Chapter 22: Problem 65
Give the chemical formula for (a) hydrocyanic acid, (b) nickel tetracarbonyl, (c) barium bicarbonate, (d) calcium acetylide, (e) potassium carbonate.
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Chapter 22: Problem 65
Give the chemical formula for (a) hydrocyanic acid, (b) nickel tetracarbonyl, (c) barium bicarbonate, (d) calcium acetylide, (e) potassium carbonate.
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Borazine, \((\mathrm{BH})_{3}(\mathrm{NH})_{3}\), is an analog of \(\mathrm{C}_{6} \mathrm{H}_{6}\), benzene. It can be prepared from the reaction of diborane with ammonia, with hydrogen as another product; or from lithium borohydride and ammonium chloride, with lithium chloride and hydrogen as the other products. (a) Write balanced chemical equations for the production of borazine using both synthetic methods. (b) Draw the Lewis dot structure of borazine. (c) How many grams of borazine can be prepared from \(2.00 \mathrm{~L}\) of ammonia at STP, assuming diborane is in excess?
(a) Determine the number of calcium ions in the chemical formula of the mineral hardystonite, \(\mathrm{Ca}_{x} \mathrm{Zn}\left(\mathrm{Si}_{2} \mathrm{O}_{7}\right)\). (b) Determine the number of hydroxide ions in the chemical formula of the mineral pyrophyllite, \(\mathrm{Al}_{2}\left(\mathrm{Si}_{2} \mathrm{O}_{5}\right)_{2}(\mathrm{OH})_{x}\).
(a) What is the characteristic geometry about silicon in all silicate minerals? (b) Metasilicic acid has the empirical formula \(\mathrm{H}_{2} \mathrm{SiO}_{3}\). Which of the structures shown in Figure \(22.34\) would you expect metasilicic acid to have? 22.76 Speculate as to why carbon forms carbonate rather than silicate analogs.
Complete and balance the following equations: (a) \(\mathrm{Mg}_{3} \mathrm{~N}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l)\) (b) \(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}(l)+\mathrm{O}_{2}(g) \longrightarrow\) (c) \(\mathrm{MnO}_{2}(s)+\mathrm{C}(s) \stackrel{\Delta}{\longrightarrow}\) (d) \(\mathrm{AlP}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow\) (e) \(\mathrm{Na}_{2} \mathrm{~S}(s)+\mathrm{HCl}(a q) \longrightarrow\)
The dissolved oxygen present in any highly pressurized, high-temperature steam boiler can be extremely corrosive to its metal parts. Hydrazine, which is completely miscible with water, can be added to remove oxygen by reacting with it to form nitrogen and water. (a) Write the balanced equation for the reaction between gaseous hydrazine and oxygen. (b) Calculate the enthalpy change accompanying this reaction. (c) Oxygen in air dissolves in water to the extent of \(9.1\) Ppm at \(20^{\circ} \mathrm{C}\) at sea level. How many grams of hydrazine are required to react with all the oxygen in \(3.0 \times 10^{4} \mathrm{~L}\) (the volume of a small swimming pool) under these conditions?
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