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Commercial concentrated aqueous ammonia is \(28 \% \mathrm{NH}_{3}\) by mass and has a density of \(0.90 \mathrm{~g} / \mathrm{mL}\). What is the molarity of this solution?

Short Answer

Expert verified
The molarity of the ammonia solution is approximately 14.80 mol/L.

Step by step solution

01

Calculate the Mass of NH3

Calculate the mass of ammonia, \( \mathrm{NH}_{3} \), in grams present in 100 grams of the solution. Since the solution is \( 28\% \) \( \mathrm{NH}_{3} \) by mass, this means there are \( 28 \) grams of \( \mathrm{NH}_{3} \) in 100 grams of the solution.
02

Determine the Volume of the Solution

Since the density of the solution is given as \( 0.90 \mathrm{~g/mL} \), use this to determine the volume of the 100 grams of the solution. Volume \( V \) is calculated as \( V = \frac{\text{mass}}{\text{density}} = \frac{100 \, \mathrm{g}}{0.90 \, \mathrm{g/mL}} = 111.11 \, \mathrm{mL} \).
03

Convert Volume from mL to L

Convert the volume from milliliters to liters since molarity requires volume in liters. So, \( 111.11 \, \mathrm{mL} = 0.11111 \, \mathrm{L} \).
04

Calculate Moles of NH3

Using the molar mass of \( \mathrm{NH}_{3} \) (which is approximately \( 17.03 \, \mathrm{g/mol} \)), calculate the number of moles of \( \mathrm{NH}_{3} \) present. Moles of \( \mathrm{NH}_{3} = \frac{28 \, \mathrm{g}}{17.03 \, \mathrm{g/mol}} \approx 1.644 \, \mathrm{mol} \).
05

Calculate the Molarity of the Solution

Finally, calculate the molarity by dividing the moles of \( \mathrm{NH}_{3} \) by the volume of the solution in liters. Molarity \( M = \frac{1.644 \, \mathrm{mol}}{0.11111 \, \mathrm{L}} \approx 14.80 \, \mathrm{mol/L} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Density
Density is a measure of how much mass is contained in a given volume. It is typically expressed in units like grams per milliliter (g/mL) or kilograms per liter (kg/L). To pick an example from everyday life, think of density as comparing a heavy rock and a light piece of foam. Even if they are the same size in volume, the rock is heavier because it is denser.

In our exercise, the density of the ammonia solution is given as \(0.90 \, \mathrm{g/mL}\). This means that every milliliter of the solution weighs 0.90 grams. Knowing the density is crucial because it allows us to convert between mass and volume—an essential step in calculating the molarity of the solution.

To find the volume of the solution, you simply divide the mass by the density. This gives us a sense of how much space the solution occupies, which is important for understanding its concentration in terms of molarity.
Percent by mass
Percent by mass, also known as mass percent, is a way to express the concentration of a component in a mixture. It tells you what fraction of the total mass of the solution is made up by the solute. If you imagine a pie chart, percent by mass is like a slice of that pie representing the component.

In our example, the ammonia solution is stated to be 28% NH3 by mass. This means in a sample of 100 grams of the solution, 28 grams are ammonia. The remaining 72 grams would be the other components of the solution, typically water in an aqueous solution.

Understanding percent by mass helps us determine how much of a solute is in our mixture, providing another piece of the puzzle necessary for calculating molarity, which is a volume-based concentration measure.
Aqueous solution
An aqueous solution is a type of solution where the solvent is water. Water is often referred to as the "universal solvent" because it can dissolve a wide variety of substances, making these kinds of solutions quite common in chemistry.

In our problem, we have an aqueous ammonia solution. This means that ammonia is dissolved in water. "Aqueous" comes from "aqua", the Latin word for water, signifying the presence of water in the mixture.

