/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 71 This reaction can be used to gen... [FREE SOLUTION] | 91Ó°ÊÓ

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This reaction can be used to generate hydrogen gas from methane: $$\mathrm{CH}_{4}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{g}) \longrightarrow \mathrm{CO}(\mathrm{g})+3 \mathrm{H}_{2}(\mathrm{~g})$$ If you use \(500 . \mathrm{g} \mathrm{CH}_{4}\) and \(1300 . \mathrm{g}\) water: (a) Determine the limiting reactant. (b) Calculate the mass (g) of \(\mathrm{H}_{2}\) that can be produced. (c) Calculate the mass (g) of the excess reactant remaining when the reaction is complete.

Short Answer

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(a) Limiting reactant: CHâ‚„. (b) Mass of Hâ‚‚: 188.77 g. (c) Excess Hâ‚‚O remaining: 739.82 g.

Step by step solution

01

Calculate Moles of Reactants

First, determine the molar mass of methane (CHâ‚„) and water (Hâ‚‚O). The molar mass of CHâ‚„ is approximately 16.05 g/mol and for Hâ‚‚O it's about 18.02 g/mol. Now calculate the moles of each reactant: \[ \text{Moles of CH}_4 = \frac{500 \, \text{g}}{16.05 \, \text{g/mol}} \approx 31.15 \, \text{mol} \]\[ \text{Moles of H}_2\text{O} = \frac{1300 \, \text{g}}{18.02 \, \text{g/mol}} \approx 72.15 \, \text{mol} \]
02

Determine the Stoichiometry

Check the balanced chemical equation to find the stoichiometric ratio for the reactants. The reaction equation is:\[ \text{CH}_4 + \text{H}_2\text{O} \rightarrow \text{CO} + 3\text{H}_2 \]This shows a \(1:1\) molar ratio between CHâ‚„ and Hâ‚‚O.
03

Identify the Limiting Reactant

Compare the mole ratio from the calculation with the stoichiometric ratio in the equation. Since the mole ratio should be \(1:1\), check if moles of CHâ‚„ and Hâ‚‚O are equal:Moles of CHâ‚„ = 31.15 molMoles of Hâ‚‚O = 72.15 molSince fewer moles of CHâ‚„ are available than Hâ‚‚O, CHâ‚„ is the limiting reactant.
04

Calculate Mass of Hydrogen Produced

Use the moles of the limiting reactant (CHâ‚„) to calculate the amount of hydrogen (Hâ‚‚) produced. From the balanced equation, 1 mole of CHâ‚„ produces 3 moles of Hâ‚‚.\[ \text{Moles of H}_2 = 31.15 \, \text{mol} \times 3 = 93.45 \, \text{mol} \] The molar mass of Hâ‚‚ is approximately 2.02 g/mol. Thus, the mass of Hâ‚‚ is:\[ \text{Mass of H}_2 = 93.45 \, \text{mol} \times 2.02 \, \text{g/mol} \approx 188.77 \, \text{g} \]
05

