Chapter 16: Problem 9
Give two reasons to measure initial rates in a kinetics study.
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Chapter 16: Problem 9
Give two reasons to measure initial rates in a kinetics study.
These are the key concepts you need to understand to accurately answer the question.
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What is the difference between a reaction intermediate and a transition state?
Does a catalyst increase reaction rate by the same means as a rise in temperature does? Explain.
How does an increase in pressure affect the rate of a gasphase reaction? Explain.
The overall equation and rate law for the gas-phase decomposition of dinitrogen pentoxide are \(2 \mathrm{~N}_{2} \mathrm{O}_{5}(g) \longrightarrow 4 \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g) \quad\) rate \(=k\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right]\) Which of the following can be considered valid mechanisms for the reaction? I One-step collision II \(2 \mathrm{~N}_{2} \mathrm{O}_{5}(g) \longrightarrow 2 \mathrm{NO}_{3}(g)+2 \mathrm{NO}_{2}(g) \quad[\) slow \(]\) \(2 \mathrm{NO}_{3}(g) \longrightarrow 2 \mathrm{NO}_{2}(g)+2 \mathrm{O}(g)\) [fast] \(2 \mathrm{O}(g) \longrightarrow \mathrm{O}_{2}(g)\) [fast] III \(\mathrm{N}_{2} \mathrm{O}_{5}(g) \rightleftharpoons \mathrm{NO}_{3}(g)+\mathrm{NO}_{2}(g)\) [fast] \(\mathrm{NO}_{2}(g)+\mathrm{N}_{2} \mathrm{O}_{5}(g) \longrightarrow 3 \mathrm{NO}_{2}(g)+\mathrm{O}(g) \quad\) [slow] \(\mathrm{NO}_{3}(g)+\mathrm{O}(g) \longrightarrow \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g) \quad[\) fast \(]\) \(\mathrm{IV} 2 \mathrm{~N}_{2} \mathrm{O}_{5}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g)+\mathrm{N}_{2} \mathrm{O}_{3}(g)+3 \mathrm{O}(g) \quad[\) fast \(]\) \(\mathrm{N}_{2} \mathrm{O}_{3}(g)+\mathrm{O}(g) \longrightarrow 2 \mathrm{NO}_{2}(g)\) [slow] \(2 \mathrm{O}(g) \longrightarrow \mathrm{O}_{2}(g) \quad[\) fast \(]\) \(\mathrm{V} \quad 2 \mathrm{~N}_{2} \mathrm{O}_{5}(g) \longrightarrow \mathrm{N}_{4} \mathrm{O}_{10}(g)\) [slow] \(\mathrm{N}_{4} \mathrm{O}_{10}(g) \longrightarrow 4 \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g)\) [fast]
Express the rate of this reaction in terms of the change in concentration of each of the reactants and products: $$ \mathrm{D}(g) \rightarrow \frac{3}{2} \mathrm{E}(g)+\frac{5}{2} \mathrm{~F}(g) $$ When [E] is increasing at \(0.25 \mathrm{~mol} / \mathrm{L}\) -s, how fast is [F] increasing?
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