/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 57 The metabolic oxidation of gluco... [FREE SOLUTION] | 91Ó°ÊÓ

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The metabolic oxidation of glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6},\) in our bodies produces \(\mathrm{CO}_{2},\) which is expelled from our lungs as a gas: $$ \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(a q)+6 \mathrm{O}_{2}(g) \longrightarrow 6 \mathrm{CO}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) $$ (a) Calculate the volume of dry \(\mathrm{CO}_{2}\) produced at normal body temperature, \(37^{\circ} \mathrm{C},\) and \(101.33 \mathrm{kPa}\) when \(10.0 \mathrm{~g}\) of glucose is consumed in this reaction. (b) Calculate the volume of oxygen you would need, at \(100 \mathrm{kPa}\) and \(298 \mathrm{~K},\) to completely oxidize \(15.0 \mathrm{~g}\) of glucose.

Short Answer

Expert verified
(a) 8.51 L of CO2; (b) 12.36 L of O2.

Step by step solution

01

Calculate Molar Mass of Glucose

The molecular formula for glucose is \( \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6 \). Calculate the molar mass by using the atomic masses \( (\mathrm{C} = 12.01\, \text{g/mol}, \mathrm{H} = 1.008\, \text{g/mol}, \mathrm{O} = 16.00\, \text{g/mol}) \). This results in: \( 6(12.01) + 12(1.008) + 6(16.00) = 180.16\, \text{g/mol} \).
02

Calculate Moles of Glucose

For \( 10.0 \, \text{g} \) of glucose, use the formula: moles = mass / molar mass. Thus, \( \text{moles of glucose} = \frac{10.0}{180.16} \approx 0.0555 \, \text{mol} \).
03

Determine Moles of \(\mathrm{CO}_2\) Produced

From the balanced equation, 1 mole of glucose produces 6 moles of \(\mathrm{CO}_2\). Therefore, \( 0.0555 \, \text{mol of glucose} \times 6 = 0.333 \, \text{mol of } \mathrm{CO}_2 \).
04

Use Ideal Gas Law for \(\mathrm{CO}_2\) Volume

Use the ideal gas law: \( PV = nRT \). Convert temperature: \( 37\degree \mathrm{C} = 310\,\text{K} \) and pressure is \( 101.33 \, \text{kPa} = 101330 \, \text{Pa} \). \( R = 8.314 \, \text{J/(mol·K)} \). Solve for volume: \( V = \frac{nRT}{P} = \frac{0.333 \times 8.314 \times 310}{101330} \approx 8.51 \, \text{L} \).
05

Calculate Moles of Glucose for Oxygen

For \( 15.0 \, \text{g} \) glucose: \( \text{moles of glucose} = \frac{15.0}{180.16} \approx 0.0833 \, \text{mol} \).
06

Determine Moles of \(\mathrm{O}_2\) Needed

From the balanced equation, 6 moles of \(\mathrm{O}_2\) are needed per mole of glucose: \( 0.0833 \, \text{mol of glucose} \times 6 = 0.500 \, \text{mol of } \mathrm{O}_2 \).
07

Use Ideal Gas Law for \(\mathrm{O}_2\) Volume

Use the ideal gas law: \( V = \frac{nRT}{P} \). Convert temperature: \( 298\,\text{K} \) and pressure \( 100 \, \text{kPa} = 100000 \, \text{Pa} \). Solve for volume: \( V = \frac{0.500 \times 8.314 \times 298}{100000} \approx 12.36 \, \text{L} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass Calculation
Understanding molar mass calculation is essential in stoichiometry for converting between mass and moles in a chemical reaction. The molar mass of a compound is the sum of the atomic masses of all atoms present in its molecular formula. For glucose, which has the molecular formula \( \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6 \), the calculation goes as follows:

