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Choose the correct net ionic equation representing the reaction that occurs when solutions of potassium carbonate and copper (I) chloride are mixed. (A) \(\mathrm{K}_{2} \mathrm{CO}_{3}(a q)+2 \mathrm{CuCl}(a q) \rightarrow 2 \mathrm{KCl}(a q)+\mathrm{Cu}_{2} \mathrm{CO}_{3}(s)\) (B) \(\mathrm{K}_{2} \mathrm{CO}_{3}(a q)+2 \mathrm{CuCl}(a q) \rightarrow 2 \mathrm{KCl}(\mathrm{s})+\mathrm{Cu}_{2} \mathrm{CO}_{3}(a q)\) (C) \(\mathrm{CO}_{3}^{2-}+2 \mathrm{Cu}^{+} \rightarrow \mathrm{Cu}_{2} \mathrm{CO}_{3}\) (D) \(\mathrm{CO}_{3}^{2-}+\mathrm{Cu}^{2+} \rightarrow \mathrm{CuCO}_{3}(s)\)

Short Answer

Expert verified
The correct net ionic equation is (C) \(CO_{3}^{2-}+2Cu^{+} \rightarrow Cu_{2}CO_{3}\).

Step by step solution

01

Write the Complete Ionic Equations

First, it is important to write the complete ionic equations for all the given options. This means breaking apart all the compounds (except any solid, liquid, or gas products) into their ions. The correct full ionic equation for the reaction between potassium carbonate and copper (I) chloride is: \(2K^{+}(aq) + CO_{3}^{2-}(aq) + 2Cu^{+}(aq) + 2Cl^{-}(aq) \rightarrow 2K^{+}(aq) + 2Cl^{-}(aq) + Cu_{2}CO_{3}(s)\).
02

Comparison of Ionic and Net Ionic Equations

Next, compare the complete ionic equation to the proposed net ionic equations. In a net ionic equation, we 'cancel out' the spectator ions. Those are the ions that do not participate directly in the reaction. In our case, these are \(2K^{+}(aq)\) and \(2Cl^{-}(aq)\).
03

Choose the Correct Net Ionic Equation

Finally, look for the matching equation among the options given in the problem. The correct net ionic equation here will be the one that includes only the species taking part in the reaction: the carbonate ion \(CO_{3}^{2-}\) and copper (I) ion \(Cu^{+}\), as well as the solid product, copper (I) carbonate \(Cu_{2}CO_{3}\). Hence, the correct choice is: \(CO_{3}^{2-}+2Cu^{+} \rightarrow Cu_{2}CO_{3}\). This matches with option (C).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Spectator Ions
In chemical reactions, particularly those that take place in aqueous solutions, spectator ions essentially 'sit out' of the reaction. They are present in both the reactant and product sides of a chemical equation but remain unchanged throughout the process. This means they do not participate in the actual chemical change. These ions are crucial for maintaining electrical neutrality and balancing the equation but are not involved in forming the final product.

For example, in the reaction between potassium carbonate and copper (I) chloride, the spectator ions are the potassium ions \( K^+(aq) \) and chloride ions \( Cl^-(aq) \). When the original full ionic equation is written, these ions appear equally on both sides. Once we determine the net ionic equation, these spectator ions are omitted because they do not affect the outcome of the reaction.

Understanding the role of spectator ions helps us to focus on the essential parts of a reaction by simplifying equations, showing only the components that participate directly. This simplification results in something called a net ionic equation, which provides a clearer view of the chemistry occurring.
Ionic Compounds
Ionic compounds are formed through the electrostatic attraction between ions of opposite charges. Typically, they consist of metal cations and non-metal anions. In water, many ionic compounds dissolve, splitting into their respective ions. This dissolution is what allows these compounds to participate in chemical reactions.

For example, in the interaction between potassium carbonate \( \text{K}_2\text{CO}_3 \) and copper(I) chloride \( \text{CuCl} \), both compounds dissolve in water to form ions: \( 2K^+(aq) + CO_3^{2-}(aq) + 2Cu^+(aq) + 2Cl^-(aq) \). This complete ionic equation shows the ions that are present in the reaction medium.