Calculate Remaining Excess Reactant

Calculate how much Hâ‚‚O is consumed by using the stoichiometric ratio with CHâ‚„. Since CHâ‚„ is limiting, it determines the reaction amount.Moles of Hâ‚‚O used = Moles of CHâ‚„ reacted = 31.15 molFind the remaining moles of Hâ‚‚O:\[ \text{Remaining H}_2\text{O} = 72.15 \, \text{mol} - 31.15 \, \text{mol} = 41.00 \, \text{mol} \]Convert to mass:\[ \text{Mass of remaining H}_2\text{O} = 41.00 \, \text{mol} \times 18.02 \, \text{g/mol} \approx 739.82 \, \text{g} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Limiting Reactant
In a chemical reaction, not all reactants are completely used up. One of them will run out first and restrict how far the reaction can proceed. This reactant is known as the **limiting reactant**. Identifying the limiting reactant is crucial because it determines the maximum amount of products that can be formed. In our exercise, we have methane (CHâ‚„) and water (Hâ‚‚O) reacting. We first need to compare the mole amounts of CHâ‚„ and Hâ‚‚O using their molar masses.
  • Molar mass of CHâ‚„: 16.05 g/mol
  • Molar mass of Hâ‚‚O: 18.02 g/mol
Calculate moles for each:
  • Moles of CHâ‚„: \( \frac{500}{16.05} \approx 31.15 \) mol
  • Moles of Hâ‚‚O: \( \frac{1300}{18.02} \approx 72.15 \) mol
The balanced chemical equation shows a 1:1 ratio, meaning we need equal moles of CHâ‚„ and Hâ‚‚O. Since we have more moles of Hâ‚‚O than CHâ‚„, methane runs out first, making it the limiting reactant. Recognizing this lets us calculate how much Hâ‚‚ and the leftover reactant remain in reaction.
Moles Calculation
Moles serve as a bridge between the atomic scale and macroscopic measurements in stoichiometry problems. To understand the extent of chemical reactions, calculating the moles of reactants and products is vital. In stoichiometry, the amount of substance isn't directly measured in grams or liters but in moles. **Here's how we calculate the moles of reactants:**First, determine the molar mass for each reactant. Methane (CHâ‚„) has a molar mass of 16.05 g/mol, while water (Hâ‚‚O) is 18.02 g/mol. Using the mass provided in the exercise, we apply the formula:\[ \text{Moles} = \frac{\text{Mass}}{\text{Molar Mass}} \]For CHâ‚„, we calculate:\[ \frac{500 \text{ g}}{16.05 \text{ g/mol}} \approx 31.15 \text{ mol of CH}_4 \]And for Hâ‚‚O:\[ \frac{1300 \text{ g}}{18.02 \text{ g/mol}} \approx 72.15 \text{ mol of H}_2\text{O} \]These mole calculations are essential for determining the limiting reactant and predicting the amounts of products formed in the reaction.
Chemical Reaction
Chemical reactions describe how substances transform into new products. For this, it is crucial to comprehend the balanced reaction equation.In this problem, we use the chemical equation:\[ \text{CH}_4 + \text{H}_2\text{O} \rightarrow \text{CO} + 3\text{H}_2 \]This equation shows that one molecule of methane reacts with one molecule of water to produce one molecule of carbon monoxide and three molecules of hydrogen gas. The coefficients tell us the **stoichiometric ratios** needed for balancing the reaction.Understanding the reaction mechanism is vital for anyone studying chemistry:
  • The reactants are subtracted from the system, transforming into products.
  • The products are generated based on the stoichiometric coefficients e.g., 3 moles of Hâ‚‚ produced per CHâ‚„ used.
In practical applications, reactions need specific percentages of components, especially in industries that manufacture chemicals. Stoichiometry guides these necessary calculations, ensuring efficiency and minimizing waste. By appreciating these reactions and their balance, students can foresee the outcomes of their chemical equations accurately.

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Most popular questions from this chapter

When these pairs of reactants are combined in a beaker, (a) describe in words what the contents of the beaker would look like before and after any reaction occurs; (b) use different circles for atoms, molecules, and ions to draw a nanoscale (particulate-level) diagram of what the contents would look like; and (c) write a chemical equation to represent symbolically what the contents would look like. \(\mathrm{LiCl}(\mathrm{aq})\) and \(\mathrm{AgNO}_{3}(\mathrm{aq})\) \(\mathrm{NaOH}(\mathrm{aq})\) and \(\mathrm{HCl}(\mathrm{aq})\)

Classify each of these exchange reactions as an acid-base reaction, a precipitation reaction, or a gas-forming reaction. Predict the products of the reaction and then balance the completed equation. (a) \(\mathrm{Fe}(\mathrm{OH})_{3}(\mathrm{~s})+\mathrm{HNO}_{3}(\mathrm{aq}) \longrightarrow\) (b) \(\mathrm{FeCO}_{3}(\mathrm{~s})+\mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{aq}) \longrightarrow\) (c) \(\mathrm{FeCl}_{2}(\mathrm{aq})+\left(\mathrm{NH}_{4}\right)_{2} \mathrm{~S}(\mathrm{aq}) \longrightarrow\) (d) \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{aq})+\mathrm{Na}_{2} \mathrm{CO}_{3}(\mathrm{aq}) \longrightarrow\)

You mix \(25.0 \mathrm{~mL}\) of \(0.234-\mathrm{M} \mathrm{FeCl}_{3}\) solution with \(42.5 \mathrm{~mL}\) of \(0.453-\mathrm{M} \mathrm{NaOH}\) (a) Calculate the maximum mass, in grams, of \(\mathrm{Fe}(\mathrm{OH})_{3}\) that will precipitate. (b) Determine which reactant is in excess. (c) Calculate the concentration of the excess reactant remaining in solution after the maximum mass of \(\mathrm{Fe}(\mathrm{OH})_{3}\) has precipitated.

For each substance, what ions are present in an aqueous solution? (a) \(\mathrm{KOH}\) (b) \(\mathrm{K}_{2} \mathrm{SO}_{4}\) (c) \(\mathrm{NaNO}_{3}\) (d) \(\mathrm{NH}_{4} \mathrm{Cl}\)

The Hargreaves process is an industrial method for making sodium sulfate for use in papermaking. $$4 \mathrm{NaCl}+2 \mathrm{SO}_{2}+2 \mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2} \longrightarrow 2 \mathrm{Na}_{2} \mathrm{SO}_{4}+4 \mathrm{HCl}$$ (a) If you start with \(10 .\) mol of each reactant, determine which one limits the amount of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\) produced. (b) Determine the amount of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\) produced if you start with \(100 . \mathrm{g}\) of each reactant.

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