/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 141 Lead(II) chromate \(\left(\mathr... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

Lead(II) chromate \(\left(\mathrm{PbCrO}_{4}\right)\) is used as the yellow pigment for marking traffic lanes but is banned from house paint because of the risk of lead poisoning. It is produced from chromite \(\left(\mathrm{FeCr}_{2} \mathrm{O}_{4}\right),\) an ore of chromium: $$ \begin{array}{r} 4 \mathrm{FeCr}_{2} \mathrm{O}_{4}(s)+8 \mathrm{~K}_{2} \mathrm{CO}_{3}(a q)+7 \mathrm{O}_{2}(g) \longrightarrow \\ 2 \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+8 \mathrm{~K}_{2} \mathrm{CrO}_{4}(a q)+8 \mathrm{CO}_{2}(g) \end{array} $$ Lead(II) ion then replaces the \(\mathrm{K}^{+}\) ion. If a yellow paint is to have \(0.511 \% \mathrm{PbCrO}_{4}\) by mass, how many grams of chromite are needed per kilogram of paint?

Short Answer

Expert verified
1.768 grams of chromite are needed per kilogram of paint.

Step by step solution

01

Determine Molar Masses

Calculate the molar masses of all relevant compounds. For \(\text{FeCr}_2\text{O}_4\), the molar mass is: \(55.85 + 2(51.996) + 4(16) = 223.84\) g/mol. For \(\text{PbCrO}_4\), the molar mass is: \(207.2 + 51.996 + 4(16) = 323.2\) g/mol.
02

Compute Mass Percentage Conversion

Convert the given percentage by mass into grams. Since the paint is 0.511% \(\text{PbCrO}_4\) by mass, this means \(\frac{0.511}{100} = 0.00511\) g of \(\text{PbCrO}_4\) per 1 g of paint. For 1 kg (1000 g), it's \(0.00511 \times 1000 = 5.11\) g of \(\text{PbCrO}_4\).
03

Determine Moles of \(\text{PbCrO}_4\)

Use the molar mass of \(\text{PbCrO}_4\) to find how many moles are in 5.11 g. Moles of \(\text{PbCrO}_4\) = \(\frac{5.11}{323.2} = 0.0158\) moles.
04

Relate Moles of Chromite to Moles of \(\text{PbCrO}_4\)

Use the stoichiometry of the reaction. From the balanced equation, 4 moles of \(\text{FeCr}_2\text{O}_4\) produce 8 moles of \(\text{K}_2\text{CrO}_4\), which in turn can be replaced by \(\text{PbCrO}_4\). This means 4 moles of \(\text{FeCr}_2\text{O}_4\) produce 8 moles of \(\text{PbCrO}_4\).
05

Calculate Moles of Chromite Needed

If 8 moles of \(\text{FeCr}_2\text{O}_4\) produce 4 moles of \(\text{PbCrO}_4\), then 1 mole of \(\text{FeCr}_2\text{O}_4\) produces 2 moles of \(\text{PbCrO}_4\). Thus, 0.0158 moles of \(\text{PbCrO}_4\) require \(\frac{0.0158}{2} = 0.0079\) moles of \(\text{FeCr}_2\text{O}_4\).
06

Find Mass of Chromite Needed

Use the molar mass of \(\text{FeCr}_2\text{O}_4\) to convert moles to grams. Mass of \(\text{FeCr}_2\text{O}_4\) = 0.0079 moles \(\times 223.84\) g/mol = 1.768 g.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

molar mass calculation
Molar mass calculation is a fundamental concept in chemistry. It involves finding the mass of one mole of a substance, which is expressed in grams per mole (g/mol). To calculate the molar mass of a compound, sum the molar masses of its individual elements.
For instance, take the compound Lead(II) chromate \(\text{PbCrO}_4\).
The molar mass is calculated as:
  • Lead (Pb): 207.2 g/mol
  • Chromium (Cr): 51.996 g/mol
  • Oxygen (O - four atoms): 4 \( \times \) 16 g/mol = 64 g/mol
Adding these together gives us:
\(207.2 + 51.996 + 64 = 323.2\) g/mol.
This means one mole of Lead(II) chromate weighs 323.2 grams. Such calculations help us relate masses of substances to their molar quantities in chemical reactions.
chemical reactions
Chemical reactions describe the process where reactants transform into products. Understanding the stoichiometry of a reaction is key. For the given exercise, the reaction involves chromite \( \text{FeCr}_2 \text{O}_4\):

The balanced chemical reaction is:

