Chapter 11: Problem 13
Which type of intermolecular attractive force operates between (a) all molecules, (b) polar molecules, (c) the hydrogen atom of a polar bond and a nearby small electronegative atom?
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Chapter 11: Problem 13
Which type of intermolecular attractive force operates between (a) all molecules, (b) polar molecules, (c) the hydrogen atom of a polar bond and a nearby small electronegative atom?
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Name the phase transition in each of the following situations, and indicate whether it is exothermic or endothermic: (a) Bromine vapor turns to bromine liquid as it is cooled. (b) Crystals of iodine disappear from an evaporating dish as they stand in a fume hood. (c) Rubbing alcohol in an open container slowly disappears. (d) Molten lava from a volcano turns into solid rock.
(a) What atoms must a molecule contain to participate in hydrogen bonding with other molecules of the same kind? (b) Which of the following molecules can form hydrogen bonds with other molecules of the same kind: \(\mathrm{CH}_{3} \mathrm{~F}, \mathrm{CH}_{3} \mathrm{NH}_{2}, \mathrm{CH}_{3} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{Br} ?\)
Acetone, \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CO}\), is widely used as an industrial solvent. (a) Draw the Lewis structure for the acetone molecule, and predict the geometry around each carbon atom. (b) Is the acetone molecule polar or nonpolar? (c) What kinds of intermolecular attractive forces exist between acetone molecules? (d) 1-Propanol, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\), has a molecular weight that is very similar to that of acetone, yet acetone boils at \(56.5^{\circ} \mathrm{C}\) and 1 -propanol boils at \(97.2^{\circ} \mathrm{C}\). Explain the difference.
Amorphous silica has a density of about \(2.2 \mathrm{~g} / \mathrm{cm}^{3}\), whereas the density of crystalline quartz is \(2.65 \mathrm{~g} / \mathrm{cm}^{3}\) Account for this difference in densities.
What kinds of attractive forces exist between particles in (a) molecular crystals, (b) covalent-network crystals, (c) ionic crystals, (d) metallic crystals?
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