Chapter 20: Problem 13
(a) What is meant by the term oxidation? (b) On which side of an oxidation half-reaction do the electrons appear? (c) What is meant by the term oxidant? (d) What is meant by the term oxidizing agent?
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Chapter 20: Problem 13
(a) What is meant by the term oxidation? (b) On which side of an oxidation half-reaction do the electrons appear? (c) What is meant by the term oxidant? (d) What is meant by the term oxidizing agent?
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Magnesium is obtained by electrolysis of molten \(\mathrm{MgCl}_{2}\). (a) Why is an aqueous solution of \(\mathrm{MgC}_{2}\) not used in the electrolysis? (b) Several cells are connected in parallel by very large copper bars that convey current to the cells. Assuming that the cells are \(96 \%\) efficient in producing the desired products in electrolysis, what mass of \(\mathrm{Mg}\) is formed by passing a current of \(97,000 \mathrm{~A}\) for a period of \(24 \mathrm{~h}\) ?
A voltaic cell that uses the reaction $$ \mathrm{PdCl}_{4}{ }^{2-}(a q)+\mathrm{Cd}(s) \longrightarrow \mathrm{Pd}(s)+4 \mathrm{CT}(a q)+\mathrm{Cd}^{2+}(a q) $$ has a measured standard cell potential of \(+1.03 \mathrm{~V}\). (a) Write the two half-cell reactions. (b) By using data from Appendix \(E\), determine \(E_{\text {rel }}^{0}\) for the reaction involving \(\mathrm{Pd}\). (c) Sketch the voltaic cell, label the anode and cathode, and indicate the direction of electron flow.
A common shorthand way to represent a voltaic cell is anode | anode solution || cathode solution |cathode A double vertical line represents a salt bridge or a porous barrier. A single vertical line represents a change in phase, such AS from solid to solution. (a) Write the half-reactions and overall cell reaction represented by Fe \(\left|\mathrm{Fe}^{2+}\right|\left|\mathrm{Ag}^{+}\right| \mathrm{Ag}_{\mathrm{g}}\) sketch the cell. (b) Write the half-reactions and overall cell reaction represented by \(\mathrm{Zn}\left|\mathrm{Zn}^{2+}\right|\left|\mathrm{H}^{+}\right| \mathrm{H}_{3}\) s sketch the cell. (c) Using the notation just described, represent a cell based on the following reaction: $$ \begin{aligned} \mathrm{ClO}_{3}^{-}(a q)+3 \mathrm{Cu}(s)+6 \mathrm{H}^{+}(a q) & \longrightarrow \mathrm{Cl}^{-}(a q)+3 \mathrm{Cu}^{2+}(a q)+3 \mathrm{H}_{2} \mathrm{O}(l) \end{aligned} $$ Pt is used as an inert electrode in contact with the \(\mathrm{ClO}_{3}^{-}\)and Cl. Sketch the cell.
(a) How many coulombs are required to plate a layer of chromium metal \(0.25 \mathrm{~mm}\) thick on an auto bumper with a total area of \(0.32 \mathrm{~m}^{2}\) from a solution containing \(\mathrm{CrO}_{4}{ }^{2-}\) ? The density of chromium metal is \(7.20 \mathrm{~g} / \mathrm{cm}^{3}\), (b) What current flow is required for this electroplating if the bumper is to be plated in \(10.0 \mathrm{~s}\) ? (c) If the external source has an emf of \(+6.0 \mathrm{~V}\) and the electrolytic cell is \(65 \%\) efficient, hew much electrical power is expended to electroplate the bumper?
(a) What is meant by the term reduction? (b) On which side of a reduction half-reaction do the electrons appear? (c) What is meant by the term reductant? (d) What is meant by the term reducing agent?
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