\(4 \text{FeCr}_2 \text{O}_4(s) + 8 \text{K}_2 \text{CO}_3(aq) + 7 \text{O}_2(g) \longrightarrow 2 \text{Fe}_2 \text{O}_3(s) + 8 \text{K}_2 \text{CrO}_4(aq) + 8 \text{CO}_2(g)\)

This equation shows how reactants combine in fixed ratios to form products. Here, 4 moles of chromite react with 8 moles of potassium carbonate and 7 moles of oxygen to produce potassium chromate among other products.
Conversions using stoichiometry (like moles to grams) rely on balanced equations to ensure mass and atoms are conserved. This balance is crucial for solving problems like determining required reactants for a certain product amount.
mass percentage conversion
Mass percentage conversion helps in quantifying the composition of a mixture. To convert a mass percentage to an absolute mass, use the formula:
\( \text{Mass of Compound} = \text{Percentage by Mass} \times \text{Total Mass}\)
In the exercise, the yellow paint is 0.511% by mass of \( \text{PbCrO}_4 \). If we have 1 kg (1000 g) of paint:
  • Convert the percentage: \(\frac{0.511}{100} = 0.00511\)
  • Multiply by total mass: \(0.00511 \times 1000 = 5.11 \) grams of \( \text{PbCrO}_4\)
This means there are 5.11 grams of Lead(II) chromate in 1 kg of paint. Such conversions are essential in preparing solutions and mixtures in precise concentrations.
lead poisoning risk
Lead poisoning is a serious health hazard, particularly from prolonged exposure. Lead ions, when introduced into the body, can impair neurological functions, cause anemia, and damage organs. Due to these risks, compounds containing lead, like Lead(II) chromate \( \text{PbCrO}_4 \), are restricted in applications like household paints. The regulations aim to minimize exposure, especially in children, who are more vulnerable to lead's toxic effects.
In the context of the problem, although Lead(II) chromate is useful for marking traffic lanes due to its vibrant color, its potential for harmful exposure means it must be handled with caution and restricted to non-residential applications.
chromite
Chromite \( \text{FeCr}_2 \text{O}_4 \) is an important mineral and the primary source of chromium. Chromium is used in various industrial applications, including the production of stainless steel, dyes, and pigments. Chromite ore is processed to extract potassium chromate, which can be converted to Lead(II) chromate:

In the exercise:
\(4 \text{FeCr}_2 \text{O}_4 + 8 \text{K}_2 \text{CO}_3 + 7 \text{O}_2 \rightarrow 2 \text{Fe}_2 \text{O}_3 + 8 \text{K}_2 \text{CrO}_4 + 8 \text{CO}_2 \)

This shows the transformation of chromite into useful products through chemical reactions. Understanding these processes is essential for efficient resource utilization and minimizing environmental impact.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Which of the following sets of information allows you to obtain the molecular formula of a covalent compound? In each case that allows it, explain how you would proceed (draw a road map and write a plan for a solution). (a) Number of moles of each type of atom in a given sample of the compound (b) Mass \% of each element and the total number of atoms in a molecule of the compound (c) Mass \% of each element and the number of atoms of one element in a molecule of the compound (d) Empirical formula and mass \(\%\) of each element (e) Structural formula

Is \(\mathrm{MgCl}_{2}\) an empirical or a molecular formula for magnesium chloride? Explain.

Various nitrogen oxides, as well as sulfur oxides, contribute to acidic rainfall through complex reaction sequences. Nitrogen and oxygen combine during the high-temperature combustion of fuels in air to form nitrogen monoxide gas, which reacts with more oxygen to form nitrogen dioxide gas. In contact with water vapor, nitrogen dioxide forms aqueous nitric acid and more nitrogen monoxide. (a) Write balanced equations for these reactions. (b) Use the equations to write one overall balanced equation that does not include nitrogen monoxide and nitrogen dioxide. (c) How many metric tons (t) of nitric acid form when \(1350 \mathrm{t}\) of atmospheric nitrogen is consumed \((1 \mathrm{t}=1000 \mathrm{~kg}) ?\)

Cyanogen, \((\mathrm{CN})_{2},\) has been observed in the atmosphere of Titan, Saturn's largest moon, and in the gases of interstellar nebulas. On Earth, it is used as a welding gas and a fumigant. In its reaction with fluorine gas, carbon tetrafluoride and nitrogen trifluoride gases are produced. What mass (g) of carbon tetrafluoride forms when \(60.0 \mathrm{~g}\) of each reactant is used?

What is the difference between an empirical formula and a molecular formula? Can they ever be the same?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.