Chapter 23: Problem 18
Which type of magnetic material cannot be used to make permanent magnets, a ferromagnetic substance, an antiferromagnetic substance, or a ferrimagnetic substance?
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Chapter 23: Problem 18
Which type of magnetic material cannot be used to make permanent magnets, a ferromagnetic substance, an antiferromagnetic substance, or a ferrimagnetic substance?
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True or false? The following ligand can act as a bidentate ligand?
Metallic elements are essential components of many important enzymes operating within our bodies. Carbonic anhydrase, which contains \(Z \mathrm{n}^{2+}\) in its active site, is responsible for rapidly interconverting dissolved \(\mathrm{CO}_{2}\) and bicarbonate ion, \(\mathrm{HCO}_{3}^{-}\). The zinc in carbonic anhydrase is tetrahedrally coordinated by three neutral nitrogen- containing groups and a water molecule. The coordinated water molecule has a pK of 7.5, which is crucial for the enxyme's activity. (a) Draw the active site geometry for the Zn(II) center in carbonic anhydrasc, just writing " \(\mathrm{N}^{\text {" }}\) for the three neutral nitrogen ligands from the protein. (b) Compare the \(p K_{a}\) of carbonic anhydrase's active site with that of pure water, which species is more acidic?
Based on the molar conductance values listed here for the series of platinum(IV) complexes, write the formula for each complex so as to show which ligands are in the coordination sphere of the metal. By way of example, the molar conductances of \(0.050 \mathrm{M} \mathrm{NaCl}\) and \(\mathrm{BaCl}_{2}\) are \(107 \mathrm{ohm}^{-1}\) and \(197 \mathrm{ohm}^{-1}\), respectively. \begin{tabular}{lc} \hline Complex & Molar Conductance \(\left(o \text { ohm }^{-1}\right)^{*}\) of \(0.050\) M Solution \\ \hline \(\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{6} \mathrm{Cl}_{4}\) & 523 \\ \(\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{4}\) & 228 \\ \(\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{4}\) & 97 \\ \(\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{4}\) & 0 \\ \(\left.\mathrm{KPt}_{4}\right) \mathrm{NH}_{5}\) & 108 \\ \hline \end{tabular} "The ohm is a unit of resistance; conductance is the inverse of resistance.
Consider the following three complexes (Complex 1) \(\left[\mathrm{Co}\left(\mathrm{NH}_{2}\right)_{5} \mathrm{SCN}\right]^{2+}\) (Complex 2) \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]^{2+}\) (Complex 3) \(\mathrm{CoClBx}+5 \mathrm{NH}_{3}\) Which of the three complexes can have (a) geometric isomers, (b) linkage isomers, (c) optical isomers, (d) coordinationsphere isomers?
Consider the tetrahedral anions \(\mathrm{VO}_{4}^{3-}\) (orthovanadate ion), \(\mathrm{CrO}_{4}^{2-}\) (chromate ion), and \(\mathrm{MnO}_{4}^{-}\)(permanganate ion). (a) These anions are isoelectronic. What does this statement mean? (b) Would you expect these anions to exhibit \(d-d\) transitions? Explain. (c) As mentioned in "A Closer Look" on charge- transfer color, the violet color of \(\mathrm{MnO}_{4}^{-}\)is due to a ligand- to-metal charge transfer (LMCT) transition. What is meant by this term? (d) The LMCT transition in \(\mathrm{MnO}_{4}^{-}\)occurs at a wavelength of \(565 \mathrm{~nm}\). The \(\mathrm{CrO}_{4}^{2}\) ion is yellow. Is the wavelength of the LMCT transition for chromate larger or smaller than that for \(\mathrm{MnO}_{4}^{-}\)? Explain. (e) The \(\mathrm{VO}_{4}^{3-}\) ion is colorless. Do you expect the light absorbed by the LMCT to fall in the UV or the IR region of the electromagnetic spectrum? Explain your reasoning.
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