Chapter 18: Problem 48
Discuss how catalysts can make processes more energy efficient.
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Chapter 18: Problem 48
Discuss how catalysts can make processes more energy efficient.
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The Henry's law constant for \(\mathrm{CO}_{2}\) in water at \(25^{\circ} \mathrm{C}\) is \(3.1 \times 10^{-2} \mathrm{M} \mathrm{atm}^{-1}\). (a) What is the solubility of \(\mathrm{CO}_{2}\) in water at this temperature if the solution is in contact with air at normal atmospheric pressure? (b) Assume that all of this \(\mathrm{CO}_{2}\) is in the form of \(\mathrm{H}_{2} \mathrm{CO}_{3}\) produced by the reaction between \(\mathrm{CO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\) : $$\mathrm{CO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(I) \rightarrow \mathrm{H}_{2} \mathrm{CO}_{3}(a q)$$ What is the \(\mathrm{pH}\) of this solution?
In 1986 an electrical power plant in Taylorsville, Georgia, burned \(8,376,726\) tons of coal, a national record at that time. (a) Assuming that the coal was \(83 \%\) carbon and \(2.5 \%\) sulfur and that combustion was complete, calculate the number of tons of carbon dioxide and sulfur dioxide produced by the plant during the year. (b) If \(55 \%\) of the \(\mathrm{SO}_{2}\) could be removed by reaction with powdered \(\mathrm{CaO}\) to form \(\mathrm{CaSO}_{3}\), how many tons of \(\mathrm{CaSO}_{3}\) would be produced?
Why is the photodissociation of \(\mathrm{N}_{2}\) in the atmosphere relatively unimportant compared with the photodissociation of \(\mathrm{O}_{2} ?\)
(a) Write a chemical equation that describes the attack of acid rain on limestone, \(\mathrm{CaCO}_{3}\), (b) If a limestone sculpture were treated to form a surface layer of calcium sulfate, would this help to slow down the effects of acid rain? Explain.
(a) How are the boundaries between the regions of the atmosphere determined? (b) Explain why the stratosphere, which is more than 20 miles thick, has a smaller total mass than the troposphere, which is less than 10 miles thick.
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