/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 99 Indicate whether each of the fol... [FREE SOLUTION] | 91影视

91影视

Indicate whether each of the following statements is correct or incorrect. (a) Every Br酶nsted-Lowry acid is also a Lewis acid. (b) Every Lewis acid is also a Bronsted-Lowry acid. (c) Conjugate acids of weak bases produce more acidic solutions than conjugate acids of strong bases. (d) \(\mathrm{K}^{+}\) ion is acidic in water because it causes hydrating water molecules to become more acidic. (e) The percent ionization of a weak acid in water increases as the concentration of acid decreases.

Short Answer

Expert verified
(a) Correct (b) Incorrect (c) Correct (d) Incorrect (e) Correct

Step by step solution

01

Statement (a)

Every Br酶nsted-Lowry acid is also a Lewis acid. To identify whether this statement is correct or incorrect, let's define Br酶nsted-Lowry and Lewis acids. - Br酶nsted-Lowry acids are substances that can donate a proton (H鈦). - Lewis acids are substances that can accept an electron pair. Since a Br酶nsted-Lowry acid can donate a proton, it is also considered a Lewis acid as it can accept an electron pair during the donation of its proton. Thus, this statement is correct.
02

Statement (b)

Every Lewis acid is also a Bronsted-Lowry acid. To examine this statement, let's again recall the definitions of Br酶nsted-Lowry and Lewis acids. It's important to consider some examples of Lewis acids that cannot donate a proton, like aluminum trichloride (AlCl鈧) and boron trichloride (BCl鈧). These compounds can accept an electron pair but cannot donate a proton, as they don't have any protons available. Therefore, not all Lewis acids are Br酶nsted-Lowry acids. This statement is incorrect.
03

Statement (c)

Conjugate acids of weak bases produce more acidic solutions than conjugate acids of strong bases. This statement is true because conjugate acids of weak bases have a higher tendency to donate protons (due to their weaker basic nature) than conjugate acids of strong bases (which have very weak acidic nature). Therefore, the solutions formed by conjugate acids of weak bases will be more acidic. This statement is correct.
04

Statement (d)

\(\mathrm{K}^{+}\) ion is acidic in water because it causes hydrating water molecules to become more acidic. When a \(\mathrm{K}^{+}\) ion interacts with water molecules, it forms a hydration complex, but it does not change the acidity of water. The \(\mathrm{K}^{+}\) ion cannot donate a proton to water and, thus, does not cause the hydrating water molecules to become more acidic. This statement is incorrect.
05

Statement (e)

The percent ionization of a weak acid in water increases as the concentration of acid decreases. This statement is true as the percentage ionization of a weak acid is inversely proportional to the concentration of the acid solution. When the concentration of the weak acid in water decreases, the percent ionization increases, which essentially means that more acid particles are ionized in a diluted solution than in a more concentrated solution. This statement is correct. In conclusion: - Statement (a): Correct - Statement (b): Incorrect - Statement (c): Correct - Statement (d): Incorrect - Statement (e): Correct

