Chapter 18: Problem 7
Describe the basic goals of green chemistry. [Section 18.7]
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Chapter 18: Problem 7
Describe the basic goals of green chemistry. [Section 18.7]
These are the key concepts you need to understand to accurately answer the question.
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One of the possible consequences of global warming is an increase in the temperature of ocean water. The oceans serve as a "sink" for \(\mathrm{CO}_{2}\) by dissolving large amounts of it. (a) How would the solubility of \(\mathrm{CO}_{2}\) in the oceans be affected by an increase in the temperature of the water? (b) Discuss the implications of your answer to part (a) for the problem of global warming.
Draw the Lewis structure for the chlorofluorocarbon CFC-11, CFCl \(_{3}\). What chemical characteristics of this substance allow it to effectively deplete stratospheric ozone?
(a) Distinguish between photodissociation and photoionization. (b) Use the energy requirements of these two processes to explain why photodissociation of oxygen is more important than photoionization of oxygen at altitudes below about \(90 \mathrm{~km}\).
The hydroxyl radical, \(\mathrm{OH}\), is formed at low altitudes via thereaction of excited oxygen atoms with water: $$\mathrm{O}^{*}(g)+\mathrm{H}_{2} \mathrm{O}(g) \longrightarrow 2 \mathrm{OH}(g)$$ (a) Write the Lewis structure for the hydroxyl radical. (Hint: It has one unpaired electron.) Once produced, the hydroxyl radical is very reactive. Explain why each of the following series of reactions affects the pollution in the troposphere: (b) \(\mathrm{OH}+\mathrm{NO}_{2} \longrightarrow \mathrm{HNO}_{3}\) (c) \(\mathrm{OH}+\mathrm{CO}+\mathrm{O}_{2} \longrightarrow \mathrm{CO}_{2}+\mathrm{OOH}\) \(\mathrm{OOH}+\mathrm{NO} \longrightarrow \mathrm{OH}+\mathrm{NO}_{2}\) (d) \(\mathrm{OH}+\mathrm{CH}_{4} \longrightarrow \mathrm{H}_{2} \mathrm{O}+\mathrm{CH}_{3}\) \(\mathrm{CH}_{3}+\mathrm{O}_{2} \longrightarrow \mathrm{OOCH}_{3}\) \(\mathrm{OOCH}_{3}+\mathrm{NO} \longrightarrow \mathrm{OCH}_{3}+\mathrm{NO}_{2}\)
Phosphorus is present in seawater to the extent of \(0.07 \mathrm{ppm}\) by mass. If the phosphorus is present as phosphate, \(\mathrm{PO}_{4}{ }^{3-}\), calculate the corresponding molar concentration of phosphate in seawater.
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