Chapter 18: Problem 56
Discuss how catalysts can make processes more energy efficient.
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Chapter 18: Problem 56
Discuss how catalysts can make processes more energy efficient.
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You are working with an artist who has been commissioned to make a sculpture for a big city in the eastern United States. The artist is wondering what material to use to make her sculpture because she has heard that acid rain in the eastern United States might destroy it over time. You take samples of granite, marble, bronze, and other materials, and place them outdoors for a long time in the big city. You periodically examine the appearance and measure the mass of the samples. (a) What observations would lead you to conclude that one or more of the materials are well-suited for the sculpture? (b) What chemical process (or processes) is (are) the most likely responsible for any observed changes in the materials? [Section 18.2]
Explain, using Le Chatelier's principle, why the equilibrium constant for the formation of NO from \(\mathrm{N}_{2}\) and \(\mathrm{O}_{2}\) increases with increasing temperature, whereas the equilibrium constant for the formation of \(\mathrm{NO}_{2}\) from \(\mathrm{NO}\) and \(\mathrm{O}_{2}\) decreases with increasing temperature.
Which of the following reactions in the stratosphere cause an increase in temperature there? \begin{equation}\begin{array}{l}{\text { (a) } \mathrm{O}(g)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{O}_{3}^{*}(g)} \\ {\text { (b) } \mathrm{O}_{3}^{\star}(g)+\mathrm{M}(g) \longrightarrow \mathrm{O}_{3}(g)+\mathrm{M}^{\star}(g)} \\ {\text { (c) } \mathrm{O}_{2}(g)+h \nu \longrightarrow 2 \mathrm{O}(g)}\\\\{\text { (d) } \mathrm{O}(g)+\mathrm{N}_{2}(g) \longrightarrow \mathrm{NO}(g)+\mathrm{N}(g)} \\\ {\text { (e) All of the above }}\end{array}\end{equation}
Nitrogen oxides like \(\mathrm{NO}_{2}\) and \(\mathrm{NO}\) are a significant source of acid rain. For each of these molecules write an equation that shows how an acid is formed from the reaction with water.
The first stage in corrosion of iron upon exposure to air is oxidation to \(\mathrm{Fe}^{2+} .\) (a) Write a balanced chemical equation to show the reaction of iron with oxygen and protons from acid rain. (b) Would you expect the same sort of reaction to occur with a silver surface? Explain.
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