/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 138 A person inhales air richer in \... [FREE SOLUTION] | 91影视

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A person inhales air richer in \(\mathrm{O}_{2}\) and exhales air richer in \(\mathrm{CO}_{2}\) and water vapor. During each hour of sleep, a person exhales a total of about \(300 \mathrm{~L}\) of this \(\mathrm{CO}_{2}\) -enriched and \(\mathrm{H}_{2} \mathrm{O}\) -enriched air. (a) If the partial pressures of \(\mathrm{CO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\) in exhaled air are each 30.0 torr at \(37.0^{\circ} \mathrm{C},\) calculate the mass \((\mathrm{g})\) of \(\mathrm{CO}_{2}\) and of \(\mathrm{H}_{2} \mathrm{O}\) exhaled in \(1 \mathrm{~h}\) of sleep. (b) How many grams of body mass does the person lose in \(8 \mathrm{~h}\) of sleep if all the \(\mathrm{CO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\) exhaled come from the metabolism of glucose? $$\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(s)+6 \mathrm{O}_{2}(g) \longrightarrow 6 \mathrm{CO}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)$$

Short Answer

Expert verified
In 8 hours of sleep, 115.12 g of body mass is lost due to exhaled CO鈧 and H鈧侽.

Step by step solution

01

Identify relevant quantities

We know that the person exhales 300 L of air enriched with CO鈧 and H鈧侽 each hour. Partial pressures of CO鈧 and H鈧侽 are each 30.0 torr at 37.0掳C.
02

Convert volume to moles using Ideal Gas Law

Using the Ideal Gas Law: \[ PV = nRT \]\[ n = \frac{PV}{RT} \]Where: - P = partial pressure (in atm: 30.0 torr 脳 1 atm / 760 torr = 0.03947 atm) - V = volume (in L: 300 L / 2 = 150 L for each gas) - R = gas constant (0.0821 L atm K鈦宦 mol鈦宦) - T = temperature (in K: 37.0掳C + 273.15 = 310.15 K)Plugging in the values:\[ n_{CO_{2}} = \frac{0.03947 \, \text{atm} \times 150 \, \text{L}}{0.0821 \, \text{L atm K}鈦宦 \, \text{mol}鈦宦 \times 310.15 \, \text{K}} = 0.232 \, \text{mol}\]and similarly for H鈧侽, \[ n_{H_{2}O} = 0.232 \, \text{mol} \].
03

Calculate the mass of exhaled CO鈧 and H鈧侽

Using molar masses (CO鈧 = 44.01 g/mol, H鈧侽 = 18.02 g/mol):\[ m_{CO_{2}} = 0.232 \, \text{mol} \times 44.01 \, \text{g/mol} = 10.21 \, \text{g} \]and\[ m_{H_{2}O} = 0.232 \, \text{mol} \times 18.02 \, \text{g/mol} = 4.18 \, \text{g} \].
04

Calculate the total mass in 8 hours

Each hour, total mass exhaled as CO鈧 and H鈧侽 is \[ 10.21 \, \text{g} + 4.18 \, \text{g} = 14.39 \text{g} \].For 8 hours, the total mass is\[ 14.39 \, \text{g/hour} \times 8 \, \text{hours} = 115.12 \, \text{g}. \]
05

Short answer calculation

So, in 8 hours of sleep, if all the exhaled CO鈧 and H鈧侽 come from glucose metabolism, the total grams of body mass lost would be 115.12 g.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The Ideal Gas Law is one of the most fundamental equations in chemistry, used to relate the pressure, volume, temperature, and number of moles of a gas. It is expressed as:
\[ PV = nRT \]
Where:
- \( P \) is the pressure of the gas (in atmospheres when using the universal gas constant R),
- \( V \) is the volume of the gas (in liters),
- \( n \) is the number of moles,
- \( R \) is the universal gas constant (0.0821 L atm K鈦宦 mol鈦宦),
- \( T \) is the temperature (in Kelvin).
This law helps us to determine either the unknown property of a gas or find out how the gas behaves under different conditions. In the exercise above, we used the Ideal Gas Law to determine the number of moles of \( \mathrm{CO}_{2} \) and \( \mathrm{H}_{2} \mathrm{O} \) exhaled. By rearranging the formula to solve for moles \( n \), we calculated:
\[ n = \frac{PV}{RT} \] We used the given partial pressures, volume, temperature, and the gas constant to find \( n \).
Partial Pressures
In a mixture of gases, each gas exerts its own pressure as if it were alone in the container. This individual pressure is known as the partial pressure. Dalton's Law of Partial Pressures states that the total pressure of a mixture of gases is equal to the sum of the partial pressures of the individual component gases.
For instance, in the exercise from above, the partial pressures of \( \mathrm{CO}_{2} \) and \( \mathrm{H}_{2} \mathrm{O} \) in the exhaled air are both given as 30.0 torr.
To convert these pressures to atmospheres (since the universal gas constant \( R \) in the Ideal Gas Law uses atm), we converted as follows:
\[ \text{Pressure} (\text{atm}) = \text{Pressure} (\text{torr}) \times \frac{1 \text{ atm}}{760 \text{ torr}} \] By converting these pressures and using them in the Ideal Gas Law, we accurately calculated the number of moles of each gas.
Glucose Metabolism
Glucose metabolism is the process where glucose is converted into energy, with the chemical equation:
\[ \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(s) + 6 \mathrm{O}_{2}(g) \rightarrow 6 \mathrm{CO}_{2}(g) + 6 \mathrm{H}_{2} \mathrm{O}(g) \]
This reaction means that one mole of glucose produces six moles of carbon dioxide and six moles of water.
In the exercise, the total mass of \( \mathrm{CO}_{2} \) and \( \mathrm{H}_{2} \mathrm{O} \) exhaled comes from the metabolism of glucose. The calculation of body mass lost over 8 hours of sleep is based on these products of metabolism.
Understanding glucose metabolism helps us comprehend how energy production and gas exchange work together, impacting body mass due to respiratory processes during activities such as sleeping.
Molar Mass Calculation
The molar mass of a substance is the mass of one mole of its entities (atoms, molecules, etc.) and is usually expressed in grams per mole (g/mol). It is essential for converting between the mass of a substance and the number of moles.
For example, the molar mass of carbon dioxide \( \mathrm{CO}_{2} \) and water \( \mathrm{H}_{2} \mathrm{O} \) was crucial in the exercise.
- \( \mathrm{CO}_{2} \) has a molar mass of 44.01 g/mol, calculated as:
\[ 12.01 \text{(C)} + 2 \times 16.00 \text{(O)} = 44.01 \text{ g/mol} \]
- \( \mathrm{H}_{2} \mathrm{O} \) has a molar mass of 18.02 g/mol, calculated as:
\[ 2 \times 1.01 \text{(H)} + 16.00 \text{(O)} = 18.02 \text{ g/mol} \]
Using these molar masses, we converted moles to grams, providing the final mass values needed for the calculation of how much body mass was lost over 8 hours of sleep.

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