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Which type of intermolecular attractive force operates between (a) all molecules, (b) polar molecules, (c) the hydrogen atom of a polar bond and a nearby small electronegative atom?

Short Answer

Expert verified
The types of intermolecular attractive forces operating between different molecules are as follows: (a) London dispersion forces operate between all molecules, (b) dipole-dipole forces operate between polar molecules, and (c) hydrogen bonding operates between the hydrogen atom of a polar bond and a nearby small electronegative atom (usually nitrogen, oxygen, or fluorine).

Step by step solution

01

Identify the force operating between all molecules.

London dispersion forces are the weakest intermolecular forces and act between all types of molecules, whether they are polar or nonpolar. They arise due to the temporary fluctuations in the electron distribution around the molecules, which creates a temporary dipole. Hence, the type of intermolecular attractive force that operates between all molecules is London dispersion forces.
02

Identify the force operating between polar molecules.

Dipole-dipole forces are the intermolecular forces present between polar molecules. Polar molecules have a permanent dipole moment due to the presence of polar bonds, which leads to the formation of partial positive and partial negative charges within the molecule. These charges are responsible for the attraction between the molecules. The type of intermolecular attractive force operating between polar molecules is dipole-dipole forces.
03

Identify the force operating between the hydrogen atom of a polar bond and a nearby small electronegative atom.

Hydrogen bonding is a special type of intermolecular attractive force that occurs when a hydrogen atom is bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and is also attracted to a nearby electronegative atom (usually nitrogen, oxygen, or fluorine). This creates a strong, directional force between the molecules. The type of intermolecular attractive force operating between the hydrogen atom of a polar bond and a nearby small electronegative atom is hydrogen bonding.

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