Recognizing ionic compounds and their ability to dissociate is crucial in predicting the products of a reaction. It also helps in identifying which ions remain as spectator ions and which participate directly, contributing to the net ionic equation.
Copper Reactions
Copper, especially in its ionic forms, engages in various chemical reactions. In aqueous solutions, copper ions can react with other anions to form precipitates that are typically insoluble in water. For instance, in the given exercise, copper(I) ions \( Cu^+ \) react with carbonate ions \( CO_3^{2-} \) to form copper carbonate \( Cu_2CO_3 \).

This reaction between copper ions and carbonate is an example of a precipitation reaction, where two soluble salts react to form an insoluble product, or precipitate. The copper carbonate precipitate forms as a solid, visible as a different phase from the solution. By understanding copper's reactivity, especially its ability to form such complexes, we can predict its behavior in various chemical processes.

The knowledge of copper reactions is often applied in industries, including those that involve electroplating and manufacturing copper compounds. In educational settings, these reactions serve as excellent examples to understand solubility rules and concepts of net ionic equations.

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Most popular questions from this chapter

Nitrogen gas was collected over water at \(25^{\circ} \mathrm{C}\) . If the vapor pressure of water at \(25^{\circ} \mathrm{C}\) is 23 \(\mathrm{mmH}\) g, and the total pressure in the container is measured at 781 \(\mathrm{mmH} \mathrm{g}\) , what is the partial pressure of the nitrogen gas? \(\begin{array}{ll}{\text { (A) }} & {46 \mathrm{mmH} \mathrm{g}} \\ {\text { (B) }} & {551 \mathrm{mmH} \mathrm{g}} \\ {\text { (C) }} & {735 \mathrm{mmH} \mathrm{g}} \\ {\text { (D) }} & {758 \mathrm{mmH} \mathrm{g}}\end{array}\)

Directions: Questions 4-7 are short free-response questions that require about 9 minutes each to answer and are worth 4 points each. Write your response in the space provided following each question. Examples and equations may be included in your responses where appropriate. For calculations, clearly show the method used and the steps involved in arriving at your answers. You must show your work to receive credit for your answer. Pay attention to significant figures. A stock solution of \(2.0 \mathrm{M} \mathrm{MgCl}_{2}\) is dissolved in water. (a) (i) In the beaker below, draw a particulate diagram that represents \(\mathrm{MgCl}_{2}\) dissolved in water. The approximate sizes of each atom/ion are provided for you. Your diagram should include at least four water molecules, which should be correctly oriented compared to the ions dissolved in solution. (DIAGRAM CANT COPY) (ii) Why are the chloride ions from (a)(i) larger than the magnesium (b) (i) A student wishes to make up 500 \(\mathrm{mL}\) of 0.50 \(M \mathrm{MgCl}_{2}\) for an experiment. Explain the best method of doing so utilizing a graduated cylinder and a volumetric flask. Assume \(\mathrm{MgCl}_{2}\) is fully soluble. (ii) What are the concentrations of the \(\mathrm{Mg}^{2+}\) and \(\mathrm{Cl}^{-}\) ions in the new solution?

Which of the following compounds would have the highest lattice energy? (A) LiF (B) MgCl_ (C) CaBr_ (D) \(\mathrm{C}_{2} \mathrm{H}_{6}\)

A sample of water originally at \(25^{\circ} \mathrm{C}\) is heated to \(75^{\circ} \mathrm{C}\) . As the temperature increases, the vapor pressure of the water is also observed to increase. Why? (A) Water molecules are more likely to have enough energy to break free of the intermolecular forces holding them together. (B) The covalent bonds between the hydrogen and oxygen atoms within individual water molecules are more likely to be broken. (C) The strength of the hydrogen bonding between different water molecules will increase until it exceeds the covalent bond energy within individual water molecules. (D) The electron clouds surrounding each water molecule are becoming less polarizable, weakening the intermolecular forces between them.

Which neutral atom of the following elements would have the most unpaired electrons? (A) Titanium (B) Manganese (C) Nickel (D) Zinc

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