/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 18 An impurity sometimes found in \... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

An impurity sometimes found in \(\mathrm{Ca}_{3}\left(\mathrm{PO}_{4}\right)_{2}\) is \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) which is removed during the production of phosphorus as ferrophosphorus \(\left(\mathrm{Fe}_{2} \mathrm{P}\right) .\) (a) Why is this impurity troubling from an economic standpoint? (b) If 50 . metric tons (t) of crude \(\mathrm{Ca}_{3}\left(\mathrm{PO}_{4}\right)_{2}\) contain \(2.0 \% \mathrm{Fe}_{2} \mathrm{O}_{3}\) by mass and the overall yield of phosphorus is \(90 . \%\), how many metric tons of \(\mathrm{P}_{4}\) can be isolated?

Short Answer

Expert verified
The impurity increases production costs. You can isolate 8.802 metric tons of \(\text{P}_4\).

Step by step solution

01

Understand the Economic Impact

Impurities such as \(\text{Fe}_{2}\text{O}_3\) in \(\text{Ca}_3(\text{PO}_4)_2\) can lead to additional costs and processing steps to remove them. This increases the overall cost of production and can lead to lower yields of the desired product, \(\text{P}_{4}\). Additionally, the presence of impurities can reduce the purity and quality of \(\text{P}_{4}\), affecting its market value and utility.
02

Calculate the Mass of \(\text{Fe}_{2}\text{O}_3\) in Crude \(\text{Ca}_3(\text{PO}_4)_2\)

If 50 metric tons of crude \(\text{Ca}_3(\text{PO}_4)_2\) contain 2.0% \(\text{Fe}_{2}\text{O}_3\) by mass, first find the actual mass of \(\text{Fe}_{2}\text{O}_3}\) present: \[0.02 \times 50 \text{ metric tons} = 1 \text{ metric ton} \text{ of } \(\text{Fe}_{2}\text{O}_3\)\].
03

Determine the Mass of \text{Ca}_3(\text{PO}_4)_2 Without Impurities

Subtract the mass of \(\text{Fe}_{2}\text{O}_3\) from the total mass of the crude \(\text{Ca}_3(\text{PO}_4)_2\) to find the mass of \(\text{Ca}_3(\text{PO}_4)_2\) without impurities: \[50 \text{ metric tons} - 1 \text{ metric ton} = 49 \text{ metric tons of pure} \(\text{Ca}_3(\text{PO}_4)_2\).\]
04

Calculate the Amount of Phosphorus (\text{P}) in Pure \(\text{Ca}_3(\text{PO}_4)_2\)

Determine the molecular weight of \(\text{Ca}_3(\text{PO}_4)_2\):\ \[3 \times (40.08) + 2 \times (30.97 + 4 \times 16.00) = 310.18 \text{ g/mol}\]. Phosphorus (\text{P}) constitutes part of this molecular weight:\ \[\text{P:}(2 \times 30.97) = 61.94 \text{ g/mol}\]. Thus, the proportion of phosphorus in \(\text{Ca}_3(\text{PO}_4)_2\) is: \[ \frac{61.94}{310.18} \times 49 \text{ metric tons} = 9.78 \text{ metric tons of P}\].
05

Apply Yield Rate to Find Isolated \text{P}_4

Given that the overall yield of phosphorus is 90%, calculate the actual amount of \(\text{P}_4\) that can be isolated:\[0.90 \times 9.78 \text{ metric tons} = 8.802 \text{ metric tons} \text{ of P}_4\].

