Chapter 9: Problem 10
Draw a Lewis electron-dot symbol for each atom: (a) \(\mathrm{Rb}\) (b) Si (c) I
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Chapter 9: Problem 10
Draw a Lewis electron-dot symbol for each atom: (a) \(\mathrm{Rb}\) (b) Si (c) I
These are the key concepts you need to understand to accurately answer the question.
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Aluminum oxide \(\left(\mathrm{Al}_{2} \mathrm{O}_{3}\right)\) is a widely used industrial abrasive (known as emery or corundum), for which the specific application depends on the hardness of the crystal. What does this hardness imply about the magnitude of the lattice energy? Would you have predicted from the chemical formula that \(\mathrm{Al}_{2} \mathrm{O}_{3}\) is hard? Explain.
(a) In general, how does the lattice energy of an ionic compound depend on the charges and sizes of the ions?
For each pair, choose the compound with the smaller lattice energy, and explain your choice: (a) NaF or \(\mathrm{NaCl}\) (b) \(\mathrm{K}_{2} \mathrm{O}\) or \(\mathrm{K}_{2} \mathrm{~S}\)
Geologists have a rule of thumb: when molten rock cools and solidifies, crystals of compounds with the smallest lattice energies appear at the bottom of the mass. Suggest a reason for this.
Rank the members of each set of compounds in order of \(\mathrm{de}\) creasing ionic character of their bonds. Use partial charges to indicate the bond polarity of each: (a) \(\mathrm{PCl}_{3}, \mathrm{PBr}_{3}, \mathrm{PF}_{3}\) (b) \(\mathrm{BF}_{3}, \mathrm{NF}_{3}, \mathrm{CF}_{4}\) (c) \(\mathrm{SeF}_{4}, \mathrm{TeF}_{4}, \mathrm{BrF}_{3}\)
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