Chapter 3: Problem 25
For each substance, what ions are present in an aqueous solution? (a) \(\mathrm{KOH}\) (b) \(\mathrm{K}_{2} \mathrm{SO}_{4}\) (c) \(\mathrm{NaNO}_{3}\) (d) \(\mathrm{NH}_{4} \mathrm{Cl}\)
Short Answer
Expert verified
(a) K鈦 and OH鈦; (b) K鈦 and SO鈧劼测伝; (c) Na鈦 and NO鈧冣伝; (d) NH鈧勨伜 and Cl鈦.
Step by step solution
01
Identify the Compound
Let's start by identifying the substances that dissociate in an aqueous solution: (a) KOH, (b) K2SO4, (c) NaNO3, (d) NH4Cl.
02
Determine the Ionic Components
For each substance, determine the ions that form when the compound dissociates in water. This can be achieved by breaking down the chemical formulas:
- (a) KOH will dissociate into K鈦 and OH鈦 ions.
- (b) K2SO4 will dissociate into 2 K鈦 and one SO鈧劼测伝 ions.
- (c) NaNO3 will dissociate into Na鈦 and NO鈧冣伝 ions.
- (d) NH4Cl will dissociate into NH鈧勨伜 and Cl鈦 ions.
03
Confirm charge balance
Ensure the sum of charges from the ions equals the charge of the neutral compound. For each substance, the total positive charges should equal the total negative charges:
- (a) 1 K鈦 has a +1 charge and 1 OH鈦 has a -1 charge, balancing to neutral.
- (b) 2 K鈦 ions each with +1 charges equal the -2 charge from one SO鈧劼测伝, balancing to neutral.
- (c) 1 Na鈦 has a +1 charge and 1 NO鈧冣伝 has a -1 charge, balancing to neutral.
- (d) 1 NH鈧勨伜 has a +1 charge and 1 Cl鈦 has a -1 charge, balancing to neutral.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Dissociation
Dissociation is a process whereby ionic compounds dissociate or separate into individual ions when dissolved in water. This concept is crucial for understanding how compounds behave in aqueous solutions. When an ionic substance dissolves, its cations (positively charged ions) and anions (negatively charged ions) separate and disperse uniformly throughout the solvent.
In the context of our exercise, dissociation allows us to identify the ions present in aqueous solutions. For example:
In the context of our exercise, dissociation allows us to identify the ions present in aqueous solutions. For example:
- KOH dissociates into the ions K鈦 and OH鈦.
- 碍鈧係翱鈧 dissociates into 2 K鈦 ions and one SO鈧劼测伝 ion.
- 狈补狈翱鈧 dissociates into Na鈦 and NO鈧冣伝 ions.
- 狈贬鈧凛濒 dissociates into NH鈧勨伜 and Cl鈦 ions.
Ionic Compounds
Ionic compounds are composed of positively charged ions, or cations, and negatively charged ions, or anions. These ions come together to form a neutral compound by balancing out their charges.
This balance of charges is a hallmark of ionic compounds and dictates how they will behave, especially when dissolved in water. In aqueous solutions, ionic compounds dissociate into their constituent ions, allowing the solution to conduct electricity. This property is called electrolytic conductivity.
This balance of charges is a hallmark of ionic compounds and dictates how they will behave, especially when dissolved in water. In aqueous solutions, ionic compounds dissociate into their constituent ions, allowing the solution to conduct electricity. This property is called electrolytic conductivity.
- KOH contains K鈦 and OH鈦.
- 碍鈧係翱鈧 contains double the cations (2 K鈦) to balance with one SO鈧劼测伝 anion.
- 狈补狈翱鈧 has Na鈦 and NO鈧冣伝.
- 狈贬鈧凛濒 provides NH鈧勨伜 and Cl鈦.
Charge Balance
Charge balance is a fundamental concept in chemistry that ensures the total positive charges and negative charges in a compound or solution are equal.
This balance maintains the compound as electrically neutral. When we assess ionic compounds in solutions, confirming the charge balance verifies that dissociation is accurately represented. Each compound we discussed must balance its cations and anions as follows:
This balance maintains the compound as electrically neutral. When we assess ionic compounds in solutions, confirming the charge balance verifies that dissociation is accurately represented. Each compound we discussed must balance its cations and anions as follows:
- For KOH: 1 K鈦 with +1 charge balances 1 OH鈦 with -1 charge.
- For 碍鈧係翱鈧: 2 K鈦 each with +1 charge balance 1 SO鈧劼测伝 with -2 charge.
- For 狈补狈翱鈧: 1 Na鈦 with +1 charge balances 1 NO鈧冣伝 with -1 charge.
- For 狈贬鈧凛濒: 1 NH鈧勨伜 with +1 charge balances 1 Cl鈦 with -1 charge.
Aqueous Chemistry
Aqueous chemistry refers to reactions and processes that occur in water-based solutions. Water is a polar solvent, meaning it can effectively dissolve a variety of substances, especially ionic compounds.
When ionic compounds dissolve, they separate into ions, leading to the occurrence of the chemical processes, such as:
When ionic compounds dissolve, they separate into ions, leading to the occurrence of the chemical processes, such as:
- Conductivity: Solutions with dissolved ions can conduct electricity.
- Reactivity: Ions in solution can participate in chemical reactions such as acid-base reactions and precipitation.
- Solution properties: Concentration, pH, and solubility determine how a solution behaves and reacts.