  • Carbon (C): 6 atoms, each with an atomic mass of 12.01 g/mol
  • Hydrogen (H): 12 atoms, each with an atomic mass of 1.008 g/mol
  • Oxygen (O): 6 atoms, each with an atomic mass of 16.00 g/mol
Thus, the molar mass is \( 6(12.01) + 12(1.008) + 6(16.00) = 180.16 \, \text{g/mol} \). This value allows us to calculate how many moles are present in a given mass of glucose, which is crucial for identifying how reactants and products relate in chemical reactions.
Ideal Gas Law
The ideal gas law is a useful equation in chemistry that relates the pressure, volume, temperature, and number of moles of a gas. This law is represented by the formula \( PV = nRT \), where:

  • \( P \) is the pressure of the gas
  • \( V \) is the volume of the gas
  • \( n \) is the number of moles of the gas
  • \( R \) is the ideal gas constant \( 8.314 \, \text{J/(mol·K)} \)
  • \( T \) is the temperature of the gas in Kelvin
To apply the ideal gas law, we must convert temperatures to Kelvin and pressures to the appropriate units (Pa for pressure when \( R \) is in \( \text{J/(mol·K)} \)). For example, in calculating the volume of \( \mathrm{CO}_2 \) produced at body temperature (37°C), we first convert the temperature to 310 K and the pressure from kPa to Pa, as done in the steps of the solution. The calculated volume tells us the space that a specific amount of gas occupies under given conditions.
Chemical Reaction Equations
Chemical reaction equations describe the process of reactants converting into products. In the case of glucose oxidation, the balanced equation \( \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6 (a\, q)+6 \mathrm{O}_2 (g) \rightarrow 6 \mathrm{CO}_2 (g) + 6 \mathrm{H}_2 \mathrm{O} (l) \) shows the complete reaction of glucose with oxygen to produce carbon dioxide and water.

This equation is essential for determining the stoichiometric relationships between the substances involved. Each coefficient in the equation represents the mole ratio of reactants to products. Here, 1 mole of glucose reacts with 6 moles of oxygen to produce 6 moles of carbon dioxide and 6 moles of water. Understanding these relationships enables us to calculate the exact amount of products formed from a given amount of reactants, as illustrated in the exercise solution. Such calculations form the backbone of stoichiometry in chemistry.

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Most popular questions from this chapter

You have an evacuated container of fixed volume and known mass and introduce a known mass of a gas sample. Measuring the pressure at constant temperature over time, you are surprised to see it slowly dropping. You measure the mass of the gas-filled container and find that the mass is what it should be-gas plus container-and the mass does not change over time, so you do not have a leak. Suggest an explanation for your observations.

The atmospheric concentration of \(\mathrm{CO}_{2}\) gas is presently 407 ppm (parts per million, by volume; that is, 407 L of every \(10^{6} \mathrm{~L}\) of the atmosphere are \(\mathrm{CO}_{2}\) ). What is the mole fraction of \(\mathrm{CO}_{2}\) in the atmosphere?

Which one or more of the following statements are true? (a) \(\mathrm{O}_{2}\) will effuse faster than \(\mathrm{Cl}_{2}\). (b) Effusion and diffusion are different names for the same process. (c) Perfume molecules travel to your nose by the process of effusion. (d) The higher the density of a gas, the shorter the mean free path.

A person weighing \(75 \mathrm{~kg}\) is standing on a threelegged stool. The stool momentarily tilts so that the entire weight is on one foot. If the contact area of each foot is \(5.0 \mathrm{~cm}^{2},\) calculate the pressure exerted on the underlying surface in (a) bars, \((\mathbf{b})\) atmospheres, and (c) pounds per square inch.

Propane, \(\mathrm{C}_{3} \mathrm{H}_{8}\), liquefies under modest pressure, allowing a large amount to be stored in a container. (a) Calculate the number of moles of propane gas in a 20 -L container at \(709.3 \mathrm{kPa}\) and \(25^{\circ} \mathrm{C} .\) (b) Calculate the number of moles of liquid propane that can be stored in the same volume if the density of the liquid is \(0.590 \mathrm{~g} / \mathrm{mL}\). (c) Calculate the ratio of the number of moles of liquid to moles of gas. Discuss this ratio in light of the kinetic-molecular theory of gases.

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