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Little is known about the properties of astatine, At, because of its rarity and high radioactivity. Nevertheless, it is possible for us to make many predictions about its properties. (a) Do you expect the element to be a gas, liquid, or solid at room temperature? Explain. (b) Would you expect At to be a metal, nonmetal, or metalloid? Explain. (c) What is the chemical formula of the compound it forms with Na?

Short Answer

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(a) Astatine is expected to be a solid at room temperature, as elements in its group become less volatile with higher boiling points as we move down the group. (b) Astatine is expected to be a metalloid, as its position below Iodine suggests more metallic character than other halogens but not as much as a true metal. (c) The chemical formula of the compound that Astatine forms with Sodium is NaAt, with Na鈦 and At鈦 ions balancing each other's charges.

Step by step solution

01

Identify the group and period of Astatine in the periodic table

Astatine is a member of Group 17, Period 6 in the periodic table. It is a halogen, like Fluorine (F), Chlorine (Cl), Bromine (Br), and Iodine (I). Knowing the group and period information will help us to compare its properties to the known properties of other elements in the same group or period.
02

Predict the state of Astatine at room temperature

Fluorine and Chlorine are gases at room temperature, whereas Bromine is a liquid and Iodine is a solid. As we move down the group from Fluorine to Iodine, the elements become less volatile and have higher boiling points. Since Astatine is below Iodine in the group, we can expect it to be a solid at room temperature. Answer (a): Astatine is expected to be a solid at room temperature.
03

Predict whether Astatine is a metal, non-metal, or metalloid

Astatine belongs to the halogen group, which contains non-metals. However, as we move down the group, the elements exhibit a gradual trend from non-metallic to more metallic character. Fluorine is the most non-metallic element, while Iodine has some metallic properties. Given its position below Iodine, Astatine is expected to have even more metallic character than Iodine, but not as much as a true metal. Therefore, it is predicted to be a metalloid. Answer (b): Astatine is expected to be a metalloid.
04

Determine the chemical formula of the compound Astatine forms with Sodium

Astatine, being a member of the halogen group, has 7 electrons in its outermost shell and needs one more to achieve a stable electron configuration. Sodium, a member of Group 1, has one electron in its outermost shell and readily donates it. When Astatine reacts with Sodium, each Astatine atom will gain one electron while each Sodium atom loses one. This leads to the formation of Na鈦 and At鈦 ions. The chemical formula of the compound formed by these ions will be NaAt, as the positive and negative charges balance each other. Answer (c): The chemical formula of the compound that Astatine forms with Sodium is NaAt.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Periodic table
The periodic table is a systematic arrangement of elements based on their atomic number, electron configurations, and recurring chemical properties. Astatine is found in Group 17, Period 6 of the periodic table. This group is known as the halogens, which includes elements like fluorine, chlorine, bromine, and iodine.
Astatine, being part of this group, shares certain characteristic properties. Generally, as you move down this group, the elements have increasing atomic numbers and heavier atomic masses. The periodic table helps us predict many properties of elements, even those that are not well-studied like astatine.
  • Group 17 elements tend to be very reactive and have seven electrons in their outermost shell.
  • Period 6 elements include some of the heavier and more complex atoms on the table.
Understanding the position of an element on the periodic table also helps in predicting physical and chemical behaviors such as state at room temperature and general appearance.
Halogens
Halogens are a fascinating group in the periodic table. This group consists of nonmetals that are highly reactive, particularly with alkali and alkaline earth metals. The halogens are fluorine, chlorine, bromine, iodine, and astatine. Each of these elements has seven valence electrons, which makes them eager to gain one electron to achieve a stable noble gas electron configuration.
In the halogen group, elements showcase a trend where they become less reactive and have higher boiling points as you move down from fluorine to iodine. Astatine, being the heaviest, is expected to show some unique properties. For example:
  • Reactivity tends to decrease from fluorine to astatine.
  • Fluorine and chlorine are gases, bromine is a liquid, iodine, and expectedly astatine, are solids at room temperature.
Halogens readily form salts when they react with metals, highlighting their significant role in chemical bonding scenarios.
Chemical formula prediction
Chemical formula prediction is an essential skill in chemistry that involves understanding how elements interact to form compounds. Astatine, as a member of the halogen group, typically forms an ionic compound with large electronegativity differences. When considering an astatine and sodium compound, we apply the rule of charges.
- Astatine has 7 valence electrons and needs one more to complete its outer shell. - Sodium, a Group 1 alkali metal, has 1 valence electron which it can lose easily.
In their reaction, sodium donates its electron to astatine, forming sodium ions (Na鈦) and astatine ions (At鈦). This creates an ionic bond, and by following the principle of charge neutrality, the chemical formula becomes NaAt. Predicting chemical formulas requires a basic understanding of how electrons interact across different groups and periods in the periodic table.
Nonmetals and metalloids
Astatine's classification was initially ambiguous due to limited research, but understanding its position in the periodic table provides clarity. Nonmetals are elements typically located on the right side of the periodic table and are known for their lack of metallic luster, poor conductivity, and high ionization energies. Halogens are primarily nonmetals.
- A nonmetal like iodine, when examined in Group 17, shows both metallic and nonmetallic properties, especially heavier halogens such as iodine. - Astatine, positioned below iodine, displays traits suggesting metalloid characteristics.
Metalloids have properties intermediate between metals and nonmetals, making them unique. Astatine's expected properties might include some resemblance to iodine in terms of appearance and a slight ability to conduct electricity, similar to other metalloids. Therefore, although traditionally grouped as a nonmetal, astatine could exhibit metalloid behaviors due to its position in the periodic table and trends observed among heavier halogens.

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Most popular questions from this chapter

Silver and rubidium both form \(+1\) ions, but silver is far less reactive. Suggest an explanation, taking into account the ground-state electron configurations of these elements and their atomic radii.

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