/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 65 Predict whether each of the foll... [FREE SOLUTION] | 91Ó°ÊÓ

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Predict whether each of the following compounds is molecular or ionic: \((\mathbf{a}) \mathrm{HClO}_{4}(\mathbf{b}) \mathrm{CH}_{3} \mathrm{OCH}_{3}(\mathbf{c}) \mathrm{Mg}\left(\mathrm{NO}_{3}\right)_{2}(\mathbf{d}) \mathrm{H}_{2} \mathrm{~S}\) (e) \(\mathrm{TiCl}_{4}(\mathbf{f}) \mathrm{K}_{2} \mathrm{O}_{2}(\mathbf{g}) \mathrm{PCl}_{5}(\mathbf{h}) \mathrm{P}(\mathrm{OH})_{3} .\)

Short Answer

Expert verified
\( \begin{array}{ | l | l | } \hline \textbf{Compound} & \textbf{Classification} \\ \hline \mathrm{HClO}_{4} & \text{Molecular} \\ \hline \mathrm{CH}_{3}\mathrm{OCH}_{3} & \text{Molecular} \\ \hline \mathrm{Mg}\left(\mathrm{NO}_{3}\right)_{2} & \text{Ionic} \\ \hline \mathrm{H}_{2}\mathrm{S} & \text{Molecular} \\ \hline \mathrm{TiCl}_{4} & \text{Ionic} \\ \hline \mathrm{K}_{2}\mathrm{O}_{2} & \text{Ionic} \\ \hline \mathrm{PCl}_{5} & \text{Molecular} \\ \hline \mathrm{P}(\mathrm{OH})_{3} & \text{Molecular} \\ \hline \end{array} \)

Step by step solution

01

a) HClO4

: Hydrogen (H), chlorine (Cl), and oxygen (O) are non-metals. As a result, HClO4 is a molecular compound.
02

b) CH3OCH3

: Carbon (C), hydrogen (H), and oxygen (O) are non-metals. Therefore, CH3OCH3 is a molecular compound.
03

c) Mg(NO3)2

: Magnesium (Mg) is a metal, while nitrogen (N) and oxygen (O) are non-metals. Since we have a metal bonded to non-metals, Mg(NO3)2 is an ionic compound.
04

d) H2S

: Hydrogen (H) and sulfur (S) are non-metals. Therefore, H2S is a molecular compound.
05

e) TiCl4

: Titanium (Ti) is a metal, and chlorine (Cl) is a non-metal. Thus, TiCl4 is an ionic compound.
06

f) K2O2

: Potassium (K) is a metal, and oxygen (O) is a non-metal. As a result, K2O2 is an ionic compound.
07

g) PCl5

: Phosphorus (P) and chlorine (Cl) are non-metals. Therefore, PCl5 is a molecular compound.
08

