Chapter 7: Problem 58
Discussing this chapter, a classmate says, "Since elements that form cations are metals and elements that form anions are nonmetals, elements that do not form ions are metalloids." Do you agree or disagree?
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Chapter 7: Problem 58
Discussing this chapter, a classmate says, "Since elements that form cations are metals and elements that form anions are nonmetals, elements that do not form ions are metalloids." Do you agree or disagree?
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Elemental cesium reacts more violently with water than does elemental sodium. Which of the following best explains this difference in reactivity? (i) Sodium has greater metallic character than does cesium. (ii) The first ionization energy of cesium is less than that of sodium. (iii) The electron affinity of sodium is smaller than that of cesium. (iv) The effective nuclear charge for cesium is less than that of sodium. (v) The atomic radius of cesium is smaller than that of sodium.
The electron affinities, in \(\mathrm{kJ} / \mathrm{mol},\) for the group 1 \(\mathrm{B}\) and group 2 \(\mathrm{B}\) metals are as follows: (a) Why are the electron affinities of the group 2 \(\mathrm{B}\) elements greater than zero? (b) Why do the electron affinities of the group 1 \(\mathrm{B}\) elements become more negative as we move down the group? [Hint: Examine the trends in the electron affinities of other groups as we proceed down the periodic table.]
Potassium superoxide, \(\mathrm{KO}_{2},\) is often used in oxygen masks (such as those used by firefighters) because \(\mathrm{KO}_{2}\) reacts with \(\mathrm{CO}_{2}\) to release molecular oxygen. Experiments indicate that 2 \(\mathrm{mol}\) of \(\mathrm{KO}_{2}(s)\) react with each mole of= \(\mathrm{CO}_{2}(g) .\) (a) The products of the reaction are \(\mathrm{K}_{2} \mathrm{CO}_{3}(s)\) and \(\mathrm{O}_{2}(g) .\) Write a balanced equation for the reaction between \(\mathrm{KO}_{2}(s)\) and \(\mathrm{CO}_{2}(g) .(\mathbf{b})\) Indicate the oxidation number for each atom involved in the reaction in part (a). What elements are being oxidized and reduced? (c) What mass of \(\mathrm{KO}_{2}(s)\) is needed to consume 18.0 \(\mathrm{g} \mathrm{CO}_{2}(g) ?\) What mass of \(\mathrm{O}_{2}(g)\) is produced during this reaction?
The first ionization energy of the oxygen molecule is the energy required for the following process: $$\mathrm{O}_{2}(g) \longrightarrow \mathrm{O}_{2}^{+}(g)+\mathrm{e}^{-}$$ The energy needed for this process is 1175 \(\mathrm{kJ} / \mathrm{mol}\) , very similar to the first ionization energy of \(\mathrm{Xe} .\) Would you expect \(\mathrm{O}_{2}\) to react with \(\mathrm{F}_{2} ?\) If so, suggest a product or products of this reaction.
(a) Does metallic character increase, decrease, or remain unchanged as one goes from left to right across a row of the periodic table? (b) Does metallic character increase, decrease, or remain unchanged as one goes down a column of the periodic table? (c) Are the periodic trends in (a) and (b) the same as or different from those for first ionization energy?
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