Chapter 22: Problem 42
Write the chemical formula for each of the following compounds, and indicate the oxidation state of the group 16 elements in each: (a) selenious acid, (b) sulphur trioxide, \((\mathbf{c})\) selenium dichloride, \((\mathbf{d})\) aluminium selenide, (e) iron(II) sulfate, (f) tellurium trioxide.
Short Answer
Expert verified
(a) H鈧係eO鈧, Se +4; (b) SO鈧, S +6; (c) SeCl鈧, Se +2; (d) Al鈧係e鈧, Se -2; (e) FeSO鈧, S +6; (f) TeO鈧, Te +6.
Step by step solution
01
Determine the Chemical Formula for Selenious Acid
Selenious acid is composed of selenium, oxygen, and hydrogen. The general formula for acids like selenious acid is H鈧俋鈧鈧, where X is the group 16 element. For selenious acid, X is selenium (Se). Therefore, the chemical formula of selenious acid is H鈧係eO鈧.
02
Find the Oxidation State of Selenium in Selenious Acid
In H鈧係eO鈧, each hydrogen has a +1 oxidation state, and each oxygen has a -2 oxidation state. Let's assume the oxidation state of selenium is x. Set up the equation based on the conservation of charge: \(2(+1) + x + 3(-2) = 0\). Solving gives \(x = +4\). The oxidation state of selenium in selenious acid is +4.
03
Determine the Chemical Formula for Sulphur Trioxide
Sulphur trioxide consists of sulphur and oxygen. The chemical formula is SO鈧.
04
Find the Oxidation State of Sulphur in Sulphur Trioxide
In SO鈧, each oxygen has a -2 oxidation state. Let the oxidation state of sulphur be y. Set up the equation: \(y + 3(-2) = 0\). Solving gives \(y = +6\). Thus, the oxidation state of sulphur in sulphur trioxide is +6.
05
Determine the Chemical Formula for Selenium Dichloride
Selenium dichloride consists of selenium and chlorine. The chemical formula is SeCl鈧.
06
Find the Oxidation State of Selenium in Selenium Dichloride
In SeCl鈧, each chlorine has a -1 oxidation state. Let the oxidation state of selenium be z. Set up the equation: \(z + 2(-1) = 0\). Solving gives \(z = +2\). Thus, the oxidation state of selenium in selenium dichloride is +2.
07
Determine the Chemical Formula for Aluminium Selenide
Aluminium selenide consists of aluminium and selenium. The formula for this type of compound is Al鈧係e鈧.
08
Find the Oxidation State of Selenium in Aluminium Selenide
In Al鈧係e鈧, assuming the oxidation state of selenium is a. The oxidation state of aluminium is known to be +3. Use the equation: \(2(+3) + 3a = 0\). Solving gives \(a = -2\). Therefore, the oxidation state of selenium in aluminium selenide is -2.
09
Determine the Chemical Formula for Iron(II) Sulfate
Iron(II) sulfate is composed of ferrous iron and sulfate ions. The chemical formula is FeSO鈧.
10
Find the Oxidation State of Sulfur in Iron(II) Sulfate
In FeSO鈧, the sulfate ion is SO鈧劼测伝. Assuming the oxidation state of sulfur is b: \(b + 4(-2) = -2\). Solving gives \(b = +6\). The oxidation state of sulfur in iron(II) sulfate is +6.
11
Determine the Chemical Formula for Tellurium Trioxide
Tellurium trioxide consists of tellurium and oxygen. The chemical formula is TeO鈧.
12
Find the Oxidation State of Tellurium in Tellurium Trioxide
In TeO鈧, each oxygen has a -2 oxidation state. Let the oxidation state of tellurium be c. Set the equation: \(c + 3(-2) = 0\). Solving gives \(c = +6\). Therefore, the oxidation state of tellurium in tellurium trioxide is +6.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Oxidation States
The concept of oxidation states is essential in understanding how elements participate in chemical reactions. In simple terms, an oxidation state reflects the degree of oxidation (loss of electrons) or reduction (gain of electrons) an atom has undergone in a compound. It's assigned based on a set of rules:
- Pure elements have an oxidation state of 0. For example, elemental oxygen, O鈧, has an oxidation state of 0.
- For monoatomic ions, the oxidation state equals the ion's charge. An Na鈦 ion, for example, has an oxidation state of +1.
- The sum of oxidation states in a neutral compound is 0; in ions, it matches the ion's charge.
Group 16 Elements
Group 16 elements, also known as the chalcogens, include oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and polonium (Po). These elements share similar properties, being part of the same periodic table group. Generally, they are known for forming compounds with elements from other groups, often exhibiting -2 oxidation states, though they can have varying states depending on their chemical environment.
Attributes of these elements include:
Attributes of these elements include:
- Nonmetal characteristics, particularly oxygen and sulfur.
- Increasing metallic character down the group (selenium to polonium).
Inorganic Chemistry
Inorganic chemistry is the branch studying inorganic compounds, which include metals, minerals, and organometallic compounds. It explores a broad range of substances that aren't based on carbon-hydrogen bonds, unlike organic chemistry. Central to the field is the understanding of chemical bonds, ionic, covalent, and metallic, reflecting the interactions between various elements.
This branch covers many topics, such as:
This branch covers many topics, such as:
- The periodic table and the behavior of different groups of elements.
- The study of crystal structures, polymers, and coordination compounds.
- Catalysis and materials chemistry, focusing on how substances like metals can aid in chemical reactions.
Compound Naming
Properly naming chemical compounds is fundamental in chemistry, facilitating clear communication of their compositions and structures. Various rules and conventions have been established, depending on the type of compound:
- Binary compounds (comprised of two elements) are named using the element names with appropriate suffixes or prefixes, as in selenium dichloride (SeCl鈧).
- Acids are named based on their anion forms (e.g., H鈧係eO鈧 is known as selenious acid because it forms selenite anions).
- Compounds with metals and nonmetals often indicate the metal's oxidation state with Roman numerals; e.g., iron(II) sulfate (FeSO鈧).
Chemical Equations
Chemical equations are symbolic representations of chemical reactions, showing the reactants, products, and their proportions. Equations obey the law of conservation of mass, which states that atoms can't be created or destroyed during a reaction, only rearranged.
An equation consists of:
An equation consists of:
- Reactants, the starting substances, appearing on the left.
- Products, the substances formed, appearing on the right.
- An arrow ( \(\rightarrow\)) indicating the direction of the reaction.