Chapter 22: Problem 32
Write the chemical formula for each of the following, and indicate the oxidation state of the halogen or noble-gas atom in each: (a) krypton tetrafluoride, (b) hexafluoroantimonate ion, (c) sodium hypoiodite, (d) perbromic acid, (e) aluminum perchlorate, (f) iron(II) iodite.
Short Answer
Expert verified
(a) KrF鈧, Kr +4; (b) [SbF鈧哴鈦, Sb +5; (c) NaIO, I +1; (d) HBrO鈧, Br +7; (e) Al(ClO鈧)鈧, Cl +7; (f) Fe(IO鈧)鈧, I +3.
Step by step solution
01
Determine the Chemical Formula for Krypton Tetrafluoride
Krypton tetrafluoride consists of one krypton (Kr) atom and four fluorine (F) atoms. The prefix 'tetra-' indicates four fluorine atoms. The chemical formula is KrF鈧.
02
Identify the Oxidation State of Krypton in KrF鈧
Fluorine has an oxidation state of -1. There are four fluorines: 4 x (-1) = -4. To balance this, krypton must have an oxidation state of +4 to make the compound neutral. Thus, krypton in KrF鈧 is in the +4 oxidation state.
03
Determine the Chemical Formula for Hexafluoroantimonate Ion
Hexafluoroantimonate is an ion with one antimony (Sb) and six fluorine (F) atoms. The formula is [SbF鈧哴鈦. The charge on this complex ion is -1.
04
Identify the Oxidation State of Antimony in [SbF鈧哴鈦
Fluorine has an oxidation state of -1. Thus, 6 x (-1) = -6. For the ion to have an overall charge of -1, antimony must have an oxidation state of +5. Thus, the oxidation state of Sb in [SbF鈧哴鈦 is +5.
05
Determine the Chemical Formula for Sodium Hypoiodite
Sodium hypoiodite consists of sodium (Na) and hypoiodite (IO鈦). The formula is NaIO. Sodium's charge is +1, balancing the charge on hypoiodite.
06
Identify the Oxidation State of Iodine in NaIO
Oxygen has an oxidation state of -2. Since there is one sodium with +1, iodine must be in the +1 oxidation state to balance with the hypoiodite ion IO鈦.
07
Determine the Chemical Formula for Perbromic Acid
Perbromic acid consists of one hydrogen (H), one bromine (Br), and four oxygen (O) atoms. The prefix 'per-' indicates the highest oxidation state of bromine in oxoacids. The formula is HBrO鈧.
08
Identify the Oxidation State of Bromine in HBrO鈧
Oxygen has an oxidation state of -2; thus, 4 x (-2) = -8. With hydrogen's +1 oxidation state, bromine must have a +7 to balance, giving a neutral compound. Thus, the oxidation state of Br in HBrO鈧 is +7.
09
Determine the Chemical Formula for Aluminum Perchlorate
Aluminum perchlorate consists of aluminum (Al) and perchlorate ion (ClO鈧勨伝). One aluminum bonds with three perchlorate ions, forming Al(ClO鈧)鈧. This ratio balances the +3 charge of Al with the -1 charge on each perchlorate ion.
10
Identify the Oxidation State of Chlorine in ClO鈧勨伝 (Perchlorate Ion)
In perchlorate ion ClO鈧勨伝, each oxygen has a -2 oxidation state, resulting in 4 x (-2) = -8. Thus, chlorine must have a +7 oxidation state to balance with the ion's -1 charge.
11
Determine the Chemical Formula for Iron(II) Iodite
Iron (II) iodite consists of iron with a +2 oxidation state and iodite, which is IO鈧傗伝. The formula for this compound is Fe(IO鈧)鈧, as two iodite ions are needed to balance the +2 charge of iron.
12
Identify the Oxidation State of Iodine in IO鈧傗伝
Oxygen has an oxidation state of -2, so in IO鈧傗伝, 2 x (-2) = -4. For the ion to have a -1 charge, iodine must have an oxidation state of +3. So, iodine in IO鈧傗伝 is in the +3 oxidation state.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Oxidation States
Understanding oxidation states is crucial when working with chemical formulas. Oxidation states, also known as oxidation numbers, indicate the degree of oxidation of an atom within a molecule. It helps determine how electrons are distributed among atoms. For instance, in the chemical compound krypton tetrafluoride (KrF鈧), the oxidation state of krypton is +4. This is because each of the four fluorine atoms, which are more electronegative, has an oxidation state of -1, leading to an overall -4 charge that's balanced by krypton's +4.
