Chapter 17: Problem 3
If there is no change in concentrations, why is the equilibrium state considered dynamic?
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Chapter 17: Problem 3
If there is no change in concentrations, why is the equilibrium state considered dynamic?
These are the key concepts you need to understand to accurately answer the question.
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Predict the effect of decreasing the container volume on the amounts of each reactant and product in the following reactions: (a) \(\mathrm{H}_{2}(g)+\mathrm{Cl}_{2}(g) \rightleftharpoons 2 \mathrm{HCl}(g)\) (b) \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{H}_{2} \mathrm{O}(l)\)
Balance each reaction and write its reaction quotient, \(Q_{c}\) (a) \(\mathrm{NO}_{2} \mathrm{Cl}(g) \rightleftharpoons \mathrm{NO}_{2}(g)+\mathrm{Cl}_{2}(g)\) (b) \(\mathrm{POCl}_{3}(g) \rightleftharpoons \mathrm{PCl}_{3}(g)+\mathrm{O}_{2}(g)\) (c) \(\mathrm{NH}_{3}(g)+\mathrm{O}_{2}(g) \rightleftharpoons \mathrm{N}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g)\)
The following molecular scenes depict the aqueous reaction \(2 \mathrm{D} \rightleftharpoons \mathrm{E},(\mathrm{D}\) is red and \(\mathrm{E}\) is blue \() .\) Each sphere represents \(0.0100 \mathrm{~mol}\), but the volume is \(1.00 \mathrm{~L}\) in scene \(\mathrm{A},\) whereas, in scenes \(\mathrm{B}\) and \(\mathrm{C},\) it is \(0.500 \mathrm{~L}\) (a) If the reaction in scene \(\mathrm{A}\) is at equilibrium, calculate \(K_{\mathrm{c}}\) (b) Are the reactions in scenes \(\mathrm{B}\) and \(\mathrm{C}\) at equilibrium? Which, if either, is not, and in which direction will it proceed?
Predict the effect of decreasing the container volume on the amounts of each reactant and product in the following reactions: (a) \(\mathrm{C}_{3} \mathrm{H}_{8}(g)+5 \mathrm{O}_{2}(g) \rightleftharpoons 3 \mathrm{CO}_{2}(g)+4 \mathrm{H}_{2} \mathrm{O}(l)\) (b) \(4 \mathrm{NH}_{3}(g)+3 \mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{~N}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)\)
Isolation of Group \(8 \mathrm{~B}(10)\) elements, used as industrial catalysts, involves a series of steps. For nickel, the sulfide ore is roasted in air: \(\mathrm{Ni}_{3} \mathrm{~S}_{2}(s)+\mathrm{O}_{2}(g) \rightleftharpoons \mathrm{NiO}(s)+\mathrm{SO}_{2}(g) .\) The metal oxide is reduced by the \(\mathrm{H}_{2}\) in water gas \(\left(\mathrm{CO}+\mathrm{H}_{2}\right)\) to impure \(\mathrm{Ni}: \mathrm{NiO}(s)+\mathrm{H}_{2}(g) \rightleftharpoons \mathrm{Ni}(s)+\mathrm{H}_{2} \mathrm{O}(g) .\) The \(\mathrm{CO}\) in water gas then reacts with the metal in the Mond process to form gaseous nickel carbonyl, \(\mathrm{Ni}(s)+\mathrm{CO}(g) \rightleftharpoons \mathrm{Ni}(\mathrm{CO})_{4}(g),\) which is sub- sequently decomposed to the metal. (a) Balance each of the three steps, and obtain an overall balanced equation for the conversion of \(\mathrm{Ni}_{3} \mathrm{~S}_{2}\) to \(\mathrm{Ni}(\mathrm{CO})_{4}\). (b) Show that the overall \(Q_{\mathrm{c}}\) is the product of the \(Q_{c}\) 's for the individual reactions.
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