Chapter 24: Problem 51
Write a balanced chemical equation using condensed structural formulas for the saponification (base hydrolysis) of (a) methyl propionate, (b) phenyl acetate.
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Chapter 24: Problem 51
Write a balanced chemical equation using condensed structural formulas for the saponification (base hydrolysis) of (a) methyl propionate, (b) phenyl acetate.
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Enediynes are a class of compounds that include some antibiotic drugs. Draw the structure of an "enediyne" fragment that contains six carbons in a row.
When samples of double-stranded DNA are analyzed, the quantity of adenine present equals that of thymine. Similarly, the quantity of guanine equals that of cytosine. Explain the significance of these observations.
Explain why the boiling point of ethanol \(\left(78^{\circ} \mathrm{C}\right)\) is much higher than that of its isomer, dimethyl ether \(\left(-25^{\circ} \mathrm{C}\right)\), and why the boiling point of \(\mathrm{CH}_{2} \mathrm{~F}_{1}\left(-52^{\circ} \mathrm{C}\right)\) is far above that of \(\mathrm{CH}_{4}\left(-128^{\circ} \mathrm{C}\right)\).
(a) What is the empirical formula of cellulose? (b) What is the monomer that forms the basis of the cellulose polymer? (c) What bond connects the monomer units in cellulose: amide, acid, ether, ester, or alcohol?
A typical amino acid with one amino group and one carboxylic acid group, such as serine, can exist in water in several ionic forms. (a) Suggest the forms of the amino acid at low pH and at high \(\mathrm{pH}\). (b) Amino acids generally have two \(\mathrm{p} K_{a}\) values, one in the range of 2 to 3 and the other in the range of 9 to 10. Serine, for example, has \(\mathrm{pK} K_{4}\) values of \(2.19\) and \(9.21\). Using species such as acetic acid and ammonia as models, suggest the origin of the two \(\mathrm{pK}_{\mathrm{a}}\) values. (c) Glutamic acid is an amino acid that has three \(\mathrm{pK}_{a}\) ' \(\times 2.10,4.07\), and 9.47. Draw the structure of glutamic acid, and assign each \(\mathrm{p} K_{a}\) to the appropriate part of the molecule. (d) An unknown amino acid is titrated with strong base, producing the following titration curve. Which amino acids are likely candidates for the unknown?
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