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Economic Impact of Impurities
Presence of impurities like \(\text{Fe}_2\text{O}_3\) in minerals such as \(\text{Ca}_3(\text{PO}_4)_2\) presents several economic challenges. Impurities necessitate additional processing steps to purify the product. This increases both time and cost for manufacturers. Furthermore, impurities lower the quality of the end product, which directly affects its market value. For instance, lower purity phosphorus (\text{P}_4) might not meet the stringent requirements for certain industrial applications, limiting its market potential and commanding a lower price.
Mass Calculation in Chemistry
Accurate mass calculations are crucial in stoichiometry to predict the amounts of reactants and products. To find the amount of impurity in a given sample, you calculate the percentage composition. For example, in 50 metric tons of crude \(\text{Ca}_3(\text{PO}_4)_2\) containing 2.0% \(\text{Fe}_2\text{O}_3\), the mass of \(\text{Fe}_2\text{O}_3\) is: \[0.02 \times 50 = 1\] metric ton. Next, to find the mass of the pure mineral, you subtract the mass of impurities: \[50 - 1 = 49\] metric tons of pure \(\text{Ca}_3(\text{PO}_4)_2\). Converting this to the amount of phosphorus (\text{P}) involves using molar mass ratios, where \[\text{Ca}_3(\text{PO}_4)_2\]\'s molar mass is 310.18 g/mol and phosphorus contributes 61.94 g/mol. Thus, from 49 metric tons of pure \(\text{Ca}_3(\text{PO}_4)_2\), the phosphorus content is: \[ \frac{61.94}{310.18} \times 49 = 9.78\] metric tons.
Yield Calculation in Production Processes
Yield calculation is vital to determine how much of a product can be recovered from a process. Even with precise mass calculations, yield inefficiencies due to factors like incomplete reactions and purification losses must be accounted for. In this case, with a 90% yield of phosphorus (\text{P}), from the 9.78 metric tons of phosphorus theoretically available, the actual isolated amount is: \[0.90 \times 9.78 = 8.802\] metric tons of \(\text{P}_4\). Yield calculations ensure realistic production predictions and help optimize processes to minimize losses.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Because of their different molar masses, \(\mathrm{H}_{2}\) and \(\mathrm{D}_{2}\) effuse at different rates (Section 5.5 ). (a) If it takes 16.5 min for \(0.10 \mathrm{~mol}\) of \(\mathrm{H}_{2}\) to effuse, how long does it take for \(0.10 \mathrm{~mol}\) of \(\mathrm{D}_{2}\) to do so in the same apparatus at the same \(T\) and \(P ?\) (b) How many effusion steps does it take to separate an equimolar mixture of \(\mathrm{D}_{2}\) and \(\mathrm{H}_{2}\) to \(99 \mathrm{~mol} \%\) purity?

(a) What are the three commercial products formed in the chlor-alkali process? (b) State an advantage and a disadvantage of using the mercurycell method for this process.

Elemental \(\mathrm{Li}\) and \(\mathrm{Na}\) are prepared by electrolysis of a molten salt, whereas \(\mathrm{K}, \mathrm{Rb},\) and \(\mathrm{Cs}\) are prepared by chemical reduction. (a) In general terms, explain why the alkali metals cannot be prepared by electrolysis of their aqueous salt solutions. (b) Use ionization energies (see the Family Portraits for Group \(1 \mathrm{~A}(1)\) in Section 14.3 and for Group \(2 \mathrm{~A}(2)\) in \(\operatorname{Section} 14.4)\) to explain why calcium should not be able to isolate \(\mathrm{Rb}\) from molten \(\operatorname{Rb} \mathrm{X}(\mathrm{X}=\) halide \()\) (c) Use physical properties to explain why calcium is used to isolate Rb from molten \(\mathrm{RbX}\). (d) Can Ca be used to isolate Cs from molten CsX? Explain.

Silicon is prepared by the reduction of \(\mathrm{K}_{2} \mathrm{SiF}_{6}\) with \(\mathrm{Al}\). Write the equation for this reaction. (Hint: Can \(\mathrm{F}^{-}\) be oxidized in this reaction? Can \(\mathrm{K}^{+}\) be reduced?

The lead(IV) oxide used in car batteries is prepared by coating an electrode plate with \(\mathrm{PbO}\) and then oxidizing it to lead dioxide \(\left(P b O_{2}\right)\). Despite its name, \(P b O_{2}\) has a nonstoichiometric mole ratio of lead to oxygen of about \(1 / 1.98 .\) In fact, the holes in the \(\mathrm{PbO}_{2}\) crystal structure due to missing \(\mathrm{O}\) atoms are responsible for the oxide's conductivity. (a) What is the mole \(\%\) of \(\mathrm{O}\) missing from the \(\mathrm{PbO}_{2}\) structure? (b) What is the molar mass of the nonstoichiometric compound?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.