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Br酶nsted-Lowry Acids
When diving into the world of acid-base chemistry, understanding Br酶nsted-Lowry acids is essential. These acids are substances that can donate a proton, which is a hydrogen ion symbolized as H鈦. When they donate this proton to another substance, they undergo a transformation into what we call a conjugate base.
Br酶nsted-Lowry acids play a pivotal role in chemical reactions, acting as proton donors in various acid-base interactions. For example, when hydrochloric acid (HCl) donates its proton to water, it forms a hydronium ion (H鈧僌鈦) and a chloride ion (Cl鈦).
This framework of acid-base reactions helps in understanding how substances interact in solutions, allowing scientists to predict and control chemical behavior effectively.
  • Proton donor: Main characteristic of a Br酶nsted-Lowry acid.
  • Forms a conjugate base: The remaining part after the proton is donated.
Lewis Acids
Unlike Br酶nsted-Lowry acids, Lewis acids focus on the acceptance of electron pairs rather than the donation of protons. This broader definition helps to categorize substances that don't necessarily donate protons, like some metals.
A common example is aluminum trichloride (AlCl鈧), which can accept an electron pair and form bonds without the need to interact with hydrogen ions. Lewis acids are often used in catalysis and other chemical processes where the transfer of electrons plays a crucial role.
Understanding Lewis acids expands the scope of chemistry beyond traditional definitions of acids and bases, providing a more inclusive picture of chemical interactions.
  • Electron pair acceptor: The main feature of Lewis acids.
  • Allows for wider categorization: Includes substances like metal ions.
Conjugate Acids
Conjugate acids are formed when a base gains a proton. This concept is a key part of Br酶nsted-Lowry theory, showcasing the dynamic nature of acids and bases exchanging protons.
The strength of a conjugate acid depends on the strength of its original base. Generally, conjugate acids of weak bases are more likely to donate protons, making their solutions more acidic compared to conjugate acids of strong bases.
This relationship helps predict the behavior of solutions and understand the balance between conjugate acids and bases in a reaction.
  • Forms when base gains a proton: Key transformation defining conjugate acids.
  • Influences solution acidity: Stronger acids form from weaker bases.
Ionization
Ionization refers to the process by which a molecule breaks apart into ions. In acid-base chemistry, this often relates to an acid releasing protons into a solution.
The extent of ionization is important for determining how strong or weak an acid is. A strong acid like hydrochloric acid fully ionizes in water, while a weak acid like acetic acid only partially ionizes, leading to different behaviors in solution.
Understanding ionization helps predict how substances will interact in various concentrations and conditions, providing insight into their chemical properties and potential reactions.
  • Process of forming ions: Essential for understanding acid strength.
  • Affects solution behavior: Varies between strong and weak acids.
Acidic Solutions
An acidic solution contains a higher concentration of hydronium ions (H鈧僌鈦) than hydroxide ions (OH鈦). This imbalance is what gives the solution its characteristic acidic properties.
The pH scale measures the acidity of a solution, with lower values indicating higher acidity. Solutions of strong acids have lower pH values due to complete ionization, whereas solutions of weak acids have higher pH values as they only partially ionize.
Different factors, such as concentration and the nature of the acid, influence the acidity of a solution. Understanding these can help control and utilize acids in various applications ranging from industrial processes to everyday uses.
  • Defined by ion concentration: More H鈧僌鈦 than OH鈦.
  • Measured by pH: Lower pH indicates higher acidity.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Identify the Br酶nsted-Lowry acid and the Br酶nstedLowry base on the left side of each equation, and also identify the conjugate acid and conjugate base of each on the right side. $$ \begin{array}{l} \text { (a) } \mathrm{HBrO}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{H}_{3} \mathrm{O}^{+}(a q)+\mathrm{BrO}^{-}(a q) \\\ \text { (b) } \mathrm{HSO}_{4}^{-}(a q)+\mathrm{HCO}_{3}^{-}(a q) \rightleftharpoons \mathrm{SO}_{4}^{2-}(a q)+\mathrm{H}_{2} \mathrm{CO}_{3}(a q) \\ \text { (c) } \mathrm{HSO}_{3}^{-}(a q)+\mathrm{H}_{3} \mathrm{O}^{+}(a q) \rightleftharpoons \mathrm{H}_{2} \mathrm{SO}_{3}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \end{array} $$

An unknown salt is either \(\mathrm{NaF}, \mathrm{NaCl}\), or \(\mathrm{NaOCl}\). When 0.050 mol of the salt is dissolved in water to form 0.500 L of solution, the pH of the solution is 8.08 . What is the identity of the salt?

At the boiling point of water \(\left(100^{\circ} \mathrm{C}\right), K_{w}=5.6 \times 10^{-13} .\) Calculate \(\left[\mathrm{H}^{+}\right]\) and \(\left[\mathrm{OH}^{-}\right]\) for a neutral solution at this temperature.

Carbon dioxide in the atmosphere dissolves in raindrops to produce carbonic acid \(\left(\mathrm{H}_{2} \mathrm{CO}_{3}\right)\), causing the pH of clean, unpolluted rain to range from about 5.2 to 5.6 . What are the ranges of \(\left[\mathrm{H}^{+}\right]\) and \(\left[\mathrm{OH}^{-}\right]\) in the raindrops?

Ammonia, \(\mathrm{NH}_{3}\), acts as an Arrhenius base, a Br酶nsted-Lowry base, and a Lewis base, in aqueous solution. Write out the reaction \(\mathrm{NH}_{3}\) undergoes with water and explain what properties of ammonia correspond to each of the three definitions of "base."

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.