Aqueous solutions are major in chemistry because they allow reactions to occur between dissolved substances. In computational problems, they provide a base for various concentration measures, such as molarity. Knowing your solution is aqueous helps understand the environment in which the solute is dispersed.
Molar mass
Molar mass is a conversion factor that allows us to turn grams into moles, facilitating the calculations required for many chemical problems, including determining molarity. It is the mass of one mole of a substance and is usually expressed in grams per mole (g/mol).

In this exercise, we used the molar mass of ammonia (NH3) which is approximately 17.03 g/mol. This value is derived from the periodic table by adding up the atomic masses of nitrogen and hydrogen that make up ammonia.

To calculate moles from mass, you use the formula:
  • Moles = Mass (in grams) / Molar Mass (g/mol)
Using this formula, the 28 grams of NH3 in the solution were converted to moles, providing the information needed to further calculate the molarity of the solution.

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Most popular questions from this chapter

You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (a) The freezing point of the solution is unchanged by addition of the solvent. (b) The solid that forms as the solution freezes is nearly pure solute. (c) The freezing point of the solution is independent of the concentration of the solute. (d) The boiling point of the solution increases in proportion to the concentration of the solute. \((\mathbf{e})\) At any temperature, the vapor pressure of the solvent over the solution is lower than what it would be for the pure solvent.

Compounds like sodium stearate, called "surfactants" in general, can form structures known as micelles in water, once the solution concentration reaches the value known as the critical micelle concentration (cmc). Micelles contain dozens to hundreds of molecules. The cmc depends on the substance, the solvent, and the temperature. At and above the \(\mathrm{cmc}\), the properties of the solution vary drastically. (a) The turbidity (the amount of light scattering) of solutions increases dramatically at the \(\mathrm{cmc}\). Suggest an explanation. (b) The ionic conductivity of the solution dramatically changes at the cmc. Suggest an explanation. (c) Chemists have developed fluorescent dyes that glow brightly only when the dye molecules are in a hydrophobic environment. Predict how the intensity of such fluorescence would relate to the concentration of sodium stearate as the sodium stearate concentration approaches and then increases past the \(\mathrm{cmc}\)

At ordinary body temperature \(\left(37^{\circ} \mathrm{C}\right),\) the solubility of \(\mathrm{N}_{2}\) in water at ordinary atmospheric pressure is \(0.015 \mathrm{~g} / \mathrm{L}\). Air is approximately \(78 \mathrm{~mol} \% \mathrm{~N}_{2} .\) (a) Calculate the number of moles of \(\mathrm{N}_{2}\) dissolved per liter of blood, assuming blood is a simple aqueous solution. (b) At a depth of \(30.5 \mathrm{~m}\) in water, the external pressure is \(405 \mathrm{kPa}\). What is the solubility of \(\mathrm{N}_{2}\) from air in blood at this pressure? (c) If a scuba diver suddenly surfaces from this depth, how many milliliters of \(\mathrm{N}_{2}\) gas, in the form of tiny bubbles, are released into the bloodstream from each liter of blood?

Consider water and glycerol, \(\mathrm{CH}_{2}(\mathrm{OH}) \mathrm{CH}(\mathrm{OH}) \mathrm{CH}_{2} \mathrm{OH}\). (a) Would you expect them to be miscible in all proportions? (b) List the intermolecular attractions that occur between a water molecule and a glycerol molecule.

Soaps consist of compounds such as sodium stearate, \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{16} \mathrm{COO}^{-} \mathrm{Na}^{+},\) that have both hydrophobic and hydrophilic parts. Consider the hydrocarbon part of sodium stearate to be the "tail" and the charged part to be the "head." (a) Which part of sodium stearate, head or tail, is more likely to be solvated by water? (b) Grease is a complex mixture of (mostly) hydrophobic compounds. Which part of sodium stearate, head or tail, is most likely to bind to grease? (c) If you have large deposits of grease that you want to wash away with water, you can see that adding sodium stearate will help you produce an emulsion. What intermolecular interactions are responsible for this?

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