Chapter 11: Problem 57
(a) Draw a picture that represents a crystalline solid at the atomic level. (b) Now draw a picture that represents an amorphous solid at the atomic level.
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Chapter 11: Problem 57
(a) Draw a picture that represents a crystalline solid at the atomic level. (b) Now draw a picture that represents an amorphous solid at the atomic level.
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Covalent bonding occurs in both molecular and covalent-network solids. Why do these two kinds of solids differ so greatly in their hardness and melting points?
Using the following list of normal boiling points for a series of hydrocarbons, estimate the normal boiling point for octane, \(\mathrm{C}_{8} \mathrm{H}_{18}\) : propane \(\left(\mathrm{C}_{3} \mathrm{H}_{8},-42.1{ }^{\circ} \mathrm{C}\right)\), bu- tane \(\left(\mathrm{C}_{4} \mathrm{H}_{10},-0.5^{\circ} \mathrm{C}\right)\), pentane \(\left(\mathrm{C}_{5} \mathrm{H}_{12}, 36.1^{\circ} \mathrm{C}\right)\), hexane \(\left(\mathrm{C}_{6} \mathrm{H}_{14}, 68.7^{\circ} \mathrm{C}\right)\), heptane \(\left(\mathrm{C}_{7} \mathrm{H}_{16}, 98.4{ }^{\circ} \mathrm{C}\right) .\) Explain the trend in the boiling points.
The fluorocarbon compound \(\mathrm{C}_{2} \mathrm{Cl}_{3} \mathrm{~F}_{3}\) has a normal boiling point of \(47.6^{\circ} \mathrm{C}\). The specific heats of \(\mathrm{C}_{2} \mathrm{Cl}_{3} \mathrm{~F}_{3}(l)\) and \(\mathrm{C}_{2} \mathrm{Cl}_{3} \mathrm{~F}_{3}(g)\) are \(0.91 \mathrm{~J} / \mathrm{g}-\mathrm{K}\) and \(0.67 \mathrm{~J} / \mathrm{g}-\mathrm{K}\), respectively. The heat of vaporization for the compound is \(27.49 \mathrm{~kJ} / \mathrm{mol}\). Calculate the heat required to convert \(50.0 \mathrm{~g}\) of \(\mathrm{C}_{2} \mathrm{Cl}_{3} \mathrm{~F}_{3}\) from a liquid at \(10.00{ }^{\circ} \mathrm{C}\) to a gas at \(85.00{ }^{\circ} \mathrm{C}\).
Ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\right)\) melts at \(-114{ }^{\circ} \mathrm{C}\) and boils at \(78{ }^{\circ} \mathrm{C}\). Its density is \(0.789 \mathrm{~g} / \mathrm{mL}\). The enthalpy of fusion of ethanol is \(5.02 \mathrm{~kJ} / \mathrm{mol}\), and its enthalpy of vaporization is \(38.56 \mathrm{~kJ} / \mathrm{mol}\). The specific heats of solid and liquid ethanol are \(0.97 \mathrm{~J} / \mathrm{g}-\mathrm{K}\) and \(2.3 \mathrm{~J} / \mathrm{g}-\mathrm{K}\), respectively. (a) How much heat is required to convert \(25.0 \mathrm{~g}\) of ethanol at \(25^{\circ} \mathrm{C}\) to the vapor phase at \(78^{\circ} \mathrm{C} ?\) (b) How much heat is required to convert \(5.00 \mathrm{~L}\) of ethanol at \(-140^{\circ} \mathrm{C}\) to the vapor phase at \(78^{\circ} \mathrm{C} ?\)
A particular form of cinnabar (HgS) adopts the zinc blende structure, Figure \(11.42(b)\). The length of the unit cell side is \(5.852 \AA\). (a) Calculate the density of \(\mathrm{HgS}\) in this form. (b) The mineral tiemmanite (HgSe) also forms a solid phase with the zinc blende structure. The length of the unit cell side in this mineral is \(6.085 \AA\). What accounts for the larger unit cell length in tiemmanite? (c) Which of the two substances has the higher density? How do you account for the difference in densities?
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