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(a) Give the conjugate base of the following Br酶nsted Lowry acids: \((\mathbf{i}) \mathrm{H}_{2} \mathrm{PO}_{4}^{-},(\mathbf{i i}) \mathrm{HBr}\). (b) Give the conjugate acid of the following Br酶nsted-Lowry bases: \((\mathbf{i}) \mathrm{CN}^{-},(\mathbf{i i}) \mathrm{HSO}_{4}^{-}\).

Short Answer

Expert verified
(a) \(\text{Conjugate bases: } \mathrm{HPO}_{4}^{2-}, \mathrm{Br}^{-}\); (b) \(\text{Conjugate acids: } \mathrm{HCN}, \mathrm{H}_2\mathrm{SO}_{4}\).

Step by step solution

01

Identify the Conjugate Base Definition

The conjugate base of a Br酶nsted-Lowry acid is formed by removing one proton (H鈦) from the acid. This will result in a species with one less positive charge.
02

Find the Conjugate Base of \(\mathrm{H}_{2} \mathrm{PO}_{4}^{-}\)

Remove one \(\text{H}^+\) ion from \(\mathrm{H}_{2} \mathrm{PO}_{4}^{-}\). This gives \(\mathrm{HPO}_{4}^{2-}\), which is the conjugate base.
03

Find the Conjugate Base of \(\mathrm{HBr}\)

Remove one \(\text{H}^+\) ion from \(\mathrm{HBr}\). This gives \(\mathrm{Br}^{-}\), which is the conjugate base.
04

Identify the Conjugate Acid Definition

The conjugate acid of a Br酶nsted-Lowry base is formed by adding one proton (H鈦) to the base. This addition of a proton results in a species with one more positive charge.
05

Find the Conjugate Acid of \(\mathrm{CN}^{-}\)

Add one \(\text{H}^+\) ion to \(\mathrm{CN}^{-}\). This gives \(\mathrm{HCN}\), which is the conjugate acid.
06

Find the Conjugate Acid of \(\mathrm{HSO}_{4}^{-}\)

Add one \(\text{H}^+\) ion to \(\mathrm{HSO}_{4}^{-}\). This gives \(\mathrm{H}_2\mathrm{SO}_{4}\), which is the conjugate acid.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Br酶nsted-Lowry acids
Br酶nsted-Lowry acids are substances that can donate a proton, represented as \( ext{H}^+\), to another compound. In simpler terms, they actively give away a proton to facilitate a chemical reaction. This act of donating protons makes them central players in proton transfer reactions.
In the context of conjugate acid-base pairs, a Br酶nsted-Lowry acid, after losing a proton, turns into a conjugate base. For instance, when \( \mathrm{H}_2 \mathrm{PO}_4^- \) donates a proton, it transforms into \( \mathrm{HPO}_4^{2-} \), its conjugate base. Here, \( \mathrm{HBr} \) changes to \( \mathrm{Br}^- \) upon losing a proton. Such transformations highlight the dynamic nature of acids in chemical reactions.
Key properties of Br酶nsted-Lowry acids include:
  • Act as proton donors
  • Form conjugate bases upon donating a proton
  • Play pivotal roles in acid-base reactions
Br酶nsted-Lowry bases
Br酶nsted-Lowry bases are substances that can accept a proton from another compound. When they gain this proton, they transform into their conjugate acids. This transformation demonstrates their role as proton acceptors in chemical reactions. For example, when \( \mathrm{CN}^- \) accepts a proton, it becomes \( \mathrm{HCN} \), its conjugate acid. Similarly, \( \mathrm{HSO}_4^- \) becomes \( \mathrm{H}_2\mathrm{SO}_4 \) after gaining a proton.
Here are a few characteristics of Br酶nsted-Lowry bases:
  • Serve as proton acceptors
  • Form conjugate acids upon accepting a proton
  • Essential components in neutralizing acids in reactions

By understanding these properties, you can better appreciate how bases interact with acids during proton transfer processes.
proton transfer reactions
Proton transfer reactions are a fundamental type of chemical reaction involving the transfer of protons between a donor and an acceptor. In this context, the donor is the Br酶nsted-Lowry acid, while the acceptor is the Br酶nsted-Lowry base. The transferred proton changes one substance into its conjugate base and the other into its conjugate acid.
These reactions are crucial in many biological and chemical processes. For example, during digestion, stomach acids donate protons to substances in food, aiding in their breakdown. In laboratory settings, these reactions are central to titrations, where acids and bases neutralize each other.
Key concepts to remember about proton transfer reactions include:
  • Involve the transfer of protons between acids and bases
  • Result in the formation of conjugate acid-base pairs
  • Influence the pH and reactivity of solutions

Understanding proton transfer reactions allows us to predict the outcomes of acid-base interactions in various contexts.

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Most popular questions from this chapter

Which, if any, of the following statements are true? (a) The stronger the base, the smaller the \(\mathrm{p} K_{b}\). (b) The stronger the base, the larger the \(\mathrm{p} K_{b}\). (c) The stronger the base, the smaller the \(K_{b}\). (d) The stronger the base, the larger the \(K_{b}\). (e) The stronger the base, the smaller the \(\mathrm{p} K_{a}\) of its conjugate acid. (f) The stronger the base, the larger the \(\mathrm{pK}_{a}\) of its conjugate acid.

Write the chemical equation and the \(K_{b}\) expression for the reaction of each of the following bases with water: (a) propylamine, \(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} ;\) (b) monohydrogen phosphate ion, \(\mathrm{HPO}_{4}^{2-} ;(\mathbf{c})\) benzoate ion, \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CO}_{2}^{-}\)

(a) Write an equation for the react ion in which \(\mathrm{HSO}_{4}^{-}(a q)\) acts as a base in \(\mathrm{H}_{2} \mathrm{O}(l) .\) (b) Write an equation for the reaction in which \(\mathrm{HSO}_{4}^{-}(a q)\) acts as an acid in \(\mathrm{H}_{2} \mathrm{O}(I)\) (c) What is the conjugate acid of \(\mathrm{HSO}_{4}^{-}(a q) ?\) What is its conjugate base?

Predict the stronger acid in each pair: (a) HCl or HF; (b) \(\mathrm{H}_{3} \mathrm{PO}_{4}\) or \(\mathrm{H}_{3} \mathrm{AsO}_{4} ;\) (c) \(\mathrm{HBrO}_{3}\) or \(\mathrm{HBrO}_{2}\) (d) \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}\) or \(\mathrm{HC}_{2} \mathrm{O}_{4} \overline{;} ;\) (e) benzoic acid \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COOH}\right)\) or phenol \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}\right)\).

The active ingredient in aspirin is acetylsalicylic acid \(\left(\mathrm{HC}_{9} \mathrm{H}_{7} \mathrm{O}_{4}\right)\), a monoprotic acid with \(K_{a}=3.3 \times 10^{-4}\) at \(25^{\circ} \mathrm{C}\). What is the \(\mathrm{pH}\) of a solution obtained by dissolving one regular aspirin tablet, containing \(100 \mathrm{mg}\) of acetylsalicylic acid, in \(200 \mathrm{~mL}\) of water?

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