Similarly, in the hexafluoroantimonate ion \([SbF鈧哴^{-}\), the six fluorines contribute a total of -6, and antimony's +5 oxidation state causes the ion to have a net charge of -1.
To identify oxidation states, remember:
Similarly, in the hexafluoroantimonate ion \([SbF鈧哴^{-}\), the six fluorines contribute a total of -6, and antimony's +5 oxidation state causes the ion to have a net charge of -1.
To identify oxidation states, remember:
- The sum of oxidation states in a neutral compound is zero.
- For a charged ion, the sum of oxidation states equals the ion's overall charge.
- Common oxidation states include: F (-1), O (-2), H (+1 in most cases).
Halogen Compounds
Halogen compounds are formed when halogen elements like fluorine, chlorine, bromine, and iodine bond with other elements. These compounds often contain one or more halogen elements combined with metals or non-metals. They can carry varied oxidation states depending on their structure and the atoms they're bonded to.
For example, in sodium hypoiodite ( NaIO ), iodine is bonded with sodium and oxygen. Here, iodine has a +1 oxidation state, balancing the negative charge from oxygen and the positive charge from sodium.
To understand halogen compounds better, keep in mind:
For example, in sodium hypoiodite ( NaIO ), iodine is bonded with sodium and oxygen. Here, iodine has a +1 oxidation state, balancing the negative charge from oxygen and the positive charge from sodium.
To understand halogen compounds better, keep in mind:
- Halogens are highly electronegative and often appear with negative oxidation states.
- Their interactions can result in acids, salts, or more complex ions.
- Prefixes such as 'per-' or 'hypo-' denote the oxidation states or numbers of atoms in the compound.
Chemical Nomenclature
Chemical nomenclature is a systematic way of naming chemical compounds. The goal is to ensure that each name accurately describes a specific compound, sometimes indicating the structure and oxidation states as well.
For example, krypton tetrafluoride ( KrF鈧 ) is named for its components: one krypton and four fluorine atoms, with the prefix 'tetra-' indicating four of the latter.
For more complex ions like hexafluoroantimonate ( [SbF鈧哴鈦 ), the 'hexa-' prefix indicates six fluorides bonded to antimony.
Here are some common rules:
For example, krypton tetrafluoride ( KrF鈧 ) is named for its components: one krypton and four fluorine atoms, with the prefix 'tetra-' indicating four of the latter.
For more complex ions like hexafluoroantimonate ( [SbF鈧哴鈦 ), the 'hexa-' prefix indicates six fluorides bonded to antimony.
Here are some common rules:
- Use prefixes to indicate the number of atoms: mono-, di-, tri-, tetra-, etc.
- Use suffixes like '-ide' for simple anions or '-ate'/'-ite' for oxyanions.
- Cations name usually comes first followed by anions.
Lewis Structures
Lewis structures are visual representations that show how atoms are bonded within a molecule. They provide insights into molecular geometry, bonding, and can help determine oxidation states.
To draw a Lewis structure, start by counting all valence electrons for the atoms involved, and then arrange them to satisfy the octet rule for each atom (or duet, for hydrogen).
For instance, in perbromic acid (HBrO鈧), bromine is bonded to four oxygens and one hydrogen, with the Lewis structure showing double bonds for oxygen atoms where needed, accomplishing the respective octet requirement.
Remember these steps:
To draw a Lewis structure, start by counting all valence electrons for the atoms involved, and then arrange them to satisfy the octet rule for each atom (or duet, for hydrogen).
For instance, in perbromic acid (HBrO鈧), bromine is bonded to four oxygens and one hydrogen, with the Lewis structure showing double bonds for oxygen atoms where needed, accomplishing the respective octet requirement.
Remember these steps:
- Count total valence electrons.
- Place electron pairs to form bonds and fill outer shells.
- Use dots to represent electrons, lines for bonds, and adjust for formal charges and resonance if needed.