expert verified
(B) Rate = k[A][C]

Step by step solution

01

Identify the Slow Step

Step II is identified as the slow step i.e, \(C + A \rightarrow D\).
02

Formulate the Rate Law

The rate law of a reaction is dependent on the rate-determining (slow) step. Therefore, the rate law of the reaction will have the reactants of step II: \(C\) and \(A\). Therefore, the rate law of the reaction is Rate = \(k[A][C]\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Rate Law
Rate law is an equation that relates the rate of a chemical reaction to the concentration of the reactants. It takes the form of Rate = k[Reactant 1]^[n][Reactant 2]^[m], where:\[ k \] is the rate constant, and and m are the reaction orders indicating how the rate is affected by the concentration of each reactant.
Rate laws are typically determined experimentally. However, in multi-step reactions, particularly when the slowest step (rate-determining step) is known, the rate law can be predicted from this step. - The role of the rate constant is crucial since it changes with temperature and the presence of catalysts.- Reaction orders aren’t always integers and don't necessarily correspond to the stoichiometric coefficients of the balanced equation.
This flexibility helps chemists understand the complexity and dependency of chemical reactions on various factors.
Elementary Steps
Elementary steps are individual stages in a multi-step reaction. Each elementary step represents a simple reaction that directly transforms reactants into products.
Understanding these steps is essential for constructing a complete reaction mechanism. - Each step involves only a few molecules. They often correspond to collisions or interactions between small numbers of reactant species. - Elementary steps are the building blocks of complex chemical reactions, and each step has its own activation energy and rate. When analyzing a multi-step reaction, knowing the elementary steps allows one to consider how reactants transition through intermediate states before forming final products. It provides insights into transitioning states, intermediates, and how the overall reaction progresses.
Rate-Determining Step
The rate-determining step is the slowest step in a reaction mechanism and it essentially limits the speed of the overall reaction. Think of it as a bottleneck, where the sequence of events in a multi-step process is delayed due to one especially slow step.- The rate law of the entire reaction mechanism is typically derived from this slowest step, regardless of the speed of other steps.- Identifying the rate-determining step helps predict how changes in conditions (like temperature or concentration) influence the entire reaction rate.In the example provided, Step II is the rate-determining step. This is the rationale behind choosing the rate law based on the concentrations of the reactants involved in this step, namely \[ [A] \] and \[ [C] \].
Chemical Kinetics
Chemical kinetics is the study of rates of chemical reactions and the factors that influence these rates. It helps in understanding how fast reactions proceed and which conditions optimize these processes.
Some core aspects of chemical kinetics include: - Temperature: Usually, an increase in temperature accelerates reactions by providing more energy to surpass activation energy. - Concentration of reactants: Higher concentrations often increase reaction rates as more particles are available to collide, leading to more frequent reactions. - Catalysts: These substances lower the activation energy needed for a reaction, speeding up the process without being consumed. Understanding chemical kinetics is crucial for industries like pharmaceuticals, where reaction rates determine efficiency and feasibility of production processes. Different reaction orders and mechanisms provide chemists with the means to predict and control chemical behaviors efficiently.

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Most popular questions from this chapter

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