Chapter 7: Problem 52
If the electron affinity for an element is a negative number, does it mean that the anion of the element is more stable than the neutral atom? Explain.
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Chapter 7: Problem 52
If the electron affinity for an element is a negative number, does it mean that the anion of the element is more stable than the neutral atom? Explain.
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We will see in Chapter 12 that semiconductors are materials that conduct electricity better than nonmetals but not as well as metals. The only two elements in the periodic table that are technologically useful semiconductors are silicon and germanium. Integrated circuits in computer chips today are based on silicon. Compound semiconductors are also used in the electronics industry. Examples are gallium arsenide, GaAs; gallium phosphide, GaP; cadmium sulfide, CdS; cadium selenide, CdSe. (a) What is the relationship between the compound semiconductors' compositions and the positions of their elements on the periodic table relative to \(\mathrm{Si}\) and Ge? (b) Workers in the semiconductor industry refer to \({ }^{4} \mathrm{II}-\mathrm{VI}^{m}\) and \({ }^{4} \mathrm{III}-\mathrm{V}^{n} \mathrm{ma}-\) terials, using Roman numerals; can you identify which compound semiconductors are II-VI and which are III-V? Suggest other compositions of compound semiconductors based on the positions of their elements in the periodic table.
(a) Why does Li have a larger first ionization energy than Na? (b) The difference between the third and fourth ionization energies of scandium is much larger than the difference between the third and fourth ionization energies of titanium. Why? (c) Why does Li have a much larger second ionization energy than Be?
(a) What is meant by the term effective nuclear charge? (b) How does the effective nuclear charge experienced by the valence electrons of an atom vary going from left to right across a period of the periodic table?
We can draw an analogy between the attraction of an electron to a nucleus and seeing a lightbulb -in essence, the more \(n u=\) clear charge the electron "sees," the greater the attraction. (a) Within this analogy, discuss how the screening by core electrons is analogous to putting a frosted-glass lampshade between the lightbulb and your eyes, as shown in the illustration. (b) Explain how we could mimic moving to the right in a row of the periodic table by changing the wattage of the lightbulb. (c) How would you change the wattage of the bulb and/or the frosted glass to mimic the effect of moving down a column of the periodic table? [Section 7.2]
How do the sizes of atoms change as we move (a) from left to right across a row in the periodic table, (b) from top to bottom in a group in the periodic table? (c) Arrange the following atoms in order of increasing atomic radius: \(\mathrm{O}, \mathrm{Si}, \mathrm{I}, \mathrm{Ge} .\)
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