h) P(OH)3

: Phosphorus (P), oxygen (O), and hydrogen (H) are non-metals. Thus, P(OH)3 is a molecular compound.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Non-metals
Non-metals are elements that generally lack the properties of metals. They are poor conductors of electricity and heat and have higher electronegativities, meaning they tend to attract electrons in a chemical bond. Non-metals can be found on the right side of the periodic table, and most of them exist as gases or solids under standard conditions.
Common non-metals in chemistry include:
  • Hydrogen (H)
  • Carbon (C)
  • Nitrogen (N)
  • Oxygen (O)
  • Phosphorus (P)
  • Sulfur (S)
  • Chlorine (Cl)
These elements often form covalent bonds where they share electrons with other non-metals, resulting in molecular compounds. For example, in compounds like \( ext{H}_2 ext{S} \) and \( ext{PCl}_5 \), all the participating atoms are non-metals, and they form molecules through shared pairs of electrons.
Exploring Metals
Metals are elements known for their malleability, ductility, and excellent conductivity of heat and electricity. Most metals are shiny and solid at room temperature, with only a few exceptions like mercury (Hg) which is liquid. Metals tend to lose electrons to form positive ions in chemical reactions.
Some key metallic elements include:
  • Magnesium (Mg)
  • Potassium (K)
  • Titanium (Ti)
Metals reside mainly on the left side and center of the periodic table. When metals react with non-metals, they often form ions by transferring electrons to non-metals. This process results in ionic compounds. For example, \( ext{Mg(NO}_3 ext{)}_2 \) involves magnesium transferring electrons to nitrogen and oxygen, creating an ionic structure.
Types of Chemical Bonds
Chemical bonds come in different forms, primarily ionic and covalent, depending on the elements involved and their ability to gain, lose, or share electrons.
Ionic bonds occur between metals and non-metals. In this type of bond, metals lose electrons to become positively charged ions, while non-metals gain those electrons to become negatively charged ions. This electron transfer creates an electrostatic attraction between the ions. Compounds such as \( ext{TiCl}_4 \) and \( ext{K}_2 ext{O}_2 \) are examples of ionic compounds, where metals and non-metals form this type of bond.
Covalent bonds generally occur between non-metallic elements. In these bonds, electrons are shared between atoms, allowing each to achieve a stable electron configuration. Such sharing often leads to the formation of molecular compounds. Examples include \( ext{CH}_3 ext{OCH}_3 \) and \( ext{P(OH)}_3 \) where non-metal atoms are bonded through shared electron pairs. Understanding these differences helps predict and explain the properties of various compounds.

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Most popular questions from this chapter

Name each of the following chlorides. Assuming that the compounds are ionic, what charge is associated with the metallic element in each case? (a) \(\mathrm{AgCl},(\mathbf{b}) \mathrm{TiCl}_{4},(\mathbf{c}) \operatorname{Ir} \mathrm{C} 1_{3},\) (d) \(\mathrm{LiCl}\).

From the following list of elements \(-\mathrm{Mg}, \mathrm{Li}, \mathrm{T}, \mathrm{Pb}, \mathrm{Se}, \mathrm{Cl}, \mathrm{Xe}, \mathrm{Si},\) C-pick the one that best fits each description. Use each element only once: (a) an alkali metal, \((\mathbf{b})\) an alkaline earth metal, \((\mathbf{c})\) a noble gas, (d) a halogen, \((\mathbf{e})\) a metalloidin group \(14,(\mathbf{f})\) a nonmetal listed in group \(14,(\mathbf{g})\) a metal that forms a \(3+\) ion, \((\mathbf{h})\) a nonmetal that forms a 2 - ion, (i) an element that is used as radiation shielding.

Fill in the blanks in the following table: $$ \begin{array}{l|l|l|l|} \hline \text { Cation } & \text { Anion } & \text { Formula } & \text { Name } \\\ \hline \mathrm{Ni}^{2+} & \mathrm{CH}_{3} \mathrm{COO} & & \text { Sodium carbonate } \\ & & & \\ \mathrm{Ca}^{2+} & \mathrm{F}^{-} & & \\ & & \mathrm{Cu}\left(\mathrm{ClO}_{4}\right)_{2} & \\ & & & \\ & & & \\ \hline \end{array} $$

Mass spectrometry is more often applied to molecules than to atoms. We will see in Chapter 3 that the molecular weight of a molecule is the sum of the atomic weights of the atoms in the molecule. The mass spectrum of \(\mathrm{H}_{2}\) is taken under conditions that prevent decomposition into \(\mathrm{H}\) atoms. The two naturally occurring isotopes of hydrogen are \({ }^{1} \mathrm{H}\) (atomic mass \(=1.00783 \mathrm{u}\); abundance \(\left.99.9885 \%\right)\) and \({ }^{2} \mathrm{H}\) (atomic mass \(=2.01410 \mathrm{u}\); abundance \(\left.0.0115 \%\right)\). (a) How many peaks will the mass spectrum have? (b) Give the relative atomic masses of each of these peaks. (c) Which peak will be the largest, and which the smallest?

Answer the following questions without referring to Table 2.1: (a) What are the main subatomic particles that make up the atom? (b) What is the relative charge (in multiples of the electronic charge) of each of the particles? (c) Which of the particles is the most massive? (d) Which